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      Highly Integrated Triboelectric Nanogenerator for Efficiently Harvesting Raindrop Energy

      1 , 2 , 3 , 4 , 1 , 2 , 3 , 4
      Advanced Materials Technologies
      Wiley

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          Abstract

          The emergence of triboelectric nanogenerators (TENG) has promoted the harvesting of raindrop energy, which mainly includes the kinetic energy and electrostatic energy generated during the fall of raindrops. However, maximizing the use of such energy is quite challenging due to its fragmentary characteristics. A highly integrated TENG is developed that can efficiently collect raindrop energy. It consists of a saccular contact‐separation mode TENG (SCS‐TENG), a freestanding TENG with interdigitated electrodes (I‐TENG), and strip‐shaped I‐TENGs (SI‐TENG). At a water drop rate of 22 mL s −1, it demonstrates a striking increase with short‐circuit current of 95.4 µA and open‐circuit voltage of 42.2 V, whereas the output of single TENGs is only 8.1 µA/5.9 V (SI‐TENG), 75.1 µA/29.3 V (I‐TENG), and 9.1 µA/28.9 V (SCS‐TENG), respectively. Moreover, it can be used in self‐powered devices and as a rain alarm system. It not only provides a promising step toward the efficient collection of raindrop energy but also provides a new perspective for the research and development of self‐powered sensors based on rainfall.

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          Most cited references31

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          Progress in triboelectric nanogenerators as a new energy technology and self-powered sensors

          A review on the principles, novel applications and perspectives of triboelectric nanogenerators as power sources and as self-powered sensors.
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            On Maxwell's displacement current for energy and sensors: the origin of nanogenerators

            Zhong Wang (2017)
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              Triboelectric nanogenerators as new energy technology for self-powered systems and as active mechanical and chemical sensors.

              Zhong Wang (2013)
              Triboelectrification is an effect that is known to each and every one probably since ancient Greek time, but it is usually taken as a negative effect and is avoided in many technologies. We have recently invented a triboelectric nanogenerator (TENG) that is used to convert mechanical energy into electricity by a conjunction of triboelectrification and electrostatic induction. As for this power generation unit, in the inner circuit, a potential is created by the triboelectric effect due to the charge transfer between two thin organic/inorganic films that exhibit opposite tribo-polarity; in the outer circuit, electrons are driven to flow between two electrodes attached on the back sides of the films in order to balance the potential. Since the most useful materials for TENG are organic, it is also named organic nanogenerator, which is the first using organic materials for harvesting mechanical energy. In this paper, we review the fundamentals of the TENG in the three basic operation modes: vertical contact-separation mode, in-plane sliding mode, and single-electrode mode. Ever since the first report of the TENG in January 2012, the output power density of TENG has been improved 5 orders of magnitude within 12 months. The area power density reaches 313 W/m(2), volume density reaches 490 kW/m(3), and a conversion efficiency of ∼60% has been demonstrated. The TENG can be applied to harvest all kinds of mechanical energy that is available but wasted in our daily life, such as human motion, walking, vibration, mechanical triggering, rotating tire, wind, flowing water, and more. Alternatively, TENG can also be used as a self-powered sensor for actively detecting the static and dynamic processes arising from mechanical agitation using the voltage and current output signals of the TENG, respectively, with potential applications for touch pad and smart skin technologies. To enhance the performance of the TENG, besides the vast choices of materials in the triboelectric series, from polymer to metal and to fabric, the morphologies of their surfaces can be modified by physical techniques with the creation of pyramid-, square-, or hemisphere-based micro- or nanopatterns, which are effective for enhancing the contact area and possibly the triboelectrification. The surfaces of the materials can be functionalized chemically using various molecules, nanotubes, nanowires, or nanoparticles, in order to enhance the triboelectric effect. The contact materials can be composites, such as embedding nanoparticles in a polymer matrix, which may change not only the surface electrification but also the permittivity of the materials so that they can be effective for electrostatic induction. Therefore, there are numerous ways to enhance the performance of the TENG from the materials point of view. This gives an excellent opportunity for chemists and materials scientists to do extensive study both in the basic science and in practical applications. We anticipate that a better enhancement of the output power density will be achieved in the next few years. The TENG is possible not only for self-powered portable electronics but also as a new energy technology with potential to contribute to the world energy in the near future.
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                Author and article information

                Contributors
                Journal
                Advanced Materials Technologies
                Adv Materials Technologies
                Wiley
                2365-709X
                2365-709X
                November 2019
                September 26 2019
                November 2019
                : 4
                : 11
                Affiliations
                [1 ] Key Lab New Processing Technology for Nonferrous Metals and Materials Ministry of Education College of Materials science and engineering Guilin University of Technology Guilin 541004 China
                [2 ] CAS Center for Excellence in Nanoscience Beijing Key Laboratory of Micro‐Nano Energy and Sensor Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences Beijing 100083 China
                [3 ] School of Nanoscience and Technology University of Chinese Academy of Sciences Beijing 100049 China
                [4 ] Center on Nanoenergy Research School of Physical Science and Technology Guangxi University Nanning 530004 China
                Article
                10.1002/admt.201900608
                2914e777-4357-4c78-8edf-5109dd0a6088
                © 2019

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