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      Nanomaterials for the Removal of Heavy Metals from Wastewater

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          Abstract

          Removal of contaminants in wastewater, such as heavy metals, has become a severe problem in the world. Numerous technologies have been developed to deal with this problem. As an emerging technology, nanotechnology has been gaining increasing interest and many nanomaterials have been developed to remove heavy metals from polluted water, due to their excellent features resulting from the nanometer effect. In this work, novel nanomaterials, including carbon-based nanomaterials, zero-valent metal, metal-oxide based nanomaterials, and nanocomposites, and their applications for the removal of heavy metal ions from wastewater were systematically reviewed. Their efficiency, limitations, and advantages were compared and discussed. Furthermore, the promising perspective of nanomaterials in environmental applications was also discussed and potential directions for future work were suggested.

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          Most cited references238

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          Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review.

          Efficient removal of hazardous materials from the environment has become an important issue from a biological and environmental standpoint. Adsorptive removal of toxic components from fuel, waste-water or air is one of the most attractive approaches for cleaning technologies. Recently, porous metal-organic framework (MOF) materials have been very promising in the adsorption/separation of various liquids and gases due to their unique characteristics. This review summarizes the recent literatures on the adsorptive removal of various hazardous compounds mainly from fuel, water, and air by virgin or modified MOF materials. Possible interactions between the adsorbates and active adsorption sites of the MOFs will be also discussed to understand the adsorption mechanism. Most of the observed results can be explained with the following mechanisms: (1) adsorption onto a coordinatively unsaturated site, (2) adsorption via acid-base interaction, (3) adsorption via π-complex formation, (4) adsorption via hydrogen bonding, (5) adsorption via electrostatic interaction, and (6) adsorption based on the breathing properties of some MOFs and so on.
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            The use of zero-valent iron for groundwater remediation and wastewater treatment: a review.

            Recent industrial and urban activities have led to elevated concentrations of a wide range of contaminants in groundwater and wastewater, which affect the health of millions of people worldwide. In recent years, the use of zero-valent iron (ZVI) for the treatment of toxic contaminants in groundwater and wastewater has received wide attention and encouraging treatment efficiencies have been documented. This paper gives an overview of the recent advances of ZVI and progress obtained during the groundwater remediation and wastewater treatment utilizing ZVI (including nanoscale zero-valent iron (nZVI)) for the removal of: (a) chlorinated organic compounds, (b) nitroaromatic compounds, (c) arsenic, (d) heavy metals, (e) nitrate, (f) dyes, and (g) phenol. Reaction mechanisms and removal efficiencies were studied and evaluated. It was found that ZVI materials with wide availability have appreciable removal efficiency for several types of contaminants. Concerning ZVI for future research, some suggestions are proposed and conclusions have been drawn. Copyright © 2014 Elsevier B.V. All rights reserved.
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              Heavy metal removal from aqueous solution by advanced carbon nanotubes: Critical review of adsorption applications

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                Author and article information

                Journal
                Nanomaterials (Basel)
                Nanomaterials (Basel)
                nanomaterials
                Nanomaterials
                MDPI
                2079-4991
                12 March 2019
                March 2019
                : 9
                : 3
                : 424
                Affiliations
                National Engineering Research Center of Industrial Crystallization Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; jyyang@ 123456tju.edu.cn (J.Y.); jkwang@ 123456tju.edu.cn (J.W.); beiqiantian@ 123456tju.edu.cn (B.T.); jingtaob@ 123456gmail.com (J.B.); wangna224@ 123456tju.edu.cn (N.W.); 2016207425@ 123456tju.edu.cn (X.L.)
                Author notes
                [* ]Correspondence: houbaohong@ 123456tju.edu.cn (B.H.); x_huang@ 123456tju.edu.cn (X.H.); Tel.: +86-22-27403200 (X.H.)
                Author information
                https://orcid.org/0000-0001-9865-9425
                https://orcid.org/0000-0003-3358-5044
                Article
                nanomaterials-09-00424
                10.3390/nano9030424
                6473982
                30871096
                6b4f8011-3a69-4ce7-8167-adf4f0028864
                © 2019 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 26 January 2019
                : 07 March 2019
                Categories
                Review

                nanomaterials,heavy metal,wastewater,carbon-based nanomaterials,zero-valent metal,metal oxide,nanocomposite

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