Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries

Author(s): Zhenzhen Wu ¹ ^, ² ^, ³ ^, ³ ^, ⁴ , Jian Xie ¹ ^, ² ^, ³ ^, ³ , Zhichuan J. Xu ¹ ^, ² ^, ³ ^, ³ , Shanqing Zhang ⁴ ^, ⁵ ^, ⁶ ^, ⁷ ^, ⁸ , Qichun Zhang ¹ ^, ² ^, ³ ^, ³

Publication date (Electronic): 2019

Journal: Journal of Materials Chemistry A

Publisher: Royal Society of Chemistry (RSC)

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Abstract

Recent progress in the usage of metal organic polymers (coordination polymers (CPs), metal–organic frameworks (MOFs), Prussian blue and Prussian blue analogues (PBAs)) as electrodes in Li/Na rechargeable batteries has been reviewed.

Abstract

Metal organic polymers (MOPs), including metal coordination polymers (CPs, one-dimensional), metal–organic frameworks (MOFs, two-/three-dimensional), Prussian blue (PB) and Prussian blue analogues (PBAs), have recently emerged as promising electrochemically active materials for energy storage and conversion systems. Due to the tunability of their composition and the structural versatility, diverse electrochemical behaviors for multi-electron reactions, fast-ion diffusion, and small volume change of electrodes could be achieved upon charging and discharging. Because of these superiorities, MOPs are considered as effective substitutes for future advanced energy storage systems. Here, we summarize the recent progress in pristine MOPs as electrode candidates for rechargeable lithium and sodium ion batteries. The working mechanisms and strategies for enhancing the electrochemical performance in related advanced electrochemical energy storage (EES) applications are also highlighted in this review.

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The chemistry and applications of metal-organic frameworks.

Hiroyasu Furukawa, Kyle E. Cordova, Michael O'Keeffe … (2013)

Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.