Synthesis and optical properties of WS ₂ nanotubes with relatively small diameters

Abstract

Tungsten disulfide (WS ₂) nanotubes exhibit various unique properties depending on their structures, such as their diameter and wall number. The development of techniques to prepare WS ₂ nanotubes with the desired structure is crucial for understanding their basic properties. Notably, the synthesis and characterization of multi-walled WS ₂ nanotubes with small diameters are challenging. This study reports the synthesis and characterization of small-diameter WS ₂ nanotubes with an average inner diameter of 6 nm. The optical absorption and photoluminescence (PL) spectra of the as-prepared nanotubes indicate that a decrease in the nanotube diameter induces a red-shift in the PL, suggesting that the band gap narrowed due to a curvature effect, as suggested by theoretical calculations.