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      Flexible electrodes and supercapacitors for wearable energy storage: a review by category

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          Abstract

          Currently-developed flexible electrodes/supercapacitors are summarized according a hierarchical and detailed classification strategy.

          Supercapacitors are important energy storage devices capable of delivering energy at a very fast rate. With the increasing interest in portable and wearable electronic equipment, various flexible supercapacitors (FSCs) and flexible electrodes (FEs) have been investigated widely and constantly in recent years. Currently-developed FEs/FSCs exhibit myriad physical forms and functional features and form a complicated and extensive system. Herein, we summarize the recent results about FEs/FSCs and present this review by categories. According to different micro-structures and macroscopic patterns, the existing FEs/FSCs can be divided into three types: fiber-like FEs/FSCs; paper-like FEs/FSCs; and three-dimensional porous FEs (and corresponding FSCs). Subsequently each type of the FEs/FSCs is further sub-classified based on their construction rules, and mechanical and electrochemical properties. To our best knowledge, this is the first time such a hierarchical and detailed classification strategy has been propose. We believe it will be beneficial for researchers around the world to understand FEs/FSCs. In addition, we bring up some fresh ideas for the future development of wearable energy storage devices.

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          Most cited references208

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          Preparation and characterization of graphene oxide paper.

          Free-standing paper-like or foil-like materials are an integral part of our technological society. Their uses include protective layers, chemical filters, components of electrical batteries or supercapacitors, adhesive layers, electronic or optoelectronic components, and molecular storage. Inorganic 'paper-like' materials based on nanoscale components such as exfoliated vermiculite or mica platelets have been intensively studied and commercialized as protective coatings, high-temperature binders, dielectric barriers and gas-impermeable membranes. Carbon-based flexible graphite foils composed of stacked platelets of expanded graphite have long been used in packing and gasketing applications because of their chemical resistivity against most media, superior sealability over a wide temperature range, and impermeability to fluids. The discovery of carbon nanotubes brought about bucky paper, which displays excellent mechanical and electrical properties that make it potentially suitable for fuel cell and structural composite applications. Here we report the preparation and characterization of graphene oxide paper, a free-standing carbon-based membrane material made by flow-directed assembly of individual graphene oxide sheets. This new material outperforms many other paper-like materials in stiffness and strength. Its combination of macroscopic flexibility and stiffness is a result of a unique interlocking-tile arrangement of the nanoscale graphene oxide sheets.
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            Laser scribing of high-performance and flexible graphene-based electrochemical capacitors.

            Although electrochemical capacitors (ECs), also known as supercapacitors or ultracapacitors, charge and discharge faster than batteries, they are still limited by low energy densities and slow rate capabilities. We used a standard LightScribe DVD optical drive to do the direct laser reduction of graphite oxide films to graphene. The produced films are mechanically robust, show high electrical conductivity (1738 siemens per meter) and specific surface area (1520 square meters per gram), and can thus be used directly as EC electrodes without the need for binders or current collectors, as is the case for conventional ECs. Devices made with these electrodes exhibit ultrahigh energy density values in different electrolytes while maintaining the high power density and excellent cycle stability of ECs. Moreover, these ECs maintain excellent electrochemical attributes under high mechanical stress and thus hold promise for high-power, flexible electronics.
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              Pseudocapacitive oxide materials for high-rate electrochemical energy storage

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                Author and article information

                Journal
                JMCAET
                Journal of Materials Chemistry A
                J. Mater. Chem. A
                Royal Society of Chemistry (RSC)
                2050-7488
                2050-7496
                2016
                2016
                : 4
                : 13
                : 4659-4685
                Article
                10.1039/C5TA10582J
                1f955e22-d811-4e7c-8db0-411b005395a7
                © 2016
                History

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