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      A review of recent progress in molybdenum disulfide-based supercapacitors and batteries

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          Abstract

          This article reviews the recent progress in molybdenum disulfide-based supercapacitors and batteries.

          Abstract

          Recently, transition metal chalcogenides, particularly molybdenum chalcogenides, have triggered intensive interest due to their intriguing physicochemical properties. Owing to its high anisotropy and distinct crystal structure, numerous reports have demonstrated that nanostructured MoS 2, with the merits of low cost and prominent properties, is an excellent substitute for environmentally benign energy conversion and for use in storage devices. Its different compounds, such as MoS 2/carbon, MoS 2/polymer, and MoS 2/metal oxides, have also been applied in the field of energy storage, including supercapacitors and batteries. In this review, we summarize the most recent advances made in the last 5 years in the development of MoS 2 and MoS 2-based composites in various electrochemical domains. In the discussion, emphasis is given to applications in supercapacitors, lithium-ion batteries, and sodium-ion batteries. Finally, some further prospects and promising developments of the materials in the energy storage field are proposed.

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          Nanostructured materials for advanced energy conversion and storage devices.

          New materials hold the key to fundamental advances in energy conversion and storage, both of which are vital in order to meet the challenge of global warming and the finite nature of fossil fuels. Nanomaterials in particular offer unique properties or combinations of properties as electrodes and electrolytes in a range of energy devices. This review describes some recent developments in the discovery of nanoelectrolytes and nanoelectrodes for lithium batteries, fuel cells and supercapacitors. The advantages and disadvantages of the nanoscale in materials design for such devices are highlighted.
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            MoS2/graphene composite paper for sodium-ion battery electrodes.

            We study the synthesis and electrochemical and mechanical performance of layered free-standing papers composed of acid-exfoliated few-layer molybdenum disulfide (MoS2) and reduced graphene oxide (rGO) flakes for use as a self-standing flexible electrode in sodium-ion batteries. Synthesis was achieved through vacuum filtration of homogeneous dispersions consisting of varying weight percent of acid-treated MoS2 flakes in GO in DI water, followed by thermal reduction at elevated temperatures. The electrochemical performance of the crumpled composite paper (at 4 mg cm(-2)) was evaluated as counter electrode against pure Na foil in a half-cell configuration. The electrode showed good Na cycling ability with a stable charge capacity of approximately 230 mAh g(-1) with respect to total weight of the electrode with Coulombic efficiency reaching approximately 99%. In addition, static uniaxial tensile tests performed on crumpled composite papers showed high average strain to failure reaching approximately 2%.
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              Is Open Access

              Transition Metal Carbides and Nitrides in Energy Storage and Conversion

              High‐performance electrode materials are the key to advances in the areas of energy conversion and storage (e.g., fuel cells and batteries). In this Review, recent progress in the synthesis and electrochemical application of transition metal carbides (TMCs) and nitrides (TMNs) for energy storage and conversion is summarized. Their electrochemical properties in Li‐ion and Na‐ion batteries as well as in supercapacitors, and electrocatalytic reactions (oxygen evolution and reduction reactions, and hydrogen evolution reaction) are discussed in association with their crystal structure/morphology/composition. Advantages and benefits of nanostructuring (e.g., 2D MXenes) are highlighted. Prospects of future research trends in rational design of high‐performance TMCs and TMNs electrodes are provided at the end.
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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                ICFNAW
                Inorganic Chemistry Frontiers
                Inorg. Chem. Front.
                Royal Society of Chemistry (RSC)
                2052-1553
                2017
                2017
                : 4
                : 10
                : 1602-1620
                Affiliations
                [1 ]College of Chemistry and Chemical Engineering
                [2 ]Xinyang Normal University
                [3 ]Xinyang 464000
                [4 ]China
                [5 ]Henan Province Key Laboratory of Utilization of Non-metallic Mineral in the South of Henan
                Article
                10.1039/C7QI00515F
                97985dae-efe1-46c9-9170-dfaf1bff517f
                © 2017
                History

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