Green polymerizable deep eutectic solvent (PDES) type conductive paper for origami 3D circuits

Author(s): Li Ren’ai ¹ ^, ² ^, ³ ^, ⁴ , Kaili Zhang ¹ ^, ² ^, ³ ^, ⁴ , Guangxue Chen ¹ ^, ² ^, ³ ^, ⁴ , Bin Su ⁵ ^, ⁶ ^, ⁷ ^, ⁸ , Junfei Tian ¹ ^, ² ^, ³ ^, ⁴ , Minghui He ¹ ^, ² ^, ³ ^, ⁴ ^, ⁹ , Fachuang Lu ¹ ^, ² ^, ³ ^, ⁴ ^, ⁹

Publication date (Electronic): 2018

Journal: Chemical Communications

Publisher: Royal Society of Chemistry (RSC)

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Abstract

We report a green fabrication of conductive paper based on polymerizable deep eutectic solvents and its flexibility to origami electronics.

Abstract

We report a green fabrication of conductive paper based on in situ polymerization of polymerizable deep eutectic solvents (PDESs) through a screen printing process. By pre-designed circuit paths and careful integration, on-demand input/output 3D circuits can be achieved, showing its flexibility to origami electronics.

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Qinghua Zhang, Karine De Oliveira Vigier, Sébastien Royer … (2012)

Within the framework of green chemistry, solvents occupy a strategic place. To be qualified as a green medium, these solvents have to meet different criteria such as availability, non-toxicity, biodegradability, recyclability, flammability, and low price among others. Up to now, the number of available green solvents are rather limited. Here we wish to discuss a new family of ionic fluids, so-called Deep Eutectic Solvents (DES), that are now rapidly emerging in the current literature. A DES is a fluid generally composed of two or three cheap and safe components that are capable of self-association, often through hydrogen bond interactions, to form a eutectic mixture with a melting point lower than that of each individual component. DESs are generally liquid at temperatures lower than 100 °C. These DESs exhibit similar physico-chemical properties to the traditionally used ionic liquids, while being much cheaper and environmentally friendlier. Owing to these remarkable advantages, DESs are now of growing interest in many fields of research. In this review, we report the major contributions of DESs in catalysis, organic synthesis, dissolution and extraction processes, electrochemistry and material chemistry. All works discussed in this review aim at demonstrating that DESs not only allow the design of eco-efficient processes but also open a straightforward access to new chemicals and materials.

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Natural Deep Eutectic Solvents – Solvents for the 21st Century

Ana Rita C Duarte, Ivo Aroso, Rita Craveiro … (2014)

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Paper electronics.

Daniel Tobjörk, Ronald Österbacka (2011)

Paper is ubiquitous in everyday life and a truly low-cost substrate. The use of paper substrates could be extended even further, if electronic applications would be applied next to or below the printed graphics. However, applying electronics on paper is challenging. The paper surface is not only very rough compared to plastics, but is also porous. While this is detrimental for most electronic devices manufactured directly onto paper substrates, there are also approaches that are compatible with the rough and absorptive paper surface. In this review, recent advances and possibilities of these approaches are evaluated and the limitations of paper electronics are discussed. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.