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      Current status and pillars of direct air capture technologies

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          Summary

          Climate change calls for adaptation of negative emission technologies such as direct air capture (DAC) of carbon dioxide (CO 2) to lower the global warming impacts of greenhouse gases. Recently, elevated global interests to the DAC technologies prompted implementation of new tax credits and new policies worldwide that motivated the existing DAC companies and prompted the startup boom. There are presently 19 DAC plants operating worldwide, capturing more than 0.01 Mt CO 2/year. DAC active plants capturing in average 10,000 tons of CO 2 annually are still in their infancy and are expensive. DAC technologies still need to improve in three areas: 1) Contactor, 2) Sorbent, and 3) Regeneration to drive down the costs. Technology-based economic development in all three areas are required to achieve <$100/ton of CO 2 which makes DAC economically viable. Current DAC cost is about 2–6 times higher than the desired cost and depends highly on the source of energy used. In this review, we present the current status of commercial DAC technologies and elucidate the five pillars of technology including capture technologies, their energy demand, final costs, environmental impacts, and political support. We explain processing steps for liquid and solid carbon capture technologies and indicate their specific energy requirements. DAC capital and operational cost based on plant power energy sources, land and water needs of DAC are discussed in detail. At 0.01 Mt CO 2/year capture capacity, DAC alone faces a challenge to meet the rates of carbon capture described in the goals of the Paris Agreement with 1.5–2°C of global warming. However, DAC may partially help to offset difficult to avoid annual emissions from concrete (∼8%), transportation (∼24%), iron-steel industry (∼11%), and wildfires (∼0.8%).

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          Chemical engineering; Energy sustainability; Environmental technology; Mechanical engineering

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          Temporary reduction in daily global CO2 emissions during the COVID-19 forced confinement

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            Direct Capture of CO2 from Ambient Air.

            The increase in the global atmospheric CO2 concentration resulting from over a century of combustion of fossil fuels has been associated with significant global climate change. With the global population increase driving continued increases in fossil fuel use, humanity's primary reliance on fossil energy for the next several decades is assured. Traditional modes of carbon capture such as precombustion and postcombustion CO2 capture from large point sources can help slow the rate of increase of the atmospheric CO2 concentration, but only the direct removal of CO2 from the air, or "direct air capture" (DAC), can actually reduce the global atmospheric CO2 concentration. The past decade has seen a steep rise in the use of chemical sorbents that are cycled through sorption and desorption cycles for CO2 removal from ultradilute gases such as air. This Review provides a historical overview of the field of DAC, along with an exhaustive description of the use of chemical sorbents targeted at this application. Solvents and solid sorbents that interact strongly with CO2 are described, including basic solvents, supported amine and ammonium materials, and metal-organic frameworks (MOFs), as the primary classes of chemical sorbents. Hypothetical processes for the deployment of such sorbents are discussed, as well as the limited array of technoeconomic analyses published on DAC. Overall, it is concluded that there are many new materials that could play a role in emerging DAC technologies. However, these materials need to be further investigated and developed with a practical sorbent-air contacting process in mind if society is to make rapid progress in deploying DAC as a means of mitigating climate change.
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              Negative emissions—Part 2: Costs, potentials and side effects

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                Author and article information

                Contributors
                Journal
                iScience
                iScience
                iScience
                Elsevier
                2589-0042
                28 February 2022
                15 April 2022
                28 February 2022
                : 25
                : 4
                : 103990
                Affiliations
                [1 ]Department of Electrical and Computer Engineering, University of California Riverside, Riverside, CA, USA
                [2 ]Department of Chemistry, University of California Riverside, Riverside, CA, USA
                [3 ]Materials Science and Engineering, University of California Riverside, Riverside, CA, USA
                Author notes
                []Corresponding author mihri@ 123456ece.ucr.edu
                Article
                S2589-0042(22)00260-7 103990
                10.1016/j.isci.2022.103990
                8927912
                35310937
                015d1147-54d9-49fa-879c-134d8212aab6
                © 2022 The Author(s)

                This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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                chemical engineering,energy sustainability,environmental technology,mechanical engineering

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