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835
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Compounds of Groups 12 and 11 (Zn, Cd, Hg, Cu, Ag, Au)
Conjugate Addition Reactions in the Presence of Boron Trifluoride
other
Author(s):
H. Heaney
,
S. Christie
Publication date
(Online):
2004
Publisher:
Georg Thieme Verlag KG
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Book Chapter
Publication date (Print):
2004
Publication date (Online):
2004
Page
: 1
DOI:
10.1055/sos-SD-003-00355
SO-VID:
e627c995-45ed-473d-be00-babbd15db41b
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Book chapters
pp. 1
From Bis[bis(trimethylsilyl)amino]cadmium
pp. 1
Cycloisomerization of Dienynes
pp. 1
From Phosphonium Salts
pp. 1
Via Addition of Isonitriles to Azido Complexes
pp. 1
From an Allylic Halide and Zinc Dust
pp. 1
Via Organotin Compounds
pp. 1
Oxidative Coupling Reactions of Alkynes Involving Copper(II) and Copper(I) Salts and Complexes
pp. 1
Additional Methods
pp. 1
Coupling Reactions of Alkynes with Substituted Alkenes
pp. 1
From Arylmagnesium Halides
pp. 1
Mercury Substitution of Arenediazonium Salts
pp. 1
Coupling Reactions of Alkynes with Aryl Trifluoromethanesulfonates
pp. 1
Formation of Organomercury(II) Salts
pp. 1
Use of Aluminum Trichloride and Diethylaluminum Chloride in Conjugate Addition Reactions
pp. 1
Synthesis
pp. 1
Intramolecular Acyl Migration
pp. 1
Auration of Acetylacetone
pp. 1
2,2-Dimethylpropylmagnesium Bromide with Cadmium(II) Iodide
pp. 1
From Rieke Copper
pp. 1
Zinc–Carbenoid Complexes
pp. 1
Homologation of an Organometallic with Iodomethylzinc(II) Iodide
pp. 1
Organocadmium Halides
pp. 1
Mononuclear Gold(III) Complexes with Two Ylide Ligands
pp. 1
From (Trialkylphenyl)magnesium Halides
pp. 1
Symmetrization
pp. 1
Conjugate Addition Reactions Using a Catalytic Amount of Copper Salt
pp. 1
Unsubstituted Alkylgold(I) and Alkylgold(III) Compounds
pp. 1
Cycloisomerization of 1,6-Enynes
pp. 1
From Alkenylzinc Reagents and Copper(I) Salts
pp. 1
1,2-Addition to Carbonyl Compounds
pp. 1
Alkylmagnesium Bromides with Cadmium(II) Bromide
pp. 1
Symmetrization of an Organomercury(II) Salt to the Corresponding Diorganomercury(II) Compound
pp. 1
Cadmium–Tris(dimethylamino)methylenephosphorane Complex
pp. 1
Reaction of Bis(trifluoromethyl)cadmium–1,2-Dimethoxyethane Complex with Acyl Halides
pp. 1
Halogenation of Organomercury(II) Derivatives
pp. 1
Oxidative Addition of Halogen
pp. 1
Bis[bis(trimethylsilyl)amino](pentamethylcyclopentadienyl)cadmium(II)
pp. 1
Via Oxidative Addition of Halogen to Gold(I) Complexes
pp. 1
Reactions with Allylic Substrates
pp. 1
Allylzinc Halides from an Allylic Halide or Phosphate and Zinc
pp. 1
Lithium Triorganozincates from an Organolithium Reagent and a Zinc Halide
pp. 1
Alkylzinc Halides by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Gold-Catalyzed Suzuki Reactions
pp. 1
From Organomercury(II) Halides and Sodium Borohydride in a Mixed Aqueous Solvent
pp. 1
Synthesis
pp. 1
From Alkylmagnesium Halides
pp. 1
Allylzinc Halides by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
From Arylzinc Reagents Together with a Copper(I) Salt
pp. 1
From an Allylic Halide and Activated Zinc
pp. 1
α-Halogenated Alkylzinc Halides from a Dihalomethane and an Organozinc Reagent
pp. 1
1,6-Digoldferrocene Complexes
pp. 1
Bis(α-halomethyl)zincs or Other Zinc Carbenoids from a Dihalomethane and a Diorganozinc
pp. 1
Inter- and Intramolecular Addition of Nucleophiles to 1,5-Enynes
pp. 1
Using a Nickel Catalyst
pp. 1
Nucleophilic Attack at the γ-Position
pp. 1
Organomercury(II) Hydrides
pp. 1
Anion-Exchange Reactions
pp. 1
Synthesis of Silver–Ylide Complexes
pp. 1
Palladium-Catalyzed Acylation
pp. 1
Dibenzylzincs by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Auration of Barbituric Acid
pp. 1
Oxidative Aminooxygenation and Aminoamidation of Alkenes Using Selectfluor or (Diacetoxyiodo)benzene
pp. 1
Reactions with Propargylic Substrates
pp. 1
Oxidative Chlorination of Nonactivated Arenes
pp. 1
Cyclization Reactions of Aromatic Vicinally Related Halocarboxylic Acids
pp. 1
Applications
pp. 1
Diarylzincs by Transmetalation of a Triarylborane with a Dialkylzinc
pp. 1
Mononuclear Gold(I) Complexes with Haloalkyl and Pseudohaloalkyl Ligands
pp. 1
Arylzinc Halides by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Products from Formal Electrophilic Substitution Reactions
pp. 1
Synthesis
pp. 1
Synthesis
pp. 1
Bis- and Tris(trimethylsilyl)methyllithium with Cadmium(II) Chloride
pp. 1
Allylmercury(II) Compounds
pp. 1
(Carbene)gold(III) Complexes
pp. 1
Substitution Reactions with a Catalytic Amount of Copper
pp. 1
From the Reaction of Dimethylcadmium with Bis[,-diethyldithio(or diseleno)carbamato]cadmium(II)
pp. 1
Gold-Catalyzed Oxidative Cross Coupling with External Oxidants
pp. 1
Silver–Carbene Homoleptic Complexes from Imidazol-2-ylidene Derivatives
pp. 1
Synthesis
pp. 1
Dinuclear Gold(I) Complexes with Substituted Organic Groups
pp. 1
Synthesis of Alkylgold(I) Complexes from Organolithium or Grignard Reagents
pp. 1
Dialkylzincs from an Alkyl Halide and Zinc
pp. 1
Tetraarylaurate(III) Complexes
pp. 1
By Direct Electrochemical Synthesis
pp. 1
Oxidative Diamination of Alkenes Using (Diacetoxyiodo)benzene
pp. 1
From the Reaction of Active Cadmium Slurries and Alkyl Iodides
pp. 1
Substitution Reactions Involving a Leaving Group at an sp-Hybridized Carbon
pp. 1
Homocoupling of Propargyl Acetates Using Selectfluor
pp. 1
β- and γ-Heterosubstituted Alkylmercury(II) Compounds; Oxymercuration
pp. 1
Dialkenylcyanocuprates from Alkenyllithium Reagents
pp. 1
Synthesis of Tetraalkylaurates(III)
pp. 1
From Arylmagnesium Halides in the Presence of Boron Trifluoride and Other Lewis Acids
pp. 1
Auration of Esters
pp. 1
With Aryllithium Reagents
pp. 1
Oxidative Arylation with Arylboronic Acids Using Selectfluor
pp. 1
From an Arylmagnesium Reagent
pp. 1
Alkynylzinc Halides by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Zinc–Alkyl Complexes
pp. 1
Diastereoselective Ullmann Biaryl Syntheses from Aryl Halides and Copper(0)
pp. 1
Synthesis of Indole Derivatives
pp. 1
Substitution Reactions Using Catalytic Amounts of Copper(I)
pp. 1
By Transmetalation from Organozirconium Reagents
pp. 1
Synthesis of Cyclopropanes
pp. 1
Synthesis
pp. 1
Complexation of Gold(I) Acetylides
pp. 1
Synthesis Based on Polyborylmethanes
pp. 1
(Het)arylmethylzinc Halides from a (Het)arylmethyl Halide and Zinc
pp. 1
By Decarboxylation
pp. 1
Formation of Ketones by Addition–Elimination
pp. 1
Gold-Catalyzed Alkynylation of Heterocycles Using Alkynyliodine(III) Reagents
pp. 1
(3-Methoxypropyl)magnesium Chloride with Cadmium(II) Chloride
pp. 1
Heck-Type Addition
pp. 1
Applications of the Cycloisomerization of Oxo-1,6-enynes in Total Synthesis
pp. 1
Reactions of 1-Arylpropargylic Carboxylates
pp. 1
Monoalkenylcopper(I) Compounds
pp. 1
Alkylation
pp. 1
Using Activated Zinc
pp. 1
Substitution Reactions with a Stoichiometric Amount of Copper
pp. 1
Via Organolithium Compounds
pp. 1
Alkylzinc Halides from an Alkyl Halide and Zinc
pp. 1
Synthesis
pp. 1
Mononuclear Gold(III) Complexes with One Ylide Ligand
pp. 1
Aryl, Alk-1-ynyl, or Vinyl Coupling
pp. 1
Using an Alkyllithium Reagent
pp. 1
Alkyl[,-diethyldithio(or diseleno)carbamato]cadmium/zinc Compounds
pp. 1
Organogold Compounds with Alkenyl Ligands
pp. 1
β-Heteroalkylmercury(II) Compounds from Oxymercuration of Alkenes
pp. 1
Mononuclear Gold(I) Complexes with One Ylide and One Organic Group
pp. 1
Heterocycles as Ligands for Gold(I) and Gold(III) Complexes
pp. 1
Complex Gold(I) Acetylides by Nucleophilic Substitution
pp. 1
Mononuclear Complexes of Gold(I) with Two Ylide Ligands
pp. 1
Bis(perfluoroalkyl)cadmiums
pp. 1
Allylzincation of Alkynes
pp. 1
Using a Palladium Catalyst
pp. 1
Silver–Alkene Complexes
pp. 1
From Silver(I) Fluoride and Perfluoroalkynes
pp. 1
Cadmium Compounds of the Type RCdX (X = Heteroatom)
pp. 1
1,2-Addition to Aldehydes, Ketones, or Imines
pp. 1
(Acyloxy)allenes as Nucleophiles
pp. 1
Dialkylzincs by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Reaction of η-Allylmetal Complexes with Mercury(0)
pp. 1
From Alkyllithium Reagents
pp. 1
Silver–Carbene Complexes
pp. 1
Using 4-(Trimethylsilyl)but-2-ynyl Substrates
pp. 1
Mononuclear Complexes of Gold(I) with One Ylide and One Halogen Ligand
pp. 1
Diallylzincs by Transmetalation of an Organometallic Reagent with a Dialkylzinc
pp. 1
Synthesis
pp. 1
Synthesis
pp. 1
Synthesis
pp. 1
Decarboxylation of Mercury(II) Carboxylates
pp. 1
With Diazomethane
pp. 1
Synthesis
pp. 1
Bicyclic Dinuclear Gold(III) Complexes with Bridging Ylide Ligands
pp. 1
Silylalkylgold(I) Compounds from Organometallic Reagents
pp. 1
Gold-Catalyzed Oxidative Cross-Coupling Reaction
pp. 1
Synthesis of 1-Carboxyvinyl Ketones via Oxidative C–O Bond Formation Using Selectfluor
pp. 1
β-Heteroalkylmercury(II) Compounds from Oxymercuration of Allenes
pp. 1
Synthesis of Fluoroalkylsilver Compounds
pp. 1
From a Dialkylcadmium and an Alkyne
pp. 1
Synthesis Based on Trimethylsilyldiazomethane
pp. 1
Addition of Alkenes and Alkynes to Gold(I)
pp. 1
Cycloisomerization of Oxo-1,6-enynes
pp. 1
From Arylmagnesium Halides Using Catalytic Amounts of Copper Salts
pp. 1
Gold-Catalyzed Cycloisomerizations of Enynes
pp. 1
Catalytic Asymmetric 1,2-Addition to Aldehydes
pp. 1
From Alkynes and Copper(I) Salts and Complexes
pp. 1
From Aryllithium Reagents Formed by Metalation Reactions
pp. 1
Via [Au(R)X] as Starting Materials
pp. 1
Organogold Compounds with Substituted Alkyl Ligands
pp. 1
Reactions of Aryl Halides with Active Copper(0) (Rieke Copper)
pp. 1
Electrophilic Substitution by Mercury(II) Salts
pp. 1
Alkyl[,-diethyldithio(or diseleno)carbamato]cadmium(II) Compounds
pp. 1
By Direct Reaction with the Carbene
pp. 1
Monocyclic Dinuclear Gold(II) Complexes with Bridging Ylide Ligands
pp. 1
Copper/Palladium-Catalyzed Coupling Reactions of Terminal Alkynes with Organic Halides
pp. 1
Synthesis
pp. 1
From Alkenylmagnesium Halides
pp. 1
Additions to Alkenes and Alkynes
pp. 1
Synthesis of α-Aryl α-Fluoro Ketones via Oxidative Functionalization of Alkynes
pp. 1
(Hexafluoroacetylacetonato)silver–Alkene Complexes from Silver(I) Oxide and Alkenes
pp. 1
Synthesis
pp. 1
Biaryl Syntheses from Aryl Halides and Copper(I) Salts
pp. 1
Zinc–Allenyl Complexes
pp. 1
From the Pyrolysis of Cadmium(II) Pentafluorobenzoate
pp. 1
Formation of α-Iodo- or α-Bromoenones
pp. 1
Auration of Ketones from Cyclopropyl Silyl Ethers
pp. 1
Silver–Alkynyl Complexes from Phosphinesilver Complexes and Alkynes
pp. 1
Substitution Reactions Using a Stoichiometric Amount of Copper Salt
pp. 1
Isolation of a Gold(III) Fluoride Complex and Its Use in Cross Coupling
pp. 1
Diarylthallium Halides as Reagents
pp. 1
Formation of Cyclopropyl Rings
pp. 1
Acylation of Organomercury(II) Derivatives
pp. 1
Zinc–Hetaryl Complexes
pp. 1
Dialkenylzincs and Alkenyl(alkyl)zincs by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Elimination of Sulfinates
pp. 1
Dialkylzincs by Transmetalation of an Organometallic Reagent with Zinc
pp. 1
From Arylsilanes and Copper(I) Salts
pp. 1
Diarylcyanocuprates from Aryllithium Reagents
pp. 1
From Aryllithium Reagents
pp. 1
Mixed Cyanocuprates
pp. 1
From Aryllithium Reagents Formed by Halogen–Metal Interconversion Reactions Using an Alkyllithium Reagent
pp. 1
Applications of Organomercury(II) Hydrides
pp. 1
Using Irradiation
pp. 1
From an Allylic Phosphate and Zinc Dust
pp. 1
Silver–σ-Alkyl Homoleptic Complexes
pp. 1
Coupling Reactions of Alkynes with Alkenyl Halides
pp. 1
From Silver Nitrate and a Triene
pp. 1
Applications
pp. 1
With Arylsilver Reagents
pp. 1
Oxidative Carboheterofunctionalization of Alkenes
pp. 1
Synthesis
pp. 1
The Grignard Method
pp. 1
Mononuclear Gold(III) Complexes with Substituted Organic Groups
pp. 1
Conjugate Addition Reactions with a Catalytic Amount of Copper
pp. 1
Oxidative Homocoupling via C–H Bond Functionalization
pp. 1
From Alkenyl Halides Using Activated Rieke Copper
pp. 1
Dialkylzincs by Transmetalation of an Organometallic Reagent with a Dialkylzinc
pp. 1
Cycloisomerization of 1,5-Enynes
pp. 1
Methylcadmium Alkoxides and Alkyl Methylcadmium Sulfides
pp. 1
From 2-Thienyllithium
pp. 1
Insertion of Perfluoroalkenes
pp. 1
Synthesis
pp. 1
Substitution of Haloalkenes by Addition–Elimination Reactions
pp. 1
Applications
pp. 1
From an In Situ Generated Benzylic Halide and Zinc Dust
pp. 1
Silver–σ-Alkynyl Complexes
pp. 1
Use of Boron Trifluoride in Substitution Reactions
pp. 1
Monoalkylcopper(I) Compounds
pp. 1
Reductive Elimination from Stoichiometric Organogold(III) Complexes
pp. 1
Silver–Triene Complexes
pp. 1
Synthesis
pp. 1
Reactions of Substrates with Functionality at the Alkyne Terminus of the Propargylic Group
pp. 1
Arylgold(I) Compounds
pp. 1
Dialkylcyanocuprates from Alkyllithium Reagents
pp. 1
Lithium Triorganozincates from a Triorganozincate and an Alkyne
pp. 1
Reactions Incorporating Gold(I)/Gold(III) Catalysis
pp. 1
[(Trimethylsilyl)methyl]magnesium Chloride with Cadmium(II) Iodide
pp. 1
Alkylmercury(II) Compounds
pp. 1
Dialkylcadmium Adducts
pp. 1
Silver–η-Arene Complexes from Silver Perchlorate or Trifluoromethanesulfonate and Arenes
pp. 1
Ligand-Free Gold(I) Acetylides
pp. 1
Synthesis
pp. 1
α-Halogenated Alkylzinc Halides from a Dihalomethane and Zinc Dust
pp. 1
With Arylmercury Reagents
pp. 1
Via Substitution Reactions
pp. 1
Reactions Using Indole-3-acetyl as the Acyl Group
pp. 1
Mononuclear Gold(I) Complexes with Oxo, Ester, Sulfone, Phosphino, Silyl, and Other Functions in the Alkyl Substituent
pp. 1
Palladium-Catalyzed Aryl–Aryl Coupling
pp. 1
Reaction of Allylic Halides with Mercury(0)
pp. 1
From Arylmagnesium Halides in the Presence of Copper Salts and Chlorotrimethylsilane
pp. 1
From Alkyl Halides Using Activated Rieke Copper
pp. 1
Anionic Species via Double Arylation
pp. 1
(Het)arylmethylzinc Halides by the Methylene Homologation of a (Het)arylcopper
pp. 1
With Cadmium(II) Halides
pp. 1
Using a Copper Catalyst
pp. 1
Auration of Ketones Using Halo(phosphine)gold(I) or Oxonium Salts
pp. 1
Ketones from Acid Halides or Acid Anhydrides
pp. 1
(Hexafluoroacetylacetonato)silver–Alkyne Complexes from Silver(I) Oxide and Alkynes
pp. 1
Gold-Catalyzed Oxidative Homocoupling with External Oxidants
pp. 1
Allenylzinc Halides by the Methylene Homologation of an Alkynyl Organometallic Reagent
pp. 1
From Transmetalation Reactions of Organothallium Compounds
pp. 1
Reactions with Hydrolytic Treatment
pp. 1
Uncatalyzed Reactions
pp. 1
Polymeric Silver Acetylides from a Silver Salt and an Acetylene
pp. 1
Synthesis
pp. 1
Hetarylzinc Halides from a Hetaryl Halide and Zinc
pp. 1
Gold-Catalyzed Cross Coupling with Substrates as Oxidants
pp. 1
Arylgold Compounds
pp. 1
Using a Zinc Anode
pp. 1
Use of Ytterbium Chloride
pp. 1
Addition Reactions with a Stoichiometric Amount of Copper
pp. 1
Formation of 1,3-Dienes
pp. 1
From Silver Trifluoromethanesulfonate and Cyclopentadienylsodium
pp. 1
Synthesis Based on Phosphorus Ylides
pp. 1
Monoalkynylcopper(I) Compounds
pp. 1
Palladium-Catalyzed Cross-Coupling Reactions
pp. 1
Synthesis
pp. 1
Biaryl Formation Involving Coupling of sp-Hybridized Carbon Centers
pp. 1
Via Gold(I) Oxonium Salts
pp. 1
From Lithiated Reagents
pp. 1
Synthesis of β,γ-Unsaturated Ketones
pp. 1
Via Transmetalation
pp. 1
Mononuclear Gold(I) Complexes with Ferrocenyl and Cymantrenyl Ligands
pp. 1
Additional Methods
pp. 1
From Metal Vapor and Trifluoromethyl Radicals
pp. 1
Synthesis
pp. 1
From an Organomagnesium Reagent
pp. 1
Dialkynylzincs by Deprotonation of an Alkyne with a Dialkylzinc
pp. 1
Auracyclopentadiene Compounds
pp. 1
From a 1,1-Dihalide
pp. 1
Silver–Aryl Complexes
pp. 1
Via Oxidative Addition of Halogen
pp. 1
Sonogashira–Hagihara Coupling Reactions in Oligomer and Polymer Synthesis
pp. 1
Via Oxidative Addition of Trifluoroiodomethane
pp. 1
Cobalt-, Iron-, and Manganese-Catalyzed Reactions
pp. 1
Carbon in Gold Clusters
pp. 1
Diarylzincs by Transmetalation of a Diarylmercury with Zinc
pp. 1
Conjugate Addition Reactions Using a Stoichiometric Amount of Copper Salt
pp. 1
From Alkenyllithium Reagents
pp. 1
Gold-Catalyzed Propargylic Rearrangements
pp. 1
Synthesis
pp. 1
Alkyl(carbamato)cadmium Compounds
pp. 1
(+)-()-(2-Methylbutyl)magnesium Chloride with Cadmium(II) Chloride
pp. 1
Reaction of Bis(trifluoromethyl)cadmium–Base Complexes with Inorganic Salts
pp. 1
Coupling Reactions of Haloaromatic Compounds Leading to Disubstituted Alkynes
pp. 1
Decarboxylation of Arenecarboxylates
pp. 1
Grignard Reagents with Organocadmium Compounds (Synthesis of Unsymmetrical Dialkylcadmiums)
pp. 1
Asymmetric Reactions Mediated by Zinc Organometallics
pp. 1
Oxidative Arylation with Arylsilanes Using Selectfluor
pp. 1
Synthesis
pp. 1
Cadmium–π-Arene Complexes
pp. 1
Cascade Cyclization–Intramolecular Arylation of Alkenes
pp. 1
Via Transylidation
pp. 1
From Alkenyllithium Reagents and Stoichiometric Amounts of Copper(I)
pp. 1
Diaryl- and Dialkynylcadmiums
pp. 1
With Bis(acetylacetonato)cadmium
pp. 1
Ullmann Biaryl Syntheses from Aryl Halides and Copper(0)
pp. 1
Cyclization Reactions of 2-Iodobenzyl Alcohol and 2-Iodophenylacetic Acid
pp. 1
From Alk-1-ynes and Mercury(II) Halides with Base
pp. 1
(Acyloxy)allenes as All-Carbon 1,3-Dipoles
pp. 1
Cycloisomerization of 1,n-Enynes via Migration of Propargyl Groups
pp. 1
Gilman Cuprates
pp. 1
By Ligand-Exchange Reactions
pp. 1
From Alkylmagnesium Halides and Copper(I) Halides
pp. 1
Substitution Reactions Using Stoichiometric Amounts of Copper(I)
pp. 1
Mononuclear Gold(I) Complexes with Alkenyl Ligands
pp. 1
The Synthesis of Benzo[]furan and Pyridofuran Derivatives
pp. 1
Reactions of Arylcopper Reagents with Carbonyl Compounds
pp. 1
Homocoupling from Stoichiometric Organogold(I) Complexes Using Electrophilic Fluorinating Reagents
pp. 1
Coupling Reactions of Alkynes as Double Electrophile Components in Ring Syntheses
pp. 1
With Bis(trifluoromethyl)cadmium
pp. 1
Organogold Compounds with Ylide Ligands
pp. 1
Transmetalation with Organomagnesium Reagents
pp. 1
Aryl(phenylethynyl)diazenes from Silver Acetylides and Diazonium Salts
pp. 1
Synthesis
pp. 1
From a Preformed Aryllithium Reagent
pp. 1
Synthesis
pp. 1
Triorganozincates
pp. 1
Transmetalation with Organolithium
pp. 1
Carbene Complexes of Gold
pp. 1
Synthesis of 2-Acylbenzoic Acids
pp. 1
Substitution Reactions in the Presence of Boron Trifluoride
pp. 1
Auration of Malononitrile
pp. 1
From Metal Vapors
pp. 1
1,1-Digold(I)alkenium and 1,1-Digold(I)ferrocenium Salts
pp. 1
Triarylgold(III) Complexes
pp. 1
Chlorination Using Thallium(III) Chloride
pp. 1
Formation of Cyclobutenes or Cyclobutanones
pp. 1
Synthesis of Allylic Acetates
pp. 1
Butylmagnesium Bromide with Cadmium(II) Chloride
pp. 1
1,4-Additions to Enones
pp. 1
From an Organozirconium Reagent
pp. 1
Coupling Reactions with Alkenyl Trifluoromethanesulfonates
pp. 1
From an Aryl Iodide
pp. 1
Silver–σ-Alkenyl Complexes
pp. 1
Synthesis
pp. 1
From Alkynes and Alkenes with Mercury(II) Halides and Carboxylates under Nonbasic Conditions
pp. 1
Diallenylzincs by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
β-Heteroalkylmercury(II) Compounds from Oxymercuration of 1,3-Dienes
pp. 1
1,2-Digoldalkenes
pp. 1
Oxidative Amination of Nonactivated Arenes
pp. 1
From Alkylgold(I) Complexes and Fluoroalkyl Iodides
pp. 1
Mononuclear Gold(I) Complexes with Cyclopentadienyl Ligands
pp. 1
Propargylic Zinc Halides from a Propargylic Halide and Zinc
pp. 1
Desymmetrization and Redistribution
pp. 1
Synthetic Method Development Based on Gold-Catalyzed 3,3-Rearrangements of Propargylic Carboxylates
pp. 1
From Grignard Reagents
pp. 1
From Organomagnesium Compounds
pp. 1
Synthesis of Dialkylsilver Complexes
pp. 1
From an Organolithium Reagent
pp. 1
Applications
pp. 1
Monocyclic Dinuclear Gold(III) Complexes with Bridging Ylide Ligands
pp. 1
Diarylgold(III) Compounds
pp. 1
Methyl(trimethylsiloxy)cadmium
pp. 1
Coupling Reactions of Alkynes with Dihaloalkenes
pp. 1
Alkenylzinc Halides by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
From Alkynes and Water-Soluble Copper(I) Salts
pp. 1
Donor-Free Arylgold(I) Oligomers
pp. 1
1,4-Addition of Triorganozincates to α,β-Unsaturated Ketones
pp. 1
Conjugate Additions Reactions Using Catalytic Amounts of Copper(I)
pp. 1
Perchlorophenylacetylene Using a Silver Acetylide
pp. 1
Palladium- and Nickel-Catalyzed Reactions
pp. 1
Cyclopropanation of Alkenes
pp. 1
Reductive Demercuration
pp. 1
From the Reaction of Dimethylcadmium and Diethylamine, Followed by Insertion of Carbon Disulfide or Carbon Diselenide
pp. 1
Via Oxidative Addition
pp. 1
Dialkenylzincs and Alkenyl(alkyl)zincs by Transmetalation of an Organometallic Reagent with a Dialkylzinc
pp. 1
Zinc–Allyl Complexes
pp. 1
Reduction of Tetrachloroauric Acid by Alkenes and Alkynes
pp. 1
Arylgold(III) Compounds
pp. 1
Alkenylzinc Halides from an Alkenyl Halide and Zinc
pp. 1
Cross Coupling and Homocoupling of Aryl Halides
pp. 1
Via Addition of Alcohols or Amines to Isonitrile Complexes
pp. 1
Substitution Reactions
pp. 1
From 1-Imidazol-1-yllithium and 1-Pyrrol-1-yllithium
pp. 1
Synthesis
pp. 1
Zinc–Alkenyl Complexes
pp. 1
Diallylzincs by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Cycloisomerization of 1,7- and Higher Enynes
pp. 1
Inter- and Intramolecular Addition of Nucleophiles to 1,6-Enynes
pp. 1
Alk-1-ynyl- and Vinylmercury(II) Compounds
pp. 1
Synthesis
pp. 1
From Silver Trifluoromethanesulfonate and a Cyclophane
pp. 1
Cascade Cyclization–Oxidative Alkynylation of Allenoates Using Selectfluor
pp. 1
Synthesis
pp. 1
Zinc–Aryl Complexes
pp. 1
Cascade Cyclization–Intramolecular Arylation of Benzyl-Substituted Allenoates Using Selectfluor
pp. 1
Zinc–(Het)arylmethyl Complexes
pp. 1
From an In Situ Generated Arylnickel Reagent
pp. 1
Silver–Bis(alkyne) Complexes from Organosilver Compounds and Bis(alkynyl)titanium Complexes
pp. 1
[(Dimethylsilyl)bis(trimethylsilyl)methyl]lithium and Derivatives with Cadmium(II) Chloride
pp. 1
Synthesis of Silver–Carbonyl Complexes
pp. 1
Dialkylcadmiums
pp. 1
Auration of Heterocycles by Tetrachloroauric Acid
pp. 1
From an Organoaluminum Reagent
pp. 1
Use of Boron Trifluoride in Conjugate Addition Reactions
pp. 1
Synthesis of Dialkyl(halo)gold(III) and Related Compounds from Organometallic Reagents
pp. 1
Monoarylcopper(I) Compounds
pp. 1
Silver–Tetraene Complexes
pp. 1
From Arylmercury Salts Together with Copper(0)
pp. 1
(Carbene)gold(I) Complexes
pp. 1
Synthesis
pp. 1
Silver–Dienyl Complexes
pp. 1
Trihalomethyl Anion Addition to Arylmercury(II) Compounds
pp. 1
From Arylmagnesium Halides Using Stoichiometric Amounts of Copper Salts
pp. 1
Radical Trapping by Oxygen
pp. 1
Synthesis
pp. 1
(-Butylperoxy)methylcadmium
pp. 1
Gold-Catalyzed Sonogashira Reactions
pp. 1
Synthesis of Dicoumarins via Cyclization–Homocoupling Using -Butyl Hydroperoxide
pp. 1
Synthesis of Benzo[]thiophenes
pp. 1
From Vinyl and Alk-1-ynyl Halides and Mercury(II) Cyanide
pp. 1
Conjugate Addition Reactions in the Presence of Boron Trifluoride
pp. 1
Synthesis
pp. 1
From Alkylzirconocene Complexes
pp. 1
Reactions via Gold-Containing Oxocarbenium Intermediates
pp. 1
1,4-Addition to Michael Acceptors
pp. 1
Formation of Fused Rings by Cycloisomerization of Substituted 1,6-Enynes by Friedel–Crafts-Type Processes
pp. 1
Formation of α-Unsubstituted Enones
pp. 1
Synthesis
pp. 1
Using a Mixed-Metal System (Manganese/Copper)
pp. 1
Methylmagnesium Iodide with Cadmium(II) Chloride
pp. 1
Conjugate Addition Reactions
pp. 1
Zinc–Alkynyl Complexes
pp. 1
Homocoupling of Nonactivated Arenes Using (Diacetoxyiodo)benzene
pp. 1
Synthesis
pp. 1
Alkene and Alkyne π-Complexes of Gold(I)
pp. 1
Using Tetraphenylborates
pp. 1
From Organomercury(II) Halides and Hydride Reducing Agents
pp. 1
Dialkylzincs from an Alkyl Halide and a Dialkylzinc
pp. 1
Applications
pp. 1
Mechanistic Studies Concerning the Ullmann Reaction
pp. 1
Arylzinc Halides from an Aryl Halide and Zinc
pp. 1
From an In Situ Generated Aryllithium Reagent
pp. 1
Bis(α-halomethyl)zincs or Other Zinc Carbenoids by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
Dibenzylzincs by Transmetalation of a Tribenzylborane with a Dialkylzinc
pp. 1
Alkylcadmium Thiocyanates
pp. 1
Silver–Aryl Complexes from Metalated Reagents
pp. 1
Complexes via the Organometallic Route
pp. 1
From an Aryllithium Reagent
pp. 1
From Alkynes by Carbocupration
pp. 1
Silver–Alkyne Complexes
pp. 1
Nickel- or Palladium-Catalyzed Cross Couplings
pp. 1
Oxidative Coupling with Gold(III) as a Stoichiometric Oxidant
pp. 1
Hetarylzinc Halides by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
From an Organoborane
pp. 1
Monocyclic Dinuclear Gold(I) Complexes with Bridging Ylide Ligands
pp. 1
Palladium-Catalyzed Cross Couplings
pp. 1
Synthesis
pp. 1
Synthesis
pp. 1
From the Reaction of Pentafluorohalobenzenes and Cadmium(II) Halides
pp. 1
Synthesis of Perfluoroalkylsilver Compounds
pp. 1
Methyl(selanyl)cadmium(II) Compounds
pp. 1
Miscellaneous Complexes
pp. 1
Synthesis of α-Aryl Enones from Propargyl Acetates
pp. 1
From Ylides
pp. 1
Synthesis
pp. 1
Preparation of Tetramethylgermane of High Purity
pp. 1
Synthesis
pp. 1
Synthesis
pp. 1
Gold-Catalyzed Oxidative C–O Bond Formation
pp. 1
From Perfluoroalkyl Iodides and Dialkylcadmiums
pp. 1
Conjugate Addition Reactions Using Stoichiometric Amounts of Copper(I)
pp. 1
Coupling Reactions of Alkynyl Halides
pp. 1
Alkylzinc Halides from an Alkyl Halide and a Dialkylzinc
pp. 1
Arylmercury(II) Compounds
pp. 1
Homocoupling as a Side Reaction in Cyclizations Catalyzed by Gold(III)
pp. 1
Silver–σ-Alkyl Non-homoleptic Complexes
pp. 1
Oxidative Alkynylation of Nonactivated Arenes
pp. 1
Nucleophilic Attack at the β-Position
pp. 1
Substitution Reactions Using a Catalytic Amount of Copper Salt
pp. 1
Cascade Cyclization–Intramolecular Arylation with Nonactivated Arenes Using External Oxidants
pp. 1
Diarylzincs by Transmetalation of an Organometallic Reagent with a Zinc Halide
pp. 1
From Alkylzinc Reagents
pp. 1
Gold-Catalyzed Coupling Reactions
pp. 1
Synthesis
pp. 1
From Silver Trifluoromethanesulfonate and a Tetraene
pp. 1
Synthesis
pp. 1
Coupling Reactions of Alkynes with Aryl Halides
pp. 1
Gold-Catalyzed Oxidative Homocoupling
pp. 1
Transmetalation with Organomagnesium and Organolithium Reagents
pp. 1
Using Zinc Dust
pp. 1
Nucleophilic Attack on the (Acyloxy)allene at the β- or γ-Position
pp. 1
Cyanocuprates
pp. 1
From an Aminocadmium Derivative
pp. 1
Dinuclear Silver Complexes from Lithiated Reagents
pp. 1
Conjugate Addition in the Presence of Halotrimethylsilanes
pp. 1
Auration of Arenes
pp. 1
Organogold Compounds with Alkynyl Ligands
pp. 1
Using Enyne Substrates
pp. 1
Synthesis of Dialkylgold(I) Complexes from Organolithium Compounds
pp. 1
With Organolithium and Organosilyl Reagents
pp. 1
Synthesis
pp. 1
Organomercury(II) Compounds as Radical Sources
pp. 1
Reductive Disproportionation
pp. 1
Coupling with Acid Chlorides
pp. 1
Synthesis
pp. 1
γ-Heteroalkylmercury(II) Compounds: Oxymercuration of Cyclopropanes
pp. 1
By Mixing in an Organic Solvent
pp. 1
Copper-Catalyzed Reactions
pp. 1
Cyclization–Homocoupling of 2-Alkynylphenols with (Diacetoxyiodo)benzene
pp. 1
Open-Chain α,α′-Dihydroxy Ketones from Butane-2,3-dione
pp. 1
By Reaction under Basic Phase-Transfer-Catalysis Conditions
pp. 1
Synthesis
pp. 1
Carbonylation
pp. 1
Allylzinc Halides by the Methylene Homologation of an Alkenylcopper
pp. 1
Synthesis
pp. 1
Coupling Reactions of Haloaromatic Compounds Leading to Heterocyclic Ring Formation
pp. 1
Transmetalation with Organoboron
pp. 1
From Aryllead(IV) Acetates and Copper(I) Salts
pp. 1
Synthesis of Trialkylgold(III) Complexes
pp. 1
Ketones from Acid Halides or Ketene
pp. 1
From Organolithium Compounds
pp. 1
Oxidative Alkynylation of Nonactivated Arenes Using (Diacetoxyiodo)benzene
pp. 1
β-Heteroalkylmercury(II) Compounds from Oxymercuration of Alkynes
pp. 1
Biomimetic-Type Cyclizations: Oxymercuration of Polyenes
pp. 1
From Aryl Halides and Copper(0), Including Rieke Copper
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