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      Control of the near-field radiative heat transfer between graphene-coated nanoparticle metasurfaces

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          Abstract

          The control of near-field radiative heat transfer (NFRHT) between two metasurfaces can be achieved by manipulating the geometric and dielectric parameters of their components. Based on a 2D effective medium approximation, we describe the dielectric response of each metasurface composed of graphene-coated nanoparticles (GCNPs) on a 2D square lattice as a homogeneous uniaxial film. Wrapping Drude-like nanoparticles (NPs) with graphene enhances the effective plasmonic response of metasurfaces by significantly broadening the frequency range in which surface and hyperbolic waves can be excited by thermal photons. Consequently, the NFRHT between GCNP metasurfaces improves that observed between uncoated Drude-like nanoparticle arrays. We found that the heat flux (Q) grows with increasing metasurface packing fraction (PF) and is also sensitive to GCNP size. By tuning the graphene chemical potential \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$(\mu )$$\end{document} , Q reaches a maximum improvement of \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$88\%$$\end{document} for \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\mu \approx 0.1$$\end{document} eV with cores made of Drude-like material, while using cores made of the polar dielectric SiC, Q increases up to \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$226\%$$\end{document} for \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\mu \approx 0.45$$\end{document} eV. Our results show that, in addition to the geometric control achieved with uncoated NP arrays, the tunable optical properties of the graphene shell allow dynamic control of the heat flux, expanding the possibilities for NFRHT engineering offered by GCNP metasurfaces.

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          Theory of Radiative Heat Transfer between Closely Spaced Bodies

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            Surface phonon polaritons mediated energy transfer between nanoscale gaps.

            Surface phonon polaritons are electromagnetic waves that propagate along the interfaces of polar dielectrics and exhibit a large local-field enhancement near the interfaces at infrared frequencies. Theoretical calculations show that such surface waves can lead to breakdown of the Planck's blackbody radiation law in the near field. Here, we experimentally demonstrate that surface phonon polaritons dramatically enhance energy transfer between two surfaces at small gaps by measuring radiation heat transfer between a microsphere and a flat surface down to 30 nm separation. The corresponding heat transfer coefficients at nanoscale gaps are 3 orders of magnitude larger than that of the blackbody radiation limit. The high energy flux can be exploited to develop new radiative cooling and thermophotovoltaic technologies.
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              Thermal radiation scanning tunnelling microscopy.

              In standard near-field scanning optical microscopy (NSOM), a subwavelength probe acts as an optical 'stethoscope' to map the near field produced at the sample surface by external illumination. This technique has been applied using visible, infrared, terahertz and gigahertz radiation to illuminate the sample, providing a resolution well beyond the diffraction limit. NSOM is well suited to study surface waves such as surface plasmons or surface-phonon polaritons. Using an aperture NSOM with visible laser illumination, a near-field interference pattern around a corral structure has been observed, whose features were similar to the scanning tunnelling microscope image of the electronic waves in a quantum corral. Here we describe an infrared NSOM that operates without any external illumination: it is a near-field analogue of a night-vision camera, making use of the thermal infrared evanescent fields emitted by the surface, and behaves as an optical scanning tunnelling microscope. We therefore term this instrument a 'thermal radiation scanning tunnelling microscope' (TRSTM). We show the first TRSTM images of thermally excited surface plasmons, and demonstrate spatial coherence effects in near-field thermal emission.
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                Author and article information

                Contributors
                shunashi@fisica.unam.mx
                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group UK (London )
                2045-2322
                7 August 2024
                7 August 2024
                2024
                : 14
                : 18316
                Affiliations
                [1 ]Instituto de Física, Universidad Nacional Autónoma de México, ( https://ror.org/01tmp8f25) Apartado Postal 20-364, 01000 Mexico, Mexico
                [2 ]Tecnológico Nacional de México/ ITS de Poza Rica, Luis Donaldo Colosio Murrieta S/N, Arroyo del Maíz, 93230 Poza Rica, Mexico
                [3 ]Facultad de Ciencias de la Electrónica, Benemérita Universidad Autónoma de Puebla, ( https://ror.org/03p2z7827) Apartado Postal J-48, 72570 Puebla, Mexico
                Article
                69023
                10.1038/s41598-024-69023-0
                11306795
                39112718
                017caea9-84e6-44dd-bab7-d3ddaf10d5bf
                © The Author(s) 2024

                Open Access This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License, which permits any non-commercial use, sharing, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if you modified the licensed material. You do not have permission under this licence to share adapted material derived from this article or parts of it. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by-nc-nd/4.0/.

                History
                : 31 May 2024
                : 30 July 2024
                Funding
                Funded by: UNAM DGAPA PAPIIT
                Award ID: TA100724
                Award Recipient :
                Funded by: FundRef http://dx.doi.org/10.13039/100012725, Tecnológico Nacional de México;
                Award ID: 15279.22-PD
                Award Recipient :
                Categories
                Article
                Custom metadata
                © Springer Nature Limited 2024

                Uncategorized
                nanoscale materials,metamaterials
                Uncategorized
                nanoscale materials, metamaterials

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