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      Tuning the properties of cobalt ferrite: a road towards diverse applications

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          Abstract

          Cobalt ferrite nanostructures have been established to be promising material for future aspects.

          Abstract

          Cobalt ferrite has gained great scientific interest because of its unique properties and exceptionally promising applications. A large number of synthetic methods, such as sol–gel auto-combustion method, co-precipitation method, ball milling method, microemulsion method, polyol method, etc. have been used for its synthesis. Synthetic methodologies and heat treatment given to the sample strongly influence the particle size of the synthesized ferrite, which in turn determines its properties. In addition, the properties of cobalt ferrite can be altered by different chemical modifications such as substituting one or more ions from the lattice with some other metal ion, modifying the reaction conditions, compositing with different inorganic matrices etc. The most prominent influence on the properties of ferrites is exerted by variation in cation distribution. Among all the factors the major influence on the cation distribution is laid by doping. Guest metal ions according to their site preference occupy different lattice sites, thereby, changing the structural, magnetic, electrical and the catalytic properties of cobalt ferrite. In this review, we summarize the significant developments involving modifications in synthesis and properties of cobalt ferrite. This review also highlights the advances in the applications of cobalt ferrite in the fields of catalysis, biomedicine and sensors.

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          Most cited references238

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          Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe 2 O 4 (M = Co, Cu, Mn, and Zn) as heterogeneous catalysts in the water

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            Shape control and associated magnetic properties of spinel cobalt ferrite nanocrystals.

            By combining nonhydrolytic reaction with seed-mediated growth, high-quality and monodisperse spinel cobalt ferrite, CoFe(2)O(4), nanocrystals can be synthesized with a highly controllable shape of nearly spherical or almost perfectly cubic. The shape of the nanocrystals can also be reversibly interchanged between spherical and cubic morphology through controlling nanocrystal growth rate. Furthermore, the magnetic studies show that the blocking temperature, saturation, and remanent magnetization of nanocrystals are solely determined by the size regardless the spherical or cubic shape. However, the shape of the nanocrystals is a dominating factor for the coercivity of nanocrystals due to the effect of surface anisotropy. Such magnetic nanocrystals with distinct shapes possess tremendous potentials in fundamental understanding of magnetism and in technological applications of magnetic nanocrystals for high-density information storage.
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              The role of cobalt ferrite magnetic nanoparticles in medical science.

              The nanotechnology industry is rapidly growing and promises that the substantial changes that will have significant economic and scientific impacts be applicable to a wide range of areas, such as aerospace engineering, nano-electronics, environmental remediation and medical healthcare. In this area, cobalt ferrite nanoparticles have been regarded as one of the competitive candidates because of their suitable physical, chemical and magnetic properties like the high anisotropy constant, high coercivity and high Curie temperature, moderate saturation magnetization and ease of synthesis. This paper introduces the magnetic properties, synthesis methods and some medical applications, including the hyperthermia, magnetic resonance imaging (MRI), magnetic separation and drug delivery of cobalt ferrite nanoparticles.
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                Author and article information

                Journal
                RSCACL
                RSC Advances
                RSC Adv.
                Royal Society of Chemistry (RSC)
                2046-2069
                2016
                2016
                : 6
                : 100
                : 97694-97719
                Affiliations
                [1 ]Department of Chemistry
                [2 ]Panjab University
                [3 ]Chandigarh
                [4 ]India
                Article
                10.1039/C6RA21224G
                f8bb0ce9-c921-4648-94d5-8f6fd4058a7b
                © 2016
                History

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