Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation.

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Abstract

Molybdenum triiodide complexes bearing various substituted pyridine-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward the reduction of nitrogen gas into ammonia under ambient reaction conditions.

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Journal

Journal ID (iso-abbrev): Dalton Trans

Title: Dalton transactions (Cambridge, England : 2003)

Publisher: Royal Society of Chemistry (RSC)

ISSN (Electronic): 1477-9234

ISSN (Print): 1477-9226

Publication date (Electronic): Mar 05 2019

Volume: 48

Issue: 10

Affiliations

[1 ] Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. ynishiba@sys.t.u-tokyo.ac.jp.

Article

DOI: 10.1039/c8dt04975k

PubMed ID: 30706067

SO-VID: 1eaafc93-1c7b-4ce7-88ec-7372eefb60dd

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