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      N-[(3 RS,4 SR)-1-Benzyl-4-methyl­piperi­din-3-yl]-1-(4-methylphenyl­sulfonyl)-5-nitro-1 H-pyrrolo­[2,3- b]pyridin-4-amine

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          Abstract

          The structure of the title compound, C 27H 29N 5O 4S, displays an intra­molecular N—H⋯O hydrogen bond. The pyrrolo­[2,3- b]pyridine core makes a dihedral angle of 85.5 (4)° with the benzyl residue and a dihedral angle of 89.4 (9)° with the tosyl ring. The nitro group is slightly twisted out of the plane of the planar pyrrolo­pyridine system [(—N—)C—C—N—O torsion angle = −4.61 (18)° and (—NH—)C—C—N—O = −6.46 (18)°].

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          Author and article information

          Journal
          Acta Crystallogr Sect E Struct Rep Online
          Acta Crystallogr Sect E Struct Rep Online
          Acta Cryst. E
          Acta Crystallographica Section E: Structure Reports Online
          International Union of Crystallography
          1600-5368
          01 October 2012
          26 September 2012
          26 September 2012
          : 68
          : Pt 10 ( publisher-idID: e121000 )
          : o3000
          Affiliations
          [a ]Eberhard-Karls-University Tübingen, Auf der Morgenstelle 8, 72076 Tübingen, Germany
          [b ]University Mainz, Institute of Organic Chemistry, Duesbergweg 10-14, 55099 Mainz, Germany
          Author notes
          Article
          bt6839 ACSEBH S160053681203961X
          10.1107/S160053681203961X
          3470359
          23125772
          3c1399dc-81e9-4786-ad7b-619ff8f6fcc0
          © Pfaffenrot et al. 2012

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          : 17 September 2012
          : 18 September 2012
          Categories
          Organic Papers

          Materials characterization
          Materials characterization

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