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      Spheroidisation of iron powder in a microwave plasma reactor

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          Abstract

          Plasma-assisted spheroidisation of metal powders offers several technical advantages with respect to both the ease of materials handling and powder-metallurgical item manufacturing. Advantages include improved flowability, increased powder packing density, elimination of internal component cavities and fractures, changes in morphology resulting in decreased friction between particles and contamination during pneumatic transport and enhanced particle purity. In this empirical study, spherical iron particles were produced using a microwave plasma operating at atmospheric pressure and characterized using optical microscopy and SEM techniques. Iron powders were fed into the system at fixed operating conditions, resulting in particles with spherical structures. The theoretical estimate of the time required for melting to occur is 1.6 ms, an order of magnitude smaller than the actual residence time.

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          Plasma Chemistry

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            Entropy-driven formation of large icosahedral colloidal clusters by spherical confinement.

            Icosahedral symmetry, which is not compatible with truly long-range order, can be found in many systems, such as liquids, glasses, atomic clusters, quasicrystals and virus-capsids. To obtain arrangements with a high degree of icosahedral order from tens of particles or more, interparticle attractive interactions are considered to be essential. Here, we report that entropy and spherical confinement suffice for the formation of icosahedral clusters consisting of up to 100,000 particles. Specifically, by using real-space measurements on nanometre- and micrometre-sized colloids, as well as computer simulations, we show that tens of thousands of hard spheres compressed under spherical confinement spontaneously crystallize into icosahedral clusters that are entropically favoured over the bulk face-centred cubic crystal structure. Our findings provide insights into the interplay between confinement and crystallization and into how these are connected to the formation of icosahedral structures.
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              Plasma Chemistry

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                Author and article information

                Contributors
                Role: ND
                Role: ND
                Role: ND
                Role: ND
                Role: ND
                Journal
                jsaimm
                Journal of the Southern African Institute of Mining and Metallurgy
                J. S. Afr. Inst. Min. Metall.
                The Southern African Institute of Mining and Metallurgy (Johannesburg, Gauteng, South Africa )
                2225-6253
                2411-9717
                October 2016
                : 116
                : 10
                : 941-946
                Affiliations
                [01] Pelindaba North West Province orgnameSouth African Nuclear Energy Corporation (NECSA) SOC Ltd South Africa
                [02] Pretoria orgnameUniversity of Pretoria orgdiv1Faculty of Engineering, Built Environment and Information Technology orgdiv2Department of Chemical Engineering South Africa
                Article
                S2225-62532016001000010
                10.17159/2411-9717/2016/v116n10a8
                159c82f7-00a0-4c34-b33b-88062939f913

                This work is licensed under a Creative Commons Attribution 4.0 International License.

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                Page count
                Figures: 0, Tables: 0, Equations: 0, References: 24, Pages: 6
                Product

                SciELO South Africa


                iron powder,spheroidisation,microwave plasma
                iron powder, spheroidisation, microwave plasma

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