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      Renewable Methanol from Industrial Carbon Emissions: A Dead End or Sustainable Way Forward?

      research-article
      ACS Omega
      American Chemical Society

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          Abstract

          As the urgency to achieve net-zero emissions by 2050 intensifies, industries face an imperative to reimagine their role in the fight against climate change. One promising avenue arises from the realization that industrial emissions, often deemed pollutants, can be the building blocks of a circular economy strategy. By directly utilizing these carbon emissions as raw materials, we can produce net-zero or low-carbon fuels, carbonates, polymers, and chemicals. At the heart of this paradigm shift lies the production of carbon-neutral methanol from industrial flue gas—a technically viable approach that has gained significant momentum in recent years. The conditions under which such a circular economy model for producing renewable methanol becomes commercially sustainable based on realistic constraints, however, are not sufficiently explored in the existing literature. This paper fills this gap by investigating if and when net-zero methanol production from industrial flue gas will be a sustainable long-term strategy. Using detailed technoeconomic modeling of integrated hydrogen and methanol production ecosystems for two production capacities, I will evaluate 32 practical production scenarios using realistic regulatory, economic, and market conditions. Even though renewable methanol from industrial emissions can be a viable technical solution to address climate change and global warming, I will show why this strategy will be commercially feasible only under favorable economic, regulatory, and market conditions. Furthermore, I will demonstrate how the market price of methanol and the cost of carbon-free electricity critically influence the commercial feasibility of this approach. When these two parameters are unfavorable, I will show why other factors, namely, carbon credits and byproduct (oxygen) sales, will not be sufficient to create an economically sustainable circular economy of renewable methanol from industrial emissions. Finally, I will provide arguments on why one has to think through stakeholder cooperation and public–private partnerships to mitigate various project risks. Despite the importance of this topic, it is not sufficiently covered in the available scientific literature. To advance policy and regulatory frameworks in this area, I strongly believe that further research and development is needed. I will also share perspectives on regulatory derisking mechanisms, which can help align regulations with private investors’ preferences. With the analyses and arguments showcased in this paper, I will firmly assert that without favorable conditions, strong partnerships, and stakeholder cooperation, the production of renewable net-zero methanol from industrial emissions risks becoming a dead-end strategy.

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          Most cited references61

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          Carbon capture and storage (CCS): the way forward

          Carbon capture and storage (CCS) is vital to climate change mitigation, and has application across the economy, in addition to facilitating atmospheric carbon dioxide removal resulting in emissions offsets and net negative emissions. This contribution reviews the state-of-the-art and identifies key challenges which must be overcome in order to pave the way for its large-scale deployment. Carbon capture and storage (CCS) is broadly recognised as having the potential to play a key role in meeting climate change targets, delivering low carbon heat and power, decarbonising industry and, more recently, its ability to facilitate the net removal of CO 2 from the atmosphere. However, despite this broad consensus and its technical maturity, CCS has not yet been deployed on a scale commensurate with the ambitions articulated a decade ago. Thus, in this paper we review the current state-of-the-art of CO 2 capture, transport, utilisation and storage from a multi-scale perspective, moving from the global to molecular scales. In light of the COP21 commitments to limit warming to less than 2 °C, we extend the remit of this study to include the key negative emissions technologies (NETs) of bioenergy with CCS (BECCS), and direct air capture (DAC). Cognisant of the non-technical barriers to deploying CCS, we reflect on recent experience from the UK's CCS commercialisation programme and consider the commercial and political barriers to the large-scale deployment of CCS. In all areas, we focus on identifying and clearly articulating the key research challenges that could usefully be addressed in the coming decade.
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            Carbon capture and storage: how green can black be?

            The capture of carbon dioxide at the point of emission from coal- or gas-burning power plants is an attractive route to reducing carbon dioxide emissions into the atmosphere. To commercialize carbon capture, as well as transport of liquified carbon dioxide and its storage in exploited oil fields or saline formations, many technological, commercial, and political hurdles remain to be overcome. Urgent action is required if carbon capture and storage is to play a large role in limiting climate change.
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              Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons.

              Nature's photosynthesis uses the sun's energy with chlorophyll in plants as a catalyst to recycle carbon dioxide and water into new plant life. Only given sufficient geological time can new fossil fuels be formed naturally. In contrast, chemical recycling of carbon dioxide from natural and industrial sources as well as varied human activities or even from the air itself to methanol or dimethyl ether (DME) and their varied products can be achieved via its capture and subsequent reductive hydrogenative conversion. The present Perspective reviews this new approach and our research in the field over the last 15 years. Carbon recycling represents a significant aspect of our proposed Methanol Economy. Any available energy source (alternative energies such as solar, wind, geothermal, and atomic energy) can be used for the production of needed hydrogen and chemical conversion of CO(2). Improved new methods for the efficient reductive conversion of CO(2) to methanol and/or DME that we have developed include bireforming with methane and ways of catalytic or electrochemical conversions. Liquid methanol is preferable to highly volatile and potentially explosive hydrogen for energy storage and transportation. Together with the derived DME, they are excellent transportation fuels for internal combustion engines (ICE) and fuel cells as well as convenient starting materials for synthetic hydrocarbons and their varied products. Carbon dioxide thus can be chemically transformed from a detrimental greenhouse gas causing global warming into a valuable, renewable and inexhaustible carbon source of the future allowing environmentally neutral use of carbon fuels and derived hydrocarbon products.
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                Author and article information

                Journal
                ACS Omega
                ACS Omega
                ao
                acsodf
                ACS Omega
                American Chemical Society
                2470-1343
                31 July 2023
                15 August 2023
                : 8
                : 32
                : 29189-29201
                Affiliations
                [1]Radical Innovations Group AB , 65101 Vaasa, Finland
                Author notes
                Author information
                https://orcid.org/0000-0001-7099-2728
                Article
                10.1021/acsomega.3c02441
                10433353
                1fbcd72e-bf56-4db5-a8b9-56ed68771cc6
                © 2023 The Author. Published by American Chemical Society

                Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works ( https://creativecommons.org/licenses/by-nc-nd/4.0/).

                History
                : 11 April 2023
                : 07 July 2023
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                ao3c02441

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