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      Recent advances in process engineering and upcoming applications of metal-organic frameworks.

      Coordination Chemistry Reviews
      Elsevier BV
      PEI, Polyetherimide, PPC, Polypropylene/polycarbonate, DRIFTS, Diffuse reflectance infrared fourier transform spectroscopy, MOGs, Metal-organic gels, MB, methylene blue, sXAS, Soft X-ray absorption spectroscopy, Dispersion, Fn, Fusobacterium nucleatum, PEG-CCM, polyethylene-glycol-modified mono-functional curcumin, hXAS, Hard X-ray absorption spectroscopy, MRA, mesoporous ρ-alumina, 2,4-DNT, 2,4-dinitrotoluene, E. Coli, Escherichia coli, ZIF, zeolitic imidazolate framework, XPS, X-ray photoelectron spectroscopy, PANI, Polyaniline, MRSA, Methicillin-resistant staphylococcus aureus, PXRD, Powder x-ray diffraction, ECS, Extrusion-crushing-sieving, MVTR, Moisture vapor transport rate, FT-IR, Fourier-transform infrared spectroscopy, WLED, White light emitting diode, PS, Polystyrene, PAN, Polyacrylonitrile, SIBs, Sodium-ion batteries, EDLCs, Electrochemical double-layer capacitors, Mass production, 4-NP, 4-nitrophenol, CWC, Chemical weapons convention, Metal–organic framework, NMR, Nuclear magnetic resonance, WHO, World health organization, EXAFS, Extended X-ray absorption fine structure, EPA, Environmental protection agency, VOC, Volatile organic compound, PVF, Polyvinylformal, NMP, N-methyl-2-pyrrolidone, PSM, Post-synthetic modification, UPS, Ultraviolet photoelectron spectroscopy, TNT, 2,4,6-trinitrotoluene, LOD, Limit of detection, PVA, Polyvinyl alcohol, CNF, Cellulose nanofiber, SSEs, Solid-state electrolytes, TNP, 2,4,6-trinitrophenol, ABS, acrylonitril-butadiene-styrene, TIPS-HoP, Thermally induced phase separation-hot pressing, PVC, Polyvinylchloride, MIM, Metal-insulator–metal, TEA, Triethylamine, Future applications, PVB, Polyvinyl Butyral, Shaping, PEMFCs, Proton-exchange membrane fuel cells, BET, Brunauer–Emmett–Teller, GC–MS, Gas chromatography–mass spectrometry, DEF, N,N-Diethyl formamide, STY, space–time yield, grams of MOF per cubic meter of reaction mixture per day of synthesis, PM, Particulate matter, DMA, Dimethylacetamide, GRGDS, Gly-Arg-Gly-Asp-Ser, CWA, Chemical warfare agent, POM, Polyoxometalate, SEM, Scanning electron microscope, CA, Cellulose-acetate, MOF, metal–organic framework, DIFP, Diisopropylfluorophosphate, ILDs, Interlayer dielectrics, ITRS, International technology roadmap for semiconductors, DMF, N,N-Dimethyl formamide, MMP, Methyl methylphosphonate, SCXRD, Single-crystal X-ray diffraction, LMOF, Luminescent metal–organic framework, LED, Light-emitting diode, CNG, compressed natural gas, CVD, Chemical vapor deposition, DMMP, Dimethyl methylphosphonate, SBU, Secondary building unit, SALI, Solvent assisted ligand incorporation, CEES, 2-Chloroethyl ethyl sulfide, MIC, Minimum inhibitory concentration, LIBs, Lithium-ion batteries, ROS, Reactive oxygen species, MBC, Minimum bactericidal concentration, RDX, 1,3,5-trinitro-1,3,5-triazinane, Pg, Porphyromonas gingivalis, CIE, Commission international ed’Eclairage, DLS, Dynamic light scattering, DDM, n-dodecyl β-D-maltoside, DFT, Density functional theory, DFP, Diisopropyl fluorophosphate, Commercialization, DCP, Diethylchlorophosphonate

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          Abstract

          Progress in metal-organic frameworks (MOFs) has advanced from fundamental chemistry to engineering processes and applications, resulting in new industrial opportunities. The unique features of MOFs, such as their permanent porosity, high surface area, and structural flexibility, continue to draw industrial interest outside the traditional MOF field, both to solve existing challenges and to create new businesses. In this context, diverse research has been directed toward commercializing MOFs, but such studies have been performed according to a variety of individual goals. Therefore, there have been limited opportunities to share the challenges, goals, and findings with most of the MOF field. In this review, we examine the issues and demands for MOF commercialization and investigate recent advances in MOF process engineering and applications. Specifically, we discuss the criteria for MOF commercialization from the views of stability, producibility, regulations, and production cost. This review covers progress in the mass production and formation of MOFs along with future applications that are not currently well known but have high potential for new areas of MOF commercialization.

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          Metal-organic framework materials as chemical sensors.

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            Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.

            The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applications is included. A general conclusion and a perspective on the current limitations and recommended future research directions of lithium metal batteries are presented. The review concludes with an attempt at summarizing the theoretical and experimental achievements in lithium metal anodes and endeavors to realize the practical applications of lithium metal batteries.
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              Design and synthesis of an exceptionally stable and highly porous metal-organic framework

                Bookmark

                Author and article information

                Journal
                32981945
                7500364
                10.1016/j.ccr.2020.213544

                PEI, Polyetherimide,PPC, Polypropylene/polycarbonate,DRIFTS, Diffuse reflectance infrared fourier transform spectroscopy,MOGs, Metal-organic gels,MB, methylene blue,sXAS, Soft X-ray absorption spectroscopy,Dispersion,Fn, Fusobacterium nucleatum,PEG-CCM, polyethylene-glycol-modified mono-functional curcumin,hXAS, Hard X-ray absorption spectroscopy,MRA, mesoporous ρ-alumina,2,4-DNT, 2,4-dinitrotoluene,E. Coli, Escherichia coli,ZIF, zeolitic imidazolate framework,XPS, X-ray photoelectron spectroscopy,PANI, Polyaniline,MRSA, Methicillin-resistant staphylococcus aureus,PXRD, Powder x-ray diffraction,ECS, Extrusion-crushing-sieving,MVTR, Moisture vapor transport rate,FT-IR, Fourier-transform infrared spectroscopy,WLED, White light emitting diode,PS, Polystyrene,PAN, Polyacrylonitrile,SIBs, Sodium-ion batteries,EDLCs, Electrochemical double-layer capacitors,Mass production,4-NP, 4-nitrophenol,CWC, Chemical weapons convention,Metal–organic framework,NMR, Nuclear magnetic resonance,WHO, World health organization,EXAFS, Extended X-ray absorption fine structure,EPA, Environmental protection agency,VOC, Volatile organic compound,PVF, Polyvinylformal,NMP, N-methyl-2-pyrrolidone,PSM, Post-synthetic modification,UPS, Ultraviolet photoelectron spectroscopy,TNT, 2,4,6-trinitrotoluene,LOD, Limit of detection,PVA, Polyvinyl alcohol,CNF, Cellulose nanofiber,SSEs, Solid-state electrolytes,TNP, 2,4,6-trinitrophenol,ABS, acrylonitril-butadiene-styrene,TIPS-HoP, Thermally induced phase separation-hot pressing,PVC, Polyvinylchloride,MIM, Metal-insulator–metal,TEA, Triethylamine,Future applications,PVB, Polyvinyl Butyral,Shaping,PEMFCs, Proton-exchange membrane fuel cells,BET, Brunauer–Emmett–Teller,GC–MS, Gas chromatography–mass spectrometry,DEF, N,N-Diethyl formamide,STY, space–time yield, grams of MOF per cubic meter of reaction mixture per day of synthesis,PM, Particulate matter,DMA, Dimethylacetamide,GRGDS, Gly-Arg-Gly-Asp-Ser,CWA, Chemical warfare agent,POM, Polyoxometalate,SEM, Scanning electron microscope,CA, Cellulose-acetate,MOF, metal–organic framework,DIFP, Diisopropylfluorophosphate,ILDs, Interlayer dielectrics,ITRS, International technology roadmap for semiconductors,DMF, N,N-Dimethyl formamide,MMP, Methyl methylphosphonate,SCXRD, Single-crystal X-ray diffraction,LMOF, Luminescent metal–organic framework,LED, Light-emitting diode,CNG, compressed natural gas,CVD, Chemical vapor deposition,DMMP, Dimethyl methylphosphonate,SBU, Secondary building unit,SALI, Solvent assisted ligand incorporation,CEES, 2-Chloroethyl ethyl sulfide,MIC, Minimum inhibitory concentration,LIBs, Lithium-ion batteries,ROS, Reactive oxygen species,MBC, Minimum bactericidal concentration,RDX, 1,3,5-trinitro-1,3,5-triazinane,Pg, Porphyromonas gingivalis,CIE, Commission international ed’Eclairage,DLS, Dynamic light scattering,DDM, n-dodecyl β-D-maltoside,DFT, Density functional theory,DFP, Diisopropyl fluorophosphate,Commercialization,DCP, Diethylchlorophosphonate
                PEI, Polyetherimide, PPC, Polypropylene/polycarbonate, DRIFTS, Diffuse reflectance infrared fourier transform spectroscopy, MOGs, Metal-organic gels, MB, methylene blue, sXAS, Soft X-ray absorption spectroscopy, Dispersion, Fn, Fusobacterium nucleatum, PEG-CCM, polyethylene-glycol-modified mono-functional curcumin, hXAS, Hard X-ray absorption spectroscopy, MRA, mesoporous ρ-alumina, 2,4-DNT, 2,4-dinitrotoluene, E. Coli, Escherichia coli, ZIF, zeolitic imidazolate framework, XPS, X-ray photoelectron spectroscopy, PANI, Polyaniline, MRSA, Methicillin-resistant staphylococcus aureus, PXRD, Powder x-ray diffraction, ECS, Extrusion-crushing-sieving, MVTR, Moisture vapor transport rate, FT-IR, Fourier-transform infrared spectroscopy, WLED, White light emitting diode, PS, Polystyrene, PAN, Polyacrylonitrile, SIBs, Sodium-ion batteries, EDLCs, Electrochemical double-layer capacitors, Mass production, 4-NP, 4-nitrophenol, CWC, Chemical weapons convention, Metal–organic framework, NMR, Nuclear magnetic resonance, WHO, World health organization, EXAFS, Extended X-ray absorption fine structure, EPA, Environmental protection agency, VOC, Volatile organic compound, PVF, Polyvinylformal, NMP, N-methyl-2-pyrrolidone, PSM, Post-synthetic modification, UPS, Ultraviolet photoelectron spectroscopy, TNT, 2,4,6-trinitrotoluene, LOD, Limit of detection, PVA, Polyvinyl alcohol, CNF, Cellulose nanofiber, SSEs, Solid-state electrolytes, TNP, 2,4,6-trinitrophenol, ABS, acrylonitril-butadiene-styrene, TIPS-HoP, Thermally induced phase separation-hot pressing, PVC, Polyvinylchloride, MIM, Metal-insulator–metal, TEA, Triethylamine, Future applications, PVB, Polyvinyl Butyral, Shaping, PEMFCs, Proton-exchange membrane fuel cells, BET, Brunauer–Emmett–Teller, GC–MS, Gas chromatography–mass spectrometry, DEF, N,N-Diethyl formamide, STY, space–time yield, grams of MOF per cubic meter of reaction mixture per day of synthesis, PM, Particulate matter, DMA, Dimethylacetamide, GRGDS, Gly-Arg-Gly-Asp-Ser, CWA, Chemical warfare agent, POM, Polyoxometalate, SEM, Scanning electron microscope, CA, Cellulose-acetate, MOF, metal–organic framework, DIFP, Diisopropylfluorophosphate, ILDs, Interlayer dielectrics, ITRS, International technology roadmap for semiconductors, DMF, N,N-Dimethyl formamide, MMP, Methyl methylphosphonate, SCXRD, Single-crystal X-ray diffraction, LMOF, Luminescent metal–organic framework, LED, Light-emitting diode, CNG, compressed natural gas, CVD, Chemical vapor deposition, DMMP, Dimethyl methylphosphonate, SBU, Secondary building unit, SALI, Solvent assisted ligand incorporation, CEES, 2-Chloroethyl ethyl sulfide, MIC, Minimum inhibitory concentration, LIBs, Lithium-ion batteries, ROS, Reactive oxygen species, MBC, Minimum bactericidal concentration, RDX, 1,3,5-trinitro-1,3,5-triazinane, Pg, Porphyromonas gingivalis, CIE, Commission international ed’Eclairage, DLS, Dynamic light scattering, DDM, n-dodecyl β-D-maltoside, DFT, Density functional theory, DFP, Diisopropyl fluorophosphate, Commercialization, DCP, Diethylchlorophosphonate

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