Catalytic hydrogenation of carbon dioxide using Ir(III)-pincer complexes.

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Abstract

Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3,500,000 and a turnover frequency of 150,000 h(-1), both of which are the highest values reported to date.

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Journal

Journal ID (iso-abbrev): J Am Chem Soc

Title: Journal of the American Chemical Society

Publisher: American Chemical Society (ACS)

ISSN (Electronic): 1520-5126

ISSN (Print): 0002-7863

Publication date (Electronic): Oct 14 2009

Volume: 131

Issue: 40

Affiliations

[1 ] Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

Article

DOI: 10.1021/ja903574e

PubMed ID: 19775157

SO-VID: 0986769e-793f-4ad9-9348-f95a6c63e149

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