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      Engineering of Transition Metal Catalysts Confined in Zeolites

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          Abstract

          Transition metal–zeolite composites are versatile catalytic materials for a wide range of industrial and lab-scale processes. Significant advances in fabrication and characterization of well-defined metal centers confined in zeolite matrixes have greatly expanded the library of available materials and, accordingly, their catalytic utility. In this review, we summarize recent developments in the field from the perspective of materials chemistry, focusing on synthesis, postsynthesis modification, (operando) spectroscopy characterization, and computational modeling of transition metal–zeolite catalysts.

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          Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity

          Unni Olsbye, Stian Svelle, Morten Bjørgen … (2012)
          Article 0 comments Cited 298 times – based on 0 reviews     Review now
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            The hydrothermal synthesis of zeolites: history and development from the earliest days to the present time.

            Colin S Cundy, Paul A Cox (2003)
            Article 0 comments Cited 261 times – based on 0 reviews     Review now
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              Synergies between bio- and oil refineries for the production of fuels from biomass.

              George Huber, Avelino Corma (2007)
              As petroleum prices continue to increase, it is likely that biofuels will play an ever-increasing role in our energy future. The processing of biomass-derived feedstocks (including cellulosic, starch- and sugar-derived biomass, and vegetable fats) by catalytic cracking and hydrotreating is a promising alternative for the future to produce biofuels, and the existing infrastructure of petroleum refineries is well-suited for the production of biofuels, allowing us to rapidly transition to a more sustainable economy without large capital investments for new reaction equipment. This Review discusses the chemistry, catalysts, and challenges involved in the production of biofuels.
              Article 0 comments Cited 249 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Journal ID (nlm-ta): Chem Mater
                Journal ID (iso-abbrev): Chem Mater
                Journal ID (publisher-id): cm
                Journal ID (coden): cmatex
                Title: Chemistry of Materials
                Publisher: American Chemical Society
                ISSN (Print): 0897-4756
                ISSN (Electronic): 1520-5002
                Publication date (Electronic): 07 May 2018
                Publication date (Print): 22 May 2018
                Volume: 30
                Issue: 10
                Pages: 3177-3198
                Affiliations
                [† ]Inorganic Systems Engineering Group, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology , Van der Maasweg 9, 2629 HZ Delft, The Netherlands
                [‡ ]Schuit Institute of Catalysis, Laboratory of Inorganic Materials Chemistry, Eindhoven University of Technology , P.O. Box 513, 5600 MB Eindhoven, The Netherlands
                [§ ]TheoMAT group, ITMO University , Lomonosova str. 9, St. Petersburg 191002, Russia
                Author notes
                [* ]E-mail: n.a.kosinov@ 123456tue.nl (N.K.).
                [* ]E-mail: e.j.m.hensen@ 123456tue.nl (E.J.M.H.).
                [* ]E-mail: e.a.pidko@ 123456tudelft.nl (E.A.P.).
                Article
                DOI: 10.1021/acs.chemmater.8b01311
                PMC ID: 5973782
                PubMed ID: 29861546
                SO-VID: 4bd06892-b2e2-44a8-80bb-9194db487a39
                Copyright © Copyright © 2018 American Chemical Society
                License:

                This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.

                History
                Date received : 29 March 2018
                Date revision received : 26 April 2018
                Categories
                Subject: Review
                Custom metadata
                document-id-old-9 cm8b01311
                document-id-new-14 cm-2018-01311u
                ccc-price

                ScienceOpen disciplines: Materials science
                Data availability:
                ScienceOpen disciplines: Materials science

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