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      Large plasticity in magnesium mediated by pyramidal dislocations

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          Abstract

          Lightweight magnesium alloys are attractive as structural materials for improving energy efficiency in applications such as weight reduction of transportation vehicles. One major obstacle for widespread applications is the limited ductility of magnesium, which has been attributed to c + a dislocations failing to accommodate plastic strain. We demonstrate, using in situ transmission electron microscope mechanical testing, that c + a dislocations of various characters can accommodate considerable plasticity through gliding on pyramidal planes. We found that submicrometer-size magnesium samples exhibit high plasticity that is far greater than for their bulk counterparts. Small crystal size usually brings high stress, which in turn activates more c + a dislocations in magnesium to accommodate plasticity, leading to both high strength and good plasticity.

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          Most cited references26

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          Slip, twinning, and fracture in hexagonal close-packed metals

          M H Yoo (1981)
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            Materials science. Weight loss with magnesium alloys.

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              The origins of high hardening and low ductility in magnesium

              Magnesium is a lightweight structural metal but it exhibits low ductility-connected with unusual, mechanistically unexplained, dislocation and plasticity phenomena-which makes it difficult to form and use in energy-saving lightweight structures. We employ long-time molecular dynamics simulations utilizing a density-functional-theory-validated interatomic potential, and reveal the fundamental origins of the previously unexplained phenomena. Here we show that the key 〈c + a〉 dislocation (where 〈c + a〉 indicates the magnitude and direction of slip) is metastable on easy-glide pyramidal II planes; we find that it undergoes a thermally activated, stress-dependent transition to one of three lower-energy, basal-dissociated immobile dislocation structures, which cannot contribute to plastic straining and that serve as strong obstacles to the motion of all other dislocations. This transition is intrinsic to magnesium, driven by reduction in dislocation energy and predicted to occur at very high frequency at room temperature, thus eliminating all major dislocation slip systems able to contribute to c-axis strain and leading to the high hardening and low ductility of magnesium. Enhanced ductility can thus be achieved by increasing the time and temperature at which the transition from the easy-glide metastable dislocation to the immobile basal-dissociated structures occurs. Our results provide the underlying insights needed to guide the design of ductile magnesium alloys.
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                Author and article information

                Journal
                Science
                Science
                American Association for the Advancement of Science (AAAS)
                0036-8075
                1095-9203
                July 04 2019
                July 05 2019
                July 04 2019
                July 05 2019
                : 365
                : 6448
                : 73-75
                Article
                10.1126/science.aaw2843
                31273119
                1b3f3ba4-21bd-42b8-9628-da3c3f07bec4
                © 2019

                http://www.sciencemag.org/about/science-licenses-journal-article-reuse

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