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      Constitutive modelling of hot deformation behaviour of a CoCrFeMnNi high-entropy alloy

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          ABSTRACT

          Models describing the constitutive flow behaviour of a metallic material are desired for appropriate process design and realization of defect-free components. In this study, constitutive equations based on the hyperbolic-sinusoidal Arrhenius-type model have been developed to define the hot deformation characteristics of a CoCrFeMnNi high-entropy alloy. The experimental true stress-true strain data were generated over a wide temperature (1023–1423 K) and strain rates (10 −3–10 s −1) ranges. The impact of strain rate and temperature on deformation behaviour was further characterized through a temperature compensated strain rate parameter, i.e. Zener-Hollomon parameter. Additionally, a mathematical relation was employed to express the influence of various material constants on true-strain ranging from 0.2 to 0.75. Typical third order polynomial relations were found to be appropriate to fit the true-strain dependency of these material constants. The accuracy of the developed constitutive equations was evaluated by using the average absolute relative error (AARE) and correlation coefficient (R); the obtained values were 7.63% and 0.9858, respectively, suggesting reasonable predictions. These results demonstrate that the developed constitutive equations can predict the flow stress behaviour of the alloy with a good accuracy over a wide range of temperature and strain rate conditions and for large strains.

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          A critical review of high entropy alloys and related concepts

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            Microstructures and properties of high-entropy alloys

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              A fracture-resistant high-entropy alloy for cryogenic applications.

              High-entropy alloys are equiatomic, multi-element systems that can crystallize as a single phase, despite containing multiple elements with different crystal structures. A rationale for this is that the configurational entropy contribution to the total free energy in alloys with five or more major elements may stabilize the solid-solution state relative to multiphase microstructures. We examined a five-element high-entropy alloy, CrMnFeCoNi, which forms a single-phase face-centered cubic solid solution, and found it to have exceptional damage tolerance with tensile strengths above 1 GPa and fracture toughness values exceeding 200 MPa·m(1/2). Furthermore, its mechanical properties actually improve at cryogenic temperatures; we attribute this to a transition from planar-slip dislocation activity at room temperature to deformation by mechanical nanotwinning with decreasing temperature, which results in continuous steady strain hardening. Copyright © 2014, American Association for the Advancement of Science.
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                Author and article information

                Journal
                Sci Technol Adv Mater
                Sci Technol Adv Mater
                TSTA
                tsta20
                Science and Technology of Advanced Materials
                Taylor & Francis
                1468-6996
                1878-5514
                2020
                13 January 2020
                : 21
                : 1
                : 43-55
                Affiliations
                [a ]Materials Science and Environmental Engineering, Tampere University , Tampere, Finland
                [b ]Materials and Mechanical Engineering, Centre for Advanced Steels Research, University of Oulu , Oulu, Finland
                Author notes
                CONTACT Madan Patnamsetty madan.patnamsetty@ 123456tuni.fi Materials Science and Environmental Engineering, Tampere University , 33720, Tampere, Finland
                Author information
                http://orcid.org/0000-0002-1801-430X
                http://orcid.org/0000-0002-3175-0838
                http://orcid.org/0000-0002-4679-493X
                http://orcid.org/0000-0002-8529-0160
                Article
                1714476
                10.1080/14686996.2020.1714476
                7033692
                32158507
                15a450f9-2931-469d-9186-1176f8edc97d
                © 2020 The Author(s). Published by National Institute for Materials Science in partnership with Taylor & Francis Group.

                This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial License ( http://creativecommons.org/licenses/by-nc/4.0/), which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                : 31 October 2019
                : 09 January 2020
                : 09 January 2020
                Page count
                Figures: 9, Tables: 1, References: 49, Pages: 13
                Categories
                Engineering and Structural materials

                high entropy alloys (heas),constitutive equations,zener–holloman parameter (z),face centred cubic (fcc),dynamic recrystallization (drx),high-temperature flow behaviour,400 modeling/simulations,constitutive modelling,106 metallic materials

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