Synthesis and characterization of linear/nonlinear optical properties of graphene oxide and reduced graphene oxide-based zinc oxide nanocomposite

Abstract

In this paper, we aimed to investigate the linear and nonlinear optical properties of GO-ZnO and RGO-ZnO nanocomposites in comparison with pure GO and reduced graphene oxide (RGO). For this purpose, GO, RGO, GO-ZnO, and RGO-ZnO were synthesized and characterized by Fourier transform infrared (FT-IR), Ultraviolet–Visible (UV–Vis) absorption, X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX). XRD and EDX analysis indicated the reduction of GO as well as the successful synthesis of GO-ZnO and RGO-ZnO nanocomposites. The FT-IR spectroscopy showed that absorption bands were at 3340 cm ⁻¹, 1630 cm ⁻¹, 1730 cm ⁻¹ and 480 cm ⁻¹ related to OH, C=C, C=O, and Zn–O stretching vibrations, respectively. The direct band gaps of GO, RGO, GO-ZnO and RGO-ZnO from UV–Vis spectra were at 3.36, 3.18, 3.63 and 3.25 eV, sequentially. Moreover, the third-order nonlinear optical properties were investigated using a z-scan technique with Nd: YAG laser (532 nm, 70 mW). It can be seen that the nonlinear absorption coefficient value \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$(\upbeta )$$\end{document} increased from 5.3 × 10 ^–4 (GO) to 8.4 × 10 ^–3 cm/W (RGO-ZnO). In addition, nonlinear refractive index (n ₂) of the GO, RGO, GO-ZnO, and RGO-ZnO was obtained as 10.9 × 10 ^–10, 14.3 × 10 ^–10, 22.9 × 10 ^–10, and 31.9 × 10 ^–10 cm ²/W respectively.