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Domino carbocationic rearrangement of alpha-[bis(methylthio)methylene]alkyl-2-(3/2-indolyl) cyclopropyl ketones.
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Abstract
Domino carbocationic rearrangement of a number of substituted 3- and 2-indolylcyclopropyl ketones with an alpha-bis(methylthio)methylene group in the presence of various protic/Lewis acids yields a variety of products, mainly the pentaleno fused indoles and the carbazole derivatives.