Water-Processable Self-Doped Conducting Polymers via Direct (Hetero)arylation Polymerization

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Electrochemical considerations for determining absolute frontier orbital energy levels of conjugated polymers for solar cell applications.

Claudia M Cardona, Wei Li, Angel E Kaifer … (2011)

Narrow bandgap conjugated polymers in combination with fullerene acceptors are under intense investigation in the field of organic photovoltaics (OPVs). The open circuit voltage, and thereby the power conversion efficiency, of the devices is related to the offset of the frontier orbital energy levels of the donor and acceptor components, which are widely determined by cyclic voltammetry. Inconsistencies have appeared in the use of the ferrocenium/ferrocene (Fc + /Fc) redox couple, as well as the values used for the absolute potentials of standard electrodes, which can complicate the comparison of materials properties and determination of structure/property relationships.

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A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides

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Author and article information

Contributors

Sabine Ludwigs: (View ORCID Profile)

Mario Leclerc: (View ORCID Profile)

Journal

Title: Macromolecules

Abbreviated Title: Macromolecules

Publisher: American Chemical Society (ACS)

ISSN (Print): 0024-9297

ISSN (Electronic): 1520-5835

Publication date Created: June 22 2021

Publication date (Electronic): June 10 2021

Publication date (Print): June 22 2021

Volume: 54

Issue: 12

Pages: 5464-5472

Affiliations

[1 ]Département de Chimie, Université Laval, Québec, Québec G1V 0A6, Canada

[2 ]IPOC-Functional Polymers, Institute of Polymer Chemistry, University of Stuttgart, 70569 Stuttgart, Germany

[3 ]Polyanalytik, 700 Collip Circle #202, London, Ontario N6G 4X8, Canada

Article

DOI: 10.1021/acs.macromol.1c00847

SO-VID: 6f01a0e5-d187-42d4-9401-17ad6f851749

License:

https://doi.org/10.15223/policy-029

https://doi.org/10.15223/policy-037

https://doi.org/10.15223/policy-045

https://creativecommons.org/licenses/by-nc-nd/4.0/

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