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      Water‐Resistant Subwavelength Perovskite Lasing from Transparent Silica‐Based Nanocavity

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          Abstract

          Great research efforts are devoted to exploring the miniaturization of chip‐scale coherent light sources possessing excellent lasing performance. Despite the indispensable role in Si photonics, SiO 2 is generally considered not contributing to the starting up and operation of integrated lasers. Here, this work demonstrates an extraordinary‐performance subwavelength‐scale perovskite vertical cavity laser with all‐transparent SiO 2 cavity, whose cavity is ultra‐simple and composed of only two parallel SiO 2 plates. By introducing a ligand‐assisted thermally co‐evaporation strategy, highly luminescent perovskite film with high reproducibility and excellent optical gain is grown directly on SiO 2. Benefitting from their high‐refractive‐index contrast, low‐threshold, high‐quality factor, and single‐mode lasing is achieved in subwavelength range of ≈120 nm, and verified by long‐range coherence distance (115.6 µm) and high linear polarization degree (82%). More importantly, the subwavelength perovskite laser device could operate in water for 20 days without any observable degradation, exhibiting ultra‐stable water‐resistant performance. These findings would provide a simple but robust and reliable strategy for the miniaturized on‐chip lasers compatible with Si photonics.

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          Efficient planar heterojunction perovskite solar cells by vapour deposition.

          Many different photovoltaic technologies are being developed for large-scale solar energy conversion. The wafer-based first-generation photovoltaic devices have been followed by thin-film solid semiconductor absorber layers sandwiched between two charge-selective contacts and nanostructured (or mesostructured) solar cells that rely on a distributed heterojunction to generate charge and to transport positive and negative charges in spatially separated phases. Although many materials have been used in nanostructured devices, the goal of attaining high-efficiency thin-film solar cells in such a way has yet to be achieved. Organometal halide perovskites have recently emerged as a promising material for high-efficiency nanostructured devices. Here we show that nanostructuring is not necessary to achieve high efficiencies with this material: a simple planar heterojunction solar cell incorporating vapour-deposited perovskite as the absorbing layer can have solar-to-electrical power conversion efficiencies of over 15 per cent (as measured under simulated full sunlight). This demonstrates that perovskite absorbers can function at the highest efficiencies in simplified device architectures, without the need for complex nanostructures.
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            Metal-halide perovskites for photovoltaic and light-emitting devices.

            Metal-halide perovskites are crystalline materials originally developed out of scientific curiosity. Unexpectedly, solar cells incorporating these perovskites are rapidly emerging as serious contenders to rival the leading photovoltaic technologies. Power conversion efficiencies have jumped from 3% to over 20% in just four years of academic research. Here, we review the rapid progress in perovskite solar cells, as well as their promising use in light-emitting devices. In particular, we describe the broad tunability and fabrication methods of these materials, the current understanding of the operation of state-of-the-art solar cells and we highlight the properties that have delivered light-emitting diodes and lasers. We discuss key thermal and operational stability challenges facing perovskites, and give an outlook of future research avenues that might bring perovskite technology to commercialization.
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              Optical gain and stimulated emission in nanocrystal quantum dots.

              The development of optical gain in chemically synthesized semiconductor nanoparticles (nanocrystal quantum dots) has been intensely studied as the first step toward nanocrystal quantum dot lasers. We examined the competing dynamical processes involved in optical amplification and lasing in nanocrystal quantum dots and found that, despite a highly efficient intrinsic nonradiative Auger recombination, large optical gain can be developed at the wavelength of the emitting transition for close-packed solids of these dots. Narrowband stimulated emission with a pronounced gain threshold at wavelengths tunable with the size of the nanocrystal was observed, as expected from quantum confinement effects. These results unambiguously demonstrate the feasibility of nanocrystal quantum dot lasers.
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                Author and article information

                Contributors
                Journal
                Advanced Materials
                Advanced Materials
                Wiley
                0935-9648
                1521-4095
                December 2023
                November 20 2023
                December 2023
                : 35
                : 52
                Affiliations
                [1 ] State Key Laboratory of High Field Laser Physics and CAS Center for Excellence in Ultra‐Intense Laser Science Shanghai Institute of Optics and Fine Mechanics Chinese Academy of Sciences Shanghai 201800 China
                [2 ] Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 China
                [3 ] Wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 China
                [4 ] Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences Hangzhou 310024 China
                Article
                10.1002/adma.202306102
                0a425a3b-2517-4584-bc85-8bcbc762024a
                © 2023

                http://onlinelibrary.wiley.com/termsAndConditions#vor

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