Switching time of electrical tuning of permeability in strain-mediated multiferroic heterostructures

We review the recent developments in the electric field control of magnetism in multiferroic heterostructures, which consist of heterogeneous materials systems where a magnetoelectric coupling is engineered between magnetic and ferroelectric components. The magnetoelectric coupling in these composite systems is interfacial in origin, and can arise from elastic strain, charge, and exchange bias interactions, with different characteristic responses and functionalities. Moreover, charge transport phenomena in multiferroic heterostructures, where both magnetic and ferroelectric order parameters are used to control charge transport, suggest new possibilities to control the conduction paths of the electron spin, with potential for device applications.

We investigate the influence of a well-defined reversible biaxial strain <=0.12 % on the magnetization (M) of epitaxial ferromagnetic manganite films. M has been recorded depending on temperature, strain and magnetic field in 20 - 50 nm thick films. This is accomplished by reversibly compressing the isotropic in-plane lattice parameter of the rhombohedral piezoelectric 0.72PMN-0.28PT (001) substrates by application of an electric field E <= 12 kV cm-1. The magnitude of the total variable in-plane strain has been derived. Strain-induced shifts of the ferromagnetic Curie temperature (Tc) of up to 19 K were found in La0.7Sr0.3MnO3 (LSMO) and La0.7Ca0.3MnO3 films and are quantitatively analysed for LSMO within a cubic model. The observed large magnetoelectric coupling coefficient alpha=mu0 dM/dE <= 6 10-8 s m-1 at ambient temperature results from the strain-induced M change in the magnetic-film-ferroelectric-substrate system. It corresponds to an enhancement of mu0 DeltaM <= 19 mT upon biaxial compression of 0.1 %. The extraordinary large alpha originates from the combination of three crucial properties: (i) the strong strain dependence of M in the ferromagnetic manganites, (ii) large piezo-strain of the PMN-PT substrates and (iii) effective elastic coupling at the film-substrate interface.