Emitted from the oceans, iodine-bearing molecules are ubiquitous in the atmosphere and a source of new atmospheric aerosol particles of potentially global significance. However, its inclusion in atmospheric models is hindered by a lack of understanding of the first steps of the photochemical gas-to-particle conversion mechanism. Our laboratory results show that under a high humidity and low HO x regime, the recently proposed nucleating molecule (iodic acid, HOIO 2) does not form rapidly enough, and gas-to-particle conversion proceeds by clustering of iodine oxides (I xO y), albeit at slower rates than under dryer conditions. Moreover, we show experimentally that gas-phase HOIO 2 is not necessary for the formation of HOIO 2-containing particles. These insights help to explain new particle formation in the relatively dry polar regions and, more generally, provide for the first time a thermochemically feasible molecular mechanism from ocean iodine emissions to atmospheric particles that is currently missing in model calculations of aerosol radiative forcing.
“How iodine-bearing molecules contribute to atmospheric aerosol formation is not well understood. Here, the authors provide a new gas-to-particle conversion mechanism and show that clustering of iodine oxides is an essential component of this process while previously proposed iodic acid does not play a large role.”