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      A Novel Resistive Sensor Network Utilizing an SAP-Enhanced Ionic Layer and CNT Doping for Multipoint Pressure Measurement

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      ACS Omega
      American Chemical Society

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          Abstract

          Amidst the rapid advancements in flexible electronics, flexible pressure sensors have achieved widespread applications in fields such as wearable devices and motion monitoring. Nevertheless, it is still a challenge to design a sensor with high sensitivity, cost-effectiveness, and a simplified manufacturing process. This paper introduces a piezoresistive sensor built upon a composite conductive filler. The sensor incorporates a super absorbent polymer (SAP) to absorb a phosphoric acid solution and doped carbon nanotubes as the composite conductive filler. In contrast to conventional rigid conductive fillers, the elastic polymer SAP enhances the sensor’s stability significantly by exhibiting superior compatibility with the polydimethylsiloxane matrix, all the while reducing its Young’s modulus. This work aims to theoretically elucidate the underlying principles that enable the sensor to achieve high sensitivity. It focuses on the induction of charge carriers due to pressure, which leads to the formation of a conductive pathway and subsequent changes in resistance, thus facilitating precise pressure detection. The paper also discusses the effects of piezoresistive layers with varying thicknesses and conductive fillers on the sensor’s output performance. The results highlight the sensor’s high sensitivity (0.094 kPa –1), rapid response time (105 ms), and exceptional cyclic load/unload stability (>5000 cycles). Furthermore, this paper establishes a versatile sensing network by integrating a portable inductance, capacitance, and resistance instrument with a programmable logic controller module. Compared to individual sensors, this system enables multipoint measurements, offering high spatial resolution and real-time monitoring capabilities, significantly expanding its overall practicality.

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          Most cited references49

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          Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers.

          The development of an electronic skin is critical to the realization of artificial intelligence that comes into direct contact with humans, and to biomedical applications such as prosthetic skin. To mimic the tactile sensing properties of natural skin, large arrays of pixel pressure sensors on a flexible and stretchable substrate are required. We demonstrate flexible, capacitive pressure sensors with unprecedented sensitivity and very short response times that can be inexpensively fabricated over large areas by microstructuring of thin films of the biocompatible elastomer polydimethylsiloxane. The pressure sensitivity of the microstructured films far surpassed that exhibited by unstructured elastomeric films of similar thickness, and is tunable by using different microstructures. The microstructured films were integrated into organic field-effect transistors as the dielectric layer, forming a new type of active sensor device with similarly excellent sensitivity and response times.
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            An electrically and mechanically self-healing composite with pressure- and flexion-sensitive properties for electronic skin applications.

            Pressure sensitivity and mechanical self-healing are two vital functions of the human skin. A flexible and electrically conducting material that can sense mechanical forces and yet be able to self-heal repeatably can be of use in emerging fields such as soft robotics and biomimetic prostheses, but combining all these properties together remains a challenging task. Here, we describe a composite material composed of a supramolecular organic polymer with embedded nickel nanostructured microparticles, which shows mechanical and electrical self-healing properties at ambient conditions. We also show that our material is pressure- and flexion-sensitive, and therefore suitable for electronic skin applications. The electrical conductivity can be tuned by varying the amount of nickel particles and can reach values as high as 40 S cm(-1). On rupture, the initial conductivity is repeatably restored with ∼90% efficiency after 15 s healing time, and the mechanical properties are completely restored after ∼10 min. The composite resistance varies inversely with applied flexion and tactile forces. These results demonstrate that natural skin's repeatable self-healing capability can be mimicked in conductive and piezoresistive materials, thus potentially expanding the scope of applications of current electronic skin systems.
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              Learning the signatures of the human grasp using a scalable tactile glove

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                Author and article information

                Journal
                ACS Omega
                ACS Omega
                ao
                acsodf
                ACS Omega
                American Chemical Society
                2470-1343
                19 December 2023
                09 January 2024
                : 9
                : 1
                : 1535-1545
                Affiliations
                []School of Aerospace Engineering, Xiamen University , Xiamen 361005, China
                []Science and Technology on Reliability Physics and Application of Electronic Component Laboratory, The Fifth Electronics Research Institute of the Ministry of Industry and Information Technology , Guangzhou 511370, China
                Author notes
                Author information
                https://orcid.org/0000-0002-7315-3257
                https://orcid.org/0000-0002-4272-3552
                Article
                10.1021/acsomega.3c07945
                10785618
                38222553
                c24d6f3a-76f8-4223-a781-66f07069faac
                © 2023 The Authors. Published by American Chemical Society

                Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works ( https://creativecommons.org/licenses/by-nc-nd/4.0/).

                History
                : 11 October 2023
                : 08 December 2023
                : 06 December 2023
                Funding
                Funded by: National Natural Science Foundation of China, doi 10.13039/501100001809;
                Award ID: 12272331
                Funded by: State Key Laboratory of Mechanics and Control for Aerospace Structures, Nanjing University of Aeronautics and astronautics, doi NA;
                Award ID: MCMS-E-0423G02
                Funded by: Innovation Foundation for Young Scholar of Xiamen, doi NA;
                Award ID: 3502Z20206042
                Funded by: Innovation and Entrepreneurship Leading Team Zengcheng, doi NA;
                Award ID: 202102001
                Funded by: Fundamental Research Funds for the Central Universities, doi 10.13039/501100012226;
                Award ID: 20720210049
                Funded by: Chinese Aeronautical Establishment, doi 10.13039/501100012130;
                Award ID: 20200033068001
                Funded by: Guangzhou Municipal Science and Technology Project, doi 10.13039/501100010256;
                Award ID: 202201011247
                Funded by: Natural Science Foundation of Fujian Province, doi 10.13039/501100003392;
                Award ID: 2022J01059
                Funded by: China Postdoctoral Science Foundation, doi 10.13039/501100002858;
                Award ID: 2021M700872
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