Recent advances in the polymerization of elemental sulphur, inverse vulcanization and methods to obtain functional Chalcogenide Hybrid Inorganic/Organic Polymers (CHIPs)

Author(s): Yueyan Zhang ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Richard S. Glass ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Kookheon Char ⁶ ^, ⁷ ^, ⁸ ^, ⁹ ^, ¹⁰ , Jeffrey Pyun ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵

Publication date (Electronic): 2019

Journal: Polymer Chemistry

Publisher: Royal Society of Chemistry (RSC)

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Abstract

Recent developments in the polymerization of elemental sulfur, inverse vulcanization and functional Chalcogenide Hybrid Inorganic/Organic Polymers (CHIPs) are reviewed.

Abstract

Recent developments in the polymerization of elemental sulfur and the preparation of functional Chalcogenide Hybrid Inorganic/Organic Polymers (CHIPs) are reviewed. CHIPs represent a class of polymers synthesized from elemental sulfur with the incorporation of inorganic chalcogenide components (S, Se, Te) into the organic polymeric backbones. Novel CHIP materials exhibit interesting optical, electrochemical and mechanical properties that lead to applications in thermal imaging, energy storage, self-healable materials and separation science. The emphasis of this review is on the key advances in the synthetic approaches to prepare functional polymeric sulfur-rich materials, with recent developments in synthesis, characterization, and application milestones being highlighted.

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Author and article information

Contributors

Yueyan Zhang: (View ORCID Profile)

Kookheon Char: (View ORCID Profile)

Jeffrey Pyun: (View ORCID Profile)

Journal

Journal ID (publisher-id): PCOHC2

Title: Polymer Chemistry

Abbreviated Title: Polym. Chem.

Publisher: Royal Society of Chemistry (RSC)

ISSN (Print): 1759-9954

ISSN (Electronic): 1759-9962

Publication date Created: July 30 2019

Publication date (Electronic): 2019

Volume: 10

Issue: 30

Pages: 4078-4105

Affiliations

[1 ]Department of Chemistry and Biochemistry

[2 ]University of Arizona

[3 ]1306 East University Boulevard

[4 ]Tucson

[5 ]USA

[6 ]School of Chemical and Biological Engineering

[7 ]Program for Chemical Convergence for Energy & Environment

[8 ]The National Creative Research Initiative Center for Intelligent Hybrids

[9 ]Seoul 151-744

[10 ]Korea

Article

DOI: 10.1039/C9PY00636B

SO-VID: 27cae23a-0a66-4122-a2f0-afdc7a4be1c8

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