Alkali-feldspar and Fe-Ti oxide exsolution textures as indicators of the distribution and subsolidus effects of magmatic ‘water’ in the Klokken layered syenite intrusion, South Greenland

Abstract

The layered syenites in the Klokken intrusion consist of horizons of fine-grained, granular-textured ferroaugite syenite showing inverted cryptic layering, interleaved with coarser, laminated, more fractionated hedenbergite syenite. Distribution of hydrous mafic phases indicates build-up of water in parallel with magmatic evolution, and druses and pegmatitic segregations in the laminated syenites are evidence for late development of a gas phase. Feldspar bulk compositions are close to the minimum on the Ab-Or binary, with An decreasing from An ₇to An ₁with fractionation, and normal zoning in cryptoperthite crystals. Feldspars in granular syenites are transparent coherent cryptoperthites or braid microperthites; An-content is probably the main control of fine-perthite coarseness. Laminated syenite feldspars are turbid, coarse patch microperthites with rare relics of braid textures. This non-coherent coarsening was caused by interactions between feldspars and water entrapped at magmatic temperatures which was retained within the original lithologies to low subsolidus temperatures. Fe-Ti oxides reflect this water distribution, with regular trellis ilmenite-titanomagnetite intergrowths in less fractionated rocks and ragged granule exsolution in more advanced syenites. The sharp change in exsolution textures at granular-laminated syenite boundaries implies steep water-gradients within these interleaved rock types. Water was unable to penetrate the granular layers and did not circulate freely in the cooling intrusion.