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      Instantaneous High‐Resolution Visual Imaging of Latent Fingerprints in Water Using Color‐Tunable AIE Pincer Complexes

      1 , 1 , 1 , 2 , 3
      Advanced Materials
      Wiley

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          Abstract

          Instant visualization of latent fingerprints is developed by using a series of water‐soluble terpyridine zinc complexes as aggregation‐induced emission probes in pure water, under UV light or ambient sunlight. By simply soaking, or spraying with an aqueous solution of the probe, bright yellow fluorescence images with high contrast and resolution are readily developed on various surfaces including tinfoil, glass, paper, steel, leather, and ceramic tile. Remarkably, latent fingerprints can be visualized within seconds including details of whorl and sweat pores. The color of emission can be tuned from blue to orange by modifying the pincer ligands, allowing direct imaging under sunlight. These inexpensive, water‐resistant, and color‐tunable probes provide a practical approach for latent fingerprints recording and analysis, security protection, as well as criminal investigation in different scenarios.

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          Most cited references75

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          Aggregation‐Induced Emission: New Vistas at the Aggregate Level

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            Supramolecular materials based on AIE luminogens (AIEgens): construction and applications

            This review presents comprehensive discussions on the recent development in supramolecular materials based on luminogens with aggregation-induced emission (AIE) characteristics. The emergence of aggregation-induced emission luminogens (AIEgens) has significantly stimulated the development of luminescent supramolecular materials because their strong emissions in the aggregated state have resolved the notorious obstacle of the aggregation-caused quenching (ACQ) effect, thereby enabling AIEgen-based supramolecular materials to have a promising prospect in the fields of luminescent materials, sensors, bioimaging, drug delivery, and theranostics. Moreover, in contrast to conventional fluorescent molecules, the configuration of AIEgens is highly twisted in space. Investigating AIEgens and the corresponding supramolecular materials provides fundamental insights into the self-assembly of nonplanar molecules, drastically expands the building blocks of supramolecular materials, and pushes forward the frontiers of supramolecular chemistry. In this review, we will summarize the basic concepts, seminal studies, recent trends, and perspectives in the construction and applications of AIEgen-based supramolecular materials with the hope to inspire more interest and additional ideas from researchers and further advance the development of supramolecular chemistry.
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              Aggregation-induced emission: fundamental understanding and future developments

              In-depth discussion on recent progress of fundamental understanding of AIE mechanisms, identifying the existing challenges and opportunities for future developments. Since the introduction of the concept of aggregation-induced emission (AIE) in 2001, many research groups have become involved in AIE research. Aggregation-induced emission luminogens (AIEgens) have emerged as a novel type of advanced material with excellent performance in various fields. Much effort has been devoted to determining the AIE mechanism(s) by theoreticians and experimentalists. Restriction of intramolecular motion has been recognized as the general working mechanism of AIE, but the mechanims of some AIE systems still remain unclear. In this focus article, the progress of the fundamental understanding of the AIE mechanism is reviewed and the future developments in AIE research are discussed. The goal is to provide a brief yet insightful introduction and interpretation of the subject to both new and experienced AIE researchers.
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                Author and article information

                Contributors
                Journal
                Advanced Materials
                Advanced Materials
                Wiley
                0935-9648
                1521-4095
                September 2022
                July 20 2022
                September 2022
                : 34
                : 35
                Affiliations
                [1 ] Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Department of Chemistry Fudan University 2005 Songhu Road Shanghai 200438 P. R. China
                [2 ] State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 P. R. China
                [3 ] Green Catalysis Center and College of Chemistry Zhengzhou University 100 Kexue avenue Zhengzhou 450001 P. R. China
                Article
                10.1002/adma.202202540
                09cdfbdf-62b3-4314-a323-9e55cae4f296
                © 2022

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