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      Nano-Bioconjugate Film from Aloe vera To Detect Hazardous Chemicals Used in Cosmetics

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      ACS Omega
      American Chemical Society

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          Abstract

          It is of utmost importance to detect hazardous chemicals that affect human health. In this work, a simple method has been developed using a traditional medicinal herb Aloe vera as a carbon source to fabricate a nano-bioconjugate film. The nano-bioconjugate system comprises of A. vera gel itself and sodium alginate to form a fluorescent nano-bioconjugate film. The film was successfully used as an optical “turn-off” sensor in detecting analytes viz. para-Aminobenzoic acid (PABA), benzophenone, hydroquinone, and propylparaben, which are used in cosmetics and are listed as “red-listed” chemicals. The applicability of the fluorescent film in detecting these hazardous chemicals was even assessed with some locally purchased cosmetic samples. Mechanistic insight into the fluorescent quenching shown by nano-bioconjugate film is also discussed. Developments of such a detection system from sustainable sources make it an interesting option for fabricating sensors for hazardous chemicals.

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          Carbon quantum dots: synthesis, properties and applications

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            Carbon dots: synthesis, formation mechanism, fluorescence origin and sensing applications

            We systematically summarize the recent progress in the green synthesis and formation mechanism of CDs with the hope to provide guidance for developing CDs with the concept of green chemistry. In addition, we discuss and organize the current opinions on the fluorescence origin of CDs and the latest progress of CDs in fluorescence sensing applications. Carbon dots (CDs) have received an increasing amount of attention because of their significant advantages in terms of low toxicity, chemical inertness, tunable fluorescence, good water solubility, and physicochemical properties. Due to these desirable properties, they have been used in numerous fields, including chemo- and biosensing, fluorescence imaging, and drug delivery. In this review, we aim to demonstrate the recent progress in the green synthesis and formation mechanism of CDs, and provide guidance for developing CDs with the concepts of green chemistry. In addition, we discuss three kinds of most accepted luminescence origins: surface state, quantum confinement effect and molecular fluorescence. Finally, we systematically summarize the latest progress of CDs in fluorescence sensing applications, including both solution phase sensing and solid phase sensing. Furthermore, the challenges and future direction of CDs in this emerging field are discussed.
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              Amphiphilic egg-derived carbon dots: rapid plasma fabrication, pyrolysis process, and multicolor printing patterns.

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                Author and article information

                Journal
                ACS Omega
                ACS Omega
                ao
                acsodf
                ACS Omega
                American Chemical Society
                2470-1343
                18 November 2019
                03 December 2019
                : 4
                : 23
                : 20394-20401
                Affiliations
                [1]Material Nanochemistry Laboratory, Physical Sciences Division, Institute of Advanced Study in Science and Technology , Paschim Boragaon, Garchuk, Guwahati 781035, India
                Author notes
                [* ]E-mail: devasish@ 123456iasst.gov.in . Phone: +91 361 2912073. Fax: +91 361 2279909.
                Article
                10.1021/acsomega.9b03280
                6894156
                f06aca06-0fbd-4e39-8532-971955d8a4c4
                Copyright © 2019 American Chemical Society

                This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.

                History
                : 04 October 2019
                : 14 October 2019
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                Custom metadata
                ao9b03280
                ao9b03280

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