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Ketones
Oxidation with Osmium(VIII) Oxide/4-Methylmorpholine -Oxide
other
Author(s):
J. Suffert
Publication date
(Online):
2005
Publisher:
Georg Thieme Verlag KG
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Karger: Endocrinology
Author and book information
Book Chapter
Publication date (Print):
2005
Publication date (Online):
2005
Page
: 1
DOI:
10.1055/sos-SD-026-00847
SO-VID:
8f749455-ee9f-4af6-96a4-c9bc9b82748c
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Book chapters
pp. 1
Oxidation of 2-Alkoxyphenols
pp. 1
Of Cyclopropenone Acetals
pp. 1
Hydrolysis of Oximes and Derivatives
pp. 1
Direct Fluorination of Ketones without a Base
pp. 1
Synthesis from an Enol Ether
pp. 1
With -Butyl Hydroperoxide
pp. 1
From Alkanones through Preformed Enol Silyl Ethers
pp. 1
With Transition-Metal Complexes
pp. 1
Oxidative Deprotection of Silyl Ethers
pp. 1
By Oxidation of β-Oxo Sulfides
pp. 1
Synthesis from α-Amino Acids via an Oxazolidin-5-one
pp. 1
Aryl Ketones by Aromatization of Diels–Alder Adducts
pp. 1
By Cycloaddition
pp. 1
From Functionalized Esters, Nitriles, or Amides
pp. 1
Reduction with Dissolving Metals
pp. 1
Synthesis
pp. 1
Of (1-Formylamino)-1-(1-hydroxyalkyl)cyclopropanes
pp. 1
Substitution of Heteroatoms
pp. 1
Via a Preformed Silyl Enol Ether
pp. 1
Amine Addition to Cyclopropanone
pp. 1
From α-Diazo Ketones
pp. 1
Monoalkylation of Magnesium Enolates
pp. 1
Amino and Phosphono Ketones and Derivatives
pp. 1
Electrophilic Acylations
pp. 1
Coupling of α-Oxonitriles
pp. 1
Reduction of α-Bromo Ketones
pp. 1
Oxidative Cleavage of -Acetals
pp. 1
γ,δ-Unsaturated Ketones
pp. 1
Synthesis from Dialkoxymethyllithium Reagents
pp. 1
Conjugate Additions to α,β-Unsaturated Ketones
pp. 1
Photochemistry
pp. 1
Ring Opening of Epoxides with Chloro(dimethyl)sulfonium Chloride
pp. 1
Reduction of α-Alkoxy, α-Acyloxy, and α-Sulfonyloxy Ketones
pp. 1
By Wittig Reaction
pp. 1
Cyclopropanone Hemiaminals
pp. 1
From Monoprotected Diols and Hydroxy Sulfides
pp. 1
Synthesis from Vinyl Sulfides and Vinyl Selenides
pp. 1
[2 + 2] Cycloaddition to Benzyne Species Generated from Aromatic Halides
pp. 1
Sodium Hydrogen Sulfite Assisted Hydrolysis of Oximes and Derivatives
pp. 1
Bromination of an Enolate with Bromine
pp. 1
By Platinum-Catalyzed Hydration
pp. 1
With Manganese Compounds
pp. 1
By Radical Acylation of α,β-Unsaturated Ketones
pp. 1
Phase-Transfer Catalysis
pp. 1
Intramolecular Insertion of Trichloromethyl Ketones into Alkenes, Catalyzed by Ruthenium Complexes
pp. 1
From Hydroxy- and Sulfur-Substituted Amides and Nitriles
pp. 1
Of Hydroxynitriles
pp. 1
Enzymatic Cleavage of Hydrazone Derivatives
pp. 1
Addition of Amines to Cyclopropanone
pp. 1
Nitrosation of Phenols
pp. 1
Synthesis
pp. 1
Synthesis from Difluoro Enoxysilanes
pp. 1
Oxidation of Arylalkynes to 1,2-Diketones
pp. 1
Via the Pauson–Khand Reaction
pp. 1
By Catalyzed Nucleophilic Addition/Alkylation/Elimination
pp. 1
Rearrangement
pp. 1
Of Acyl Halides
pp. 1
Synthesis
pp. 1
Oxidative Cleavage of Hydrazone Derivatives with Peroxidic Compounds
pp. 1
Addition of Alkenylmetals to Nitriles
pp. 1
Synthesis
pp. 1
Electrophilic Acylation
pp. 1
With Organosilicon Reagents
pp. 1
Synthesis from Anhydrides, Esters, or Amides and Organometallic Reagents
pp. 1
2-(Diphenylphosphoryl)cycloalkanones by Base-Mediated Phosphinylation/Oxidation of Cycloalkanones
pp. 1
By Iron-Catalyzed Hydration
pp. 1
Miscellaneous Rearrangements
pp. 1
Synthesis
pp. 1
α,α-Disulfanyl Ketones
pp. 1
Addition
pp. 1
α-Thioxo Ketones
pp. 1
From α-Amino-α-halo Ketones or Dihydroxy Ketones
pp. 1
Hydrolysis of Enol Trifluoromethanesulfonates and Enol Phosphates
pp. 1
Rearrangement
pp. 1
Via an Iodonium Ion Transfer from the Reagent to a Silyl Enol Ether
pp. 1
By [3 + 3] Aromatic Ring Formation
pp. 1
Synthesis by Conjugate Addition to α-Iodocycloalkenones
pp. 1
Intramolecular Anionic Condensation
pp. 1
α-Oxy-α-sulfanyl Ketones
pp. 1
Addition of Allylmetals to Carboxylic Acids
pp. 1
With Chromic Acid in a Two-Phase System
pp. 1
Cyclization of Aroyl Radicals
pp. 1
From Unsaturated Carbonyl Compounds
pp. 1
Applications
pp. 1
Synthesis
pp. 1
From Cyclobutenones
pp. 1
Synthesis via Reformatsky-Type Aldol Reactions
pp. 1
Rearrangement of (1-Hydroxyalkyl)cyclopropanes
pp. 1
Hydrolysis of α-Halogenated Nitriles
pp. 1
With Chromium(VI) Compounds
pp. 1
Radical Acylation of Cyano Derivatives
pp. 1
By Elimination of Aminoalkenones
pp. 1
By Oxidation with Thallium(III) Salts
pp. 1
Synthesis
pp. 1
Bromination with Bromine Donors: Hexabromocyclopentadiene and Bromomalonic Derivatives
pp. 1
From Amino Alcohol Derivatives
pp. 1
Photodecarbonylation of Cyclobutanediones
pp. 1
Addition of Glacial Acetic Acid to Cyclopropanones
pp. 1
With Acyl Halides and Acyl Cyanides
pp. 1
Hydrolysis of α-Oxo Ketals
pp. 1
Carbonylmetalate-Induced Dehalogenation
pp. 1
Hydrolysis of Cyanohydrins and Derivatives
pp. 1
Using Permanganate and Periodate Reagents
pp. 1
Isomerization by Carbonyl Transposition
pp. 1
From α,α-Diamino Ketones
pp. 1
Addition of Carbenes or Carbenoids to Ketene Acetals
pp. 1
α-Amino-α-sulfanyl Ketones
pp. 1
Nucleophilic Acylation of Cyano Derivatives
pp. 1
Oxidation of an Alkene with Chromyl Chloride
pp. 1
Mukaiyama–Michael Reaction
pp. 1
Of 4-Oxopentyl Phosphate Carbanions
pp. 1
Willgerodt Reaction
pp. 1
Reductive Cleavage of Nitromethyl Sulfides
pp. 1
Photodenitrogenation of Dihydropyrazolones
pp. 1
Aryl Grignard Reagents
pp. 1
2-Aza Alcohol Derivatives
pp. 1
Addition to Cyclopropenone Acetals
pp. 1
Oxidative Cleavage of Thioketones
pp. 1
Ring-Closing Dehalogenation
pp. 1
Oxidation of Alkanes by Other Methods
pp. 1
Miscellaneous Reactions
pp. 1
By Oxidation with Hydroxy(mesyloxy)iodobenzene
pp. 1
Synthesis by Rearrangement
pp. 1
Metal Salt Assisted Hydrolysis of Hydrazone Derivatives
pp. 1
Oxidative Cleavage of -Disubstituted Arylalkenes
pp. 1
From Acyl Cyanides
pp. 1
Bromination of α-Alkoxy Ketones
pp. 1
Synthesis from -Alkyl or -Aryl Thioesters
pp. 1
By Oxidation with a Molybdenum Complex
pp. 1
From Alkanes and Alkenes
pp. 1
Direct Bromination with Bromine in Methanol or Carbon Tetrachloride
pp. 1
Cyclopropanation of 1-Alkoxyvinyl Esters
pp. 1
With Organotin Reagents
pp. 1
By Addition of Metal Enolates to Elemental Selenium
pp. 1
With Other Nitrogen-Based Oxidants
pp. 1
Synthesis via the Electroreductive Coupling of Aliphatic Amides
pp. 1
Ring-Closure Reactions
pp. 1
Ring Opening of Cyclopropyl Silyl Ethers
pp. 1
Addition Reactions of Ketenes
pp. 1
Coupling of Carboxylic Acid Derivatives
pp. 1
Oxy-Cope Rearrangement
pp. 1
Epoxidation of α,β-Unsaturated β-Amino Ketones
pp. 1
Oxidative Cleavage of ,-Acetals
pp. 1
Radical Oxidative Cyclization
pp. 1
Metal-Promoted Isomerization
pp. 1
Alkyl- and/or Aryl-Substituted Epoxides
pp. 1
Synthesis from S- or N-α-Substituted Sulfones
pp. 1
Aromatization of Diels–Alder Adducts
pp. 1
Synthesis
pp. 1
By Ozonolysis
pp. 1
Of Alkenes
pp. 1
Oxidative Cleavage of Oximes and Derivatives with Peroxidic Compounds
pp. 1
Synthesis from αHydroxy and αTrimethylsiloxy Alkylphosphonates
pp. 1
Cleavage of Oximes and Derivatives by the Exchange Method
pp. 1
Using Pyridinium Dichromate and Iodine
pp. 1
Cyclopropanones
pp. 1
Hydroacylation of Alkynes
pp. 1
By Transition-Metal-Catalyzed [2 + 2 + 2] Aromatic Ring Formation
pp. 1
By Addition of Organostannane Reagents
pp. 1
Synthesis
pp. 1
By α′-Alkylation of Vinylogous Esters with Rearrangement
pp. 1
Direct Chlorination with Sodium Chlorite/Manganese(III) Acetylacetonate
pp. 1
Synthesis by Insertion of a Dialkoxycarbene into Strained Cyclic Ketones
pp. 1
Organometallic Catalysis
pp. 1
In α-Diazo Ketones
pp. 1
Using Rhodium Salts with Oxygen
pp. 1
Hydrolysis of α-Cyanodithiocarbamates
pp. 1
Oxidation of Active Methylene Compounds
pp. 1
Nazarov Cyclization of Dienones
pp. 1
Peterson Reaction of α-Silyl Ketones
pp. 1
α-Selenoxo Ketones
pp. 1
Using Iodosylbenzene
pp. 1
Metal-Assisted Hydrolysis of Haloalkenes
pp. 1
α-Alkylation of Preformed α,β-Unsaturated Ketones
pp. 1
Chlorination of Terminal Alkynes
pp. 1
Reduction with Hydrides
pp. 1
Of Alkynes
pp. 1
By Reaction of a Tin Enolate with Nitrosobenzene
pp. 1
α-Amino-α-halo and α-Halo-α-nitro Ketones
pp. 1
Lewis Acid Catalyzed Addition of Alkenylmetals to Carboxylic Acid Halides and Anhydrides
pp. 1
By [4 + 2] Aromatic Ring Formation
pp. 1
α-Phosphorylated Ketones from α-Chloro Ketones
pp. 1
Fragmentation of 1,3-Amino Halides, 1,3-Amino Sulfonates, and 1,3-Hydroxy Halides
pp. 1
Carbonylation of Functionalized Ketones
pp. 1
Synthesis via the Opening of an Epoxide
pp. 1
Synthesis by Direct Chlorination of Ketones
pp. 1
Reductive Cyclization of α,α′-Dihalopropanone Acetals
pp. 1
Acidic Hydrolysis of S- or N-α-Substituted Sulfones
pp. 1
Claisen Rearrangement
pp. 1
Intermolecular Aldol Reaction of Enamines and Enol Ethers
pp. 1
Using Basic Conditions
pp. 1
By Rearrangements, Cycloadditions, and Cyclizations
pp. 1
By Hydration/Hydrolysis
pp. 1
Direct Chlorination with Sulfuryl Chloride
pp. 1
Reductive Cleavage of ,-Acetals
pp. 1
Substitution of Heteroatoms in 1,2-Diketones
pp. 1
Intermolecular Aldol Reaction of Ketones
pp. 1
Free Radical Cyclization onto Aromatic Rings
pp. 1
By Ruthenium-Catalyzed Hydration
pp. 1
Coupling of Enolates with Transition-Metal–Allyl Complexes
pp. 1
Synthesis
pp. 1
α-Imino, α-Hydroxyimino, and α-Hydrazono Ketones
pp. 1
By 1,2-Shift of an Alkynyl Group
pp. 1
Direct Addition of Alkenylmetals to Carboxylic Acid Halides and Anhydrides
pp. 1
Of Methyl 2,3-Dihalopropanoates
pp. 1
Aerobic Oxidation and Ozonolysis of Oximes and Derivatives
pp. 1
Of α-Bromo Ketones
pp. 1
By Palladium-Catalyzed Hydration
pp. 1
Synthesis
pp. 1
Of Keteniminium Salts and Alkenes
pp. 1
Using Silver Chromate and Iodine
pp. 1
α-Chloro Ketones
pp. 1
By Other Methods
pp. 1
Neber Rearrangement
pp. 1
α,α-Diamino Ketones
pp. 1
Synthesis
pp. 1
Reduction of α-Chloro Ketones
pp. 1
Hydrolysis of α-Oxo Imines
pp. 1
Hydrolysis of -Sulfanyl- and -Sulfonylimines
pp. 1
Of Mono- or Dichloroketenes and Alkenes
pp. 1
Oxidation
pp. 1
Monoalkylation of Sodium Enolates
pp. 1
[3 + 2]-Cycloaddition Reactions from α-Oxo Dithioesters
pp. 1
From Alkyl-, Alkenyl-, and Alkynylamines
pp. 1
Synthesis
pp. 1
Reduction of α-Iodo Ketones
pp. 1
Active Metals and Salts
pp. 1
Hydrolysis and Hydration Reactions
pp. 1
α-Bromo Ketones
pp. 1
Monoalkylation Using Sodium Triethylgermanate(II)
pp. 1
Synthesis from Hydrazone Derivatives
pp. 1
Synthesis
pp. 1
From α-Alkoxy- or α-Halo-α,β-unsaturated Ketones
pp. 1
Oxidation of an Alkene with Nitrosyl Chloride
pp. 1
With Peracids
pp. 1
Reduction
pp. 1
With Organic Oxoammonium Salts
pp. 1
Synthesis from α-Halo-α-sulfanyl- or α-Halo-α-oxo Ketones
pp. 1
Nitrosation of Ketones
pp. 1
Of Ketene Silyl Acetals and Alkenes
pp. 1
Conversion of Arylperfluoroalkanes into Aryl Perfluoroalkyl Ketones
pp. 1
Metal-Catalyzed Reductive Cleavage of Oximes and Derivatives
pp. 1
Cyclization of Oxo Esters and Ketones with 1,2-Dibromoethane
pp. 1
Oxidation of Allylic Alcohols
pp. 1
Transition-Metal-Catalyzed Arylation of Aryl Ketones
pp. 1
Transition-Metal-Catalyzed Coupling of Organometallics with Alkenyl Acid Halides
pp. 1
With Amides or Nitriles
pp. 1
Metal-Catalyzed Hydrolysis of Vinyl Sulfides and Vinyl Selenides
pp. 1
Ring-Opening and Ring-Expansion Reactions
pp. 1
Other Concerted Reactions
pp. 1
Synthesis from Carboxylic Esters
pp. 1
2-Halo Alcohols and Derivatives
pp. 1
Acylation of Allyl Organometallics
pp. 1
Synthesis from Diselenoacetals
pp. 1
Reduction of α-Nitrogenated Ketones
pp. 1
Direct Chlorination with Copper(II) Chloride/Lithium Chloride
pp. 1
Claisen-Type Rearrangements
pp. 1
Ring Formation by Carbonylation
pp. 1
[2 + 2]-Cycloaddition Reactions of Dichloroketenes
pp. 1
Addition of Organometallic Reagents to 1,2-Diacyl Derivatives
pp. 1
Via a Preformed Enamine or Enamide
pp. 1
β,γ-Unsaturated Ketones
pp. 1
From α-Oxo Sulfonium Ylides
pp. 1
Epoxysilanes
pp. 1
With Organomanganese Reagents
pp. 1
With Sterically Hindered Bases
pp. 1
Ring Closure of 1,1,3-Tris(phenylsulfanyl)alkanes
pp. 1
Cycloaddition Reactions
pp. 1
Cyclopropanone Acetals
pp. 1
Nitrosation of Enones
pp. 1
Cleavage of O-Silylated Cyanohydrins
pp. 1
Of 2,2-Dichlorocyclobutanones
pp. 1
Oxygen-Substituted Aryl Ketones
pp. 1
With Organoboron Reagents
pp. 1
α′-Alkylation of Preformed α,β-Unsaturated Ketones
pp. 1
Ring Expansion
pp. 1
Addition of Alkenylmetals to Carboxylic Acids
pp. 1
Hydrolysis of Vinyl Sulfides and Vinyl Selenides
pp. 1
Synthesis from -Acetals
pp. 1
Fragmentation of Alkenes
pp. 1
Copper(I)-Catalyzed Coupling of Terminal Alkynes and Acid Chlorides
pp. 1
Oxidation
pp. 1
Via an Iodonium Ion Transfer Reagent and an Enol Acetate
pp. 1
By Direct γ-Alkylation
pp. 1
Acylation of Organometallic Reagents
pp. 1
Synthesis from Amines
pp. 1
Transition-Metal-Catalyzed Carbonylation of Aryl Halides and Pseudohalides
pp. 1
Metal-Catalyzed Cleavage of Dithioketal Monosulfoxides and Dithioketal Disulfoxides
pp. 1
Synthesis via the Ring Opening of an Epoxide
pp. 1
Synthesis
pp. 1
Metal-Induced Hydrolyses of α-(Methylsulfanyl)methyl Sulfones
pp. 1
Of 1,2-Diols
pp. 1
Nucleophilic Acylation
pp. 1
Deconjugative Alkylation of α,β-Unsaturated Ketones
pp. 1
Oxidation of Ethers
pp. 1
Rearrangements of α,β-Epoxy Ketones
pp. 1
Via Acylation Reactions
pp. 1
Synthesis from α-Bromo Ketones by Substitution
pp. 1
Of (Alkoxyalkylidene)chromium Complexes
pp. 1
Synthesis
pp. 1
By Oxidation of a Titanium Enolate
pp. 1
By Addition of Bromine to 1,2-Dialkoxyalkenes
pp. 1
Bromination with Perbromide Salts
pp. 1
Chlorination of α-Alkoxy Ketones
pp. 1
Synthesis of α,α-Dialkoxy Ketones from Ketones
pp. 1
Oxidative and Nitrosative Cleavage of Diselenoacetals
pp. 1
Metal Salt Assisted Hydrolysis of Oximes and Derivatives
pp. 1
[3 + 2] Cycloaddition to Cyclopropenone
pp. 1
With Chromic Acid in Acetic Acid
pp. 1
Synthesis by Homologation from Phenylselenoacetaldehyde
pp. 1
Using Transition Metal Compounds
pp. 1
Amino-Substituted Aryl Ketones by Ionic [2 + 2 + 2] Aromatic Ring Formation
pp. 1
Synthesis of Dialkoxycyclobutanones via [2 + 2]-Cycloaddition Reactions
pp. 1
Synthesis from Carboxylic Anhydrides
pp. 1
Transition Metals and Salts
pp. 1
Rearrangement of Thiirene or Thiirane -Oxides
pp. 1
Cyclization by Intramolecular Substitution
pp. 1
Alkylation of Stannylated Enols
pp. 1
From 1,3-Dithiane
pp. 1
Transition-Metal-Catalyzed Oxidation of Alkanes
pp. 1
From α-Alkoxy-α-halo Ketones
pp. 1
With Organozinc Reagents
pp. 1
Of Sulfur Ylides to Carboxylic Acid Derivatives
pp. 1
Synthesis
pp. 1
From α-Amino-α-halo Ketones
pp. 1
With Palladium-Based Catalysts
pp. 1
Isomerization of Allene Oxides
pp. 1
Transition-Metal-Catalyzed Coupling of Alkenylmetals with Organic Halides and Carbon Monoxide
pp. 1
With Organotitanium and Organozirconium Reagents
pp. 1
Acidic Hydrolysis of 1-[(Methylsulfanyl)methyl]-1-benzotriazoles
pp. 1
Synthesis by Rearrangement of α,α′-Dialkoxy Ketones
pp. 1
With Periodate
pp. 1
With Ruthenium(VIII) Oxide
pp. 1
Of γ-Lactone Tosylhydrazones
pp. 1
With a Chiral Proton Source
pp. 1
By Carbonylation
pp. 1
Intramolecular Acylation by Electrophilic Aromatic Substitution
pp. 1
Silicon Hydrides
pp. 1
From α-Selanyl Ketones
pp. 1
Using Chromates and Permanganates under Lewis Acid Catalysis
pp. 1
By Eschenmoser Fragmentation
pp. 1
Dehydrohalogenation of α,α′-Dihalo Ketones
pp. 1
Synthesis from Aldehydes and Iminium Salts
pp. 1
Direct Bromination with Bromine in the Presence of Potassium Chlorate or Sodium Chlorate in Water
pp. 1
Aryllithium Reagents
pp. 1
Diethyl (2-Oxoethyl)phosphonates from α-Bromo Ketones and Diethyl Chlorophosphate
pp. 1
Active Metals or Salts and Electrolysis
pp. 1
Applications
pp. 1
Alkylation of Enolates Bearing α-Dithianes
pp. 1
Synthesis
pp. 1
Oxidation of α-Hydroxy-1,3-dithianes
pp. 1
In 1,2-Diketones
pp. 1
By Addition of Diaminoalkylmetal Reagents
pp. 1
Fragmentation of Acyclic 1,3-Diols and Derivatives
pp. 1
Synthesis
pp. 1
Of Cyclobutanols
pp. 1
Of 1-Alkoxy-1-(1-hydroxyalkyl)cyclopropanes
pp. 1
Cyclopropane-1,1-diamines
pp. 1
Metal-Induced Cleavage of Diselenoacetals
pp. 1
Asymmetric Reduction
pp. 1
Synthesis via Oxidative Addition to an Alkene
pp. 1
Cleavage of Hydrazone Derivatives by the Exchange Method
pp. 1
Oxidation by Molecular Oxygen
pp. 1
Synthesis from Ketenes
pp. 1
Synthesis of Dibromo Ketones by Direct Bromination of Ketones
pp. 1
Reduction of α-Sulfinyl Ketones
pp. 1
With Carboxylic Acids, Anhydrides, or Esters
pp. 1
Swern Oxidation
pp. 1
Reduction of α-Hydroxy Ketones
pp. 1
Oxidation of Alkenes without Cleavage of the Skeleton
pp. 1
Oxidation
pp. 1
Cyclopropenones
pp. 1
Allylic Oxidation with Peroxides and Catalytic Metal Salts
pp. 1
Of Ketones
pp. 1
Nonsubstituted and Carbon-Substituted Aryl Ketones
pp. 1
From α-Diazo Carbonyl Compounds
pp. 1
Reduction of α-Sulfurated Ketones
pp. 1
Reduction of α-Halo Ketones
pp. 1
Synthesis
pp. 1
Electrocyclic Rearrangements
pp. 1
α-Fluoro Ketones
pp. 1
Addition of Amines to 1,2-Diketones
pp. 1
Synthesis
pp. 1
Synthesis by Aromatic Ring Formation
pp. 1
Oxidation of α-Hydroxy Acetals
pp. 1
Oxidation of α-Chloro-α-nitro Alcohols
pp. 1
Monoalkylation of Potassium Enolates
pp. 1
Transition-Metal-Catalyzed Substitution with Acid Halides
pp. 1
By Rearrangement
pp. 1
Oxidation by Dess–Martin Periodinane
pp. 1
Of α-Sulfanyl Ketones
pp. 1
Synthesis from Trifluoromethyl Ketones via Fluorinated Silyl Enol Ethers
pp. 1
By Oxidation with Permanganate Salts
pp. 1
Hydrolysis of Enamides
pp. 1
Synthesis from Lewis Acid Mediated Aldol-Type Reactions
pp. 1
Hydrolysis of Hydrazones
pp. 1
Acylation of Organometallic Reagents
pp. 1
Synthesis from Oximes and Derivatives
pp. 1
Sulfur-Substituted Aryl Ketones
pp. 1
Ring Expansions
pp. 1
Photodecarbonylation of Cyclobutenediones
pp. 1
Friedländer Quinoline Synthesis
pp. 1
From Cyanohydrins
pp. 1
Ring Formation by [2 + 2] Cycloaddition
pp. 1
Opening of an α,β-Epoxy Ketone with Benzoyl Chloride
pp. 1
Synthesis by Acetalization of 1,2-Diketones or 1,2-Oxoaldehydes
pp. 1
Electrophilic Acylation
pp. 1
Under Irradiation
pp. 1
By Oxidation of Functional Secondary Alcohols
pp. 1
Using Dioxiranes
pp. 1
With Organocadmium Reagents
pp. 1
Synthesis from Haloalkenes
pp. 1
Of a Cobaltacyclopentan-2-one
pp. 1
Retro-Diels–Alder Reactions
pp. 1
From α-Alkylsulfanyl Ketones
pp. 1
Direct Bromination with Bromine in Acetic Acid/Water or in the Presence of Urea
pp. 1
2-Epoxy Alcohols
pp. 1
Allylic Oxidation with Selenium Reagents
pp. 1
Elimination from β-Heterosubstituted Ketones
pp. 1
Norrish Type II Fragmentation
pp. 1
Oxidation of Benzylic Nitrogen Compounds
pp. 1
Synthesis from Thioketones
pp. 1
Addition of Diazoalkanes to Ketenes
pp. 1
Synthesis via the Cyclization of an α-Amino Ester
pp. 1
Three-Component Couplings Involving Carbon Monoxide
pp. 1
1,2-Aryl Shift
pp. 1
Allylic Oxidation with Stoichiometric Chromium Reagents
pp. 1
γ-Alkylation of Preformed α,β-Unsaturated Enones
pp. 1
Photocatalytic Bromination of an Epoxide
pp. 1
γ,δ-Alkynyl Ketones
pp. 1
With Manganese(IV) Oxide
pp. 1
Addition of Allylmetals to Nitriles
pp. 1
With Organomercury Reagents
pp. 1
With Organosilicon or Organoboron Reagents
pp. 1
Fragmentation of 1,3-Diheterofunctionalized Compounds (Grob Fragmentation)
pp. 1
From Alkanones by Deprotonation/Oxidation
pp. 1
Synthesis from Amides
pp. 1
Acylation of Organometallic Reagents
pp. 1
By Rearrangement
pp. 1
Synthesis from Alkynes
pp. 1
Lewis Acid Catalyzed Substitution with Acid Halides
pp. 1
Reduction of α-Silylated Ketones
pp. 1
Bromination with Copper Bromide
pp. 1
Addition of Alkenylmetals to Carboxylic Amides and Derivatives
pp. 1
Opening of an Epoxide with Bromo(dimethyl)sulfonium Bromide
pp. 1
Addition of Alcohols
pp. 1
Oxidation of an Alkene with Chromium(VI) Oxide and Chlorotrimethylsilane
pp. 1
Using Bis(2,4,6-trimethylpyridine)iodonium(I) Tetrafluoroborate/Dimethyl Sulfoxide
pp. 1
By Alkynylation of Enolates
pp. 1
Direct Chlorination with Selenium Oxychloride
pp. 1
Synthesis from ,-Acetals
pp. 1
From Tosylmethyl Isocyanide
pp. 1
Reduction of 1,2-Diketones and α-Diazo Ketones
pp. 1
Pinacol and Related Rearrangements
pp. 1
Reductive Cleavage of Oximes and Derivatives
pp. 1
Of Nitronitriles
pp. 1
Other Methodologies
pp. 1
Oxidation by Chromium(VI) Oxide
pp. 1
Oxidative Elimination of Metal Hydride from Enol Derivatives
pp. 1
Cyclizations and Cycloadditions
pp. 1
By Sulfanylation of α-Amino Ketones
pp. 1
Reduction of α-Fluoro Ketones
pp. 1
Reduction of α-Selanyl Ketones
pp. 1
Hydrogenation under Heterogeneous Conditions
pp. 1
Intramolecular Alkylation of Aromatic Carboxylic Acid Derivatives
pp. 1
With Amides and Nitriles
pp. 1
Transition-Metal-Mediated Coupling of Organometallics with Alkenyl Halides and Carbon Monoxide
pp. 1
Synthesis from Dithioketal Monosulfoxides and Dithioketal Disulfoxides
pp. 1
Oxidation of Benzylic Sulfur Compounds
pp. 1
With Chromium(VI) Oxide in Pyridine
pp. 1
By Isomerization of Allyl Alcohols
pp. 1
Oppenauer Oxidation
pp. 1
Hydrolysis of α,α-Dihalo Ketones
pp. 1
Miscellaneous Metal-Mediated Alkylations of Enolates
pp. 1
Synthesis from Reagents Derived from α,α-Dialkoxy Ketones
pp. 1
Oxidation of an Alkene with Iron(III) Chloride
pp. 1
By Substitution of Heteroatoms
pp. 1
With Organolithium Reagents
pp. 1
From Acyl Halides
pp. 1
Synthesis
pp. 1
Monoalkylation of Manganese Enolates
pp. 1
Photoisomerization of Dienedione Monoacetals
pp. 1
Fragmentation of 1,2-Diols with Periodates
pp. 1
From Hydroxy- and Sulfanyl-Substituted Carboxylic Acids, Esters, and Thioesters
pp. 1
Thorpe–Ziegler and Related Cyclizations
pp. 1
Rearrangement of Spiro[2.2]pentanes
pp. 1
α-Selanyl Ketones
pp. 1
Horner–Wittig Reaction of Oxophosphine Oxides
pp. 1
Ring Formation by Cyclodialkylation of Protected Carbonyl Groups by 1,3-Dihalopropanes
pp. 1
Synthesis
pp. 1
Carbonylation of Aliphatic Dihalides
pp. 1
Synthesis from Trichloronitromethane
pp. 1
Electrochemical Dehalogenation
pp. 1
Using Hydrogen Peroxide and Organic Peroxides
pp. 1
Swern Oxidation of Cyclopropylcarbinols
pp. 1
By Carbon Monoxide Gas
pp. 1
Hydroxy-Substituted Aryl Ketones by [3 + 3] Aromatic Ring Formation
pp. 1
From Ortho Esters
pp. 1
Photolysis of Strained Rings
pp. 1
Reduction of α-Oxo Thioacetals
pp. 1
α,α-Dichloro Ketones
pp. 1
Reduction of α-Heterosubstituted Ketones
pp. 1
Electrocyclic Rearrangements
pp. 1
Aryl Ring Formation
pp. 1
Of Ketenes and Alkenes
pp. 1
Of Hydrazones
pp. 1
Synthesis from Silylated Enol Ethers
pp. 1
Using Sodium Periodate
pp. 1
From α-Diazo Ketones
pp. 1
Catalytic Hydrogenation
pp. 1
With Sodium Dichromate or Sodium Periodate
pp. 1
Oxidation Reactions
pp. 1
With Cobalt-Based Catalysts
pp. 1
Transition-Metal-Catalyzed Vinylation of Enolates
pp. 1
Deprotonation with an External Base
pp. 1
By Hydrogen Elimination
pp. 1
With Copper-Based Catalysts
pp. 1
Alkylation of Silylated Enol Ethers
pp. 1
With Cobalt Complexes
pp. 1
Coupling Reactions
pp. 1
Addition of Diazoalkanes to Aldehydes
pp. 1
α,α-Dialkoxy Ketones
pp. 1
Bromination with Bromine Donors: Perfluoroalkanesulfonyl Bromides or Benzeneselenenyl Bromide
pp. 1
By Metalation
pp. 1
Electrocyclic Rearrangements
pp. 1
Synthesis from Iminium Ions, Ketimines, and Derivatives
pp. 1
Carbonylation
pp. 1
Addition Reactions
pp. 1
From 1,2-Diketones or 1,2-Oxoaldehydes
pp. 1
Substitution of Hydrogen with Sulfur Reagents
pp. 1
Of Dichlorocyclopropenes
pp. 1
Cycloadditions and Cyclizations
pp. 1
Using Hexacarbonyldicobalt–Alkyne Complexes (Pauson–Khand Reaction)
pp. 1
Cycloadditions and Miscellaneous Cyclizations
pp. 1
Oxidation of 1,2-Diketones to Carboxylic Acids
pp. 1
From Nitroalkanes (The Nef Reaction)
pp. 1
Miscellaneous Cleavages of Silylated Enol Ethers
pp. 1
Reduction of α,β-Epoxy Ketones
pp. 1
Hydroxy-Substituted Aryl Ketones
pp. 1
Oxidation Adjacent to Alkenes
pp. 1
Synthesis via the Selective Reduction of Acyl Cyanides
pp. 1
Miscellaneous Rearrangements
pp. 1
Transition-Metal-Catalyzed Addition of Terminal Alkynes
pp. 1
Synthesis
pp. 1
Addition of Difluoroiodomethyl Ketones to Alkenes
pp. 1
Direct Chlorination with Trichloroisocyanuric Acid
pp. 1
With Alkylidenephosphorane Reagents
pp. 1
Synthesis
pp. 1
Addition of Organometallics to α,β-Unsaturated Nitriles
pp. 1
Oxidation of Secondary Alcohols with Halogen Compounds
pp. 1
α-Alkoxy-α-amino and α-Amino-α-hydroxy Ketones
pp. 1
Polyalkylation of Enols and Enolates
pp. 1
Amino-Substituted Aryl Ketones
pp. 1
From Carboxylic Acids, Esters, Lactones, and Anhydrides
pp. 1
α-Iodo Ketones
pp. 1
Hydrolysis of Iminium Salts and Imines
pp. 1
Addition of Organometallics to α,β-Unsaturated Carboxylic Acids
pp. 1
Addition of Selenoxides to Activated Alkynes
pp. 1
By Conjugate Addition to α,β-Unsaturated Ketones
pp. 1
Synthesis
pp. 1
By Addition of Dithiols to 1,2-Diketones
pp. 1
From α-Oxo Sulfoxides
pp. 1
With Organoaluminum Reagents
pp. 1
Oxidative Cleavage of Hydrazone Derivatives with High-Valency Metals
pp. 1
Direct Chlorination with Chlorotrimethylsilane/Dimethyl Sulfoxide
pp. 1
Hydration/Hydrolysis
pp. 1
Of 2-Acetoxycyclobutanones
pp. 1
With Organanolithium Reagents
pp. 1
Transition-Metal-Catalyzed Coupling of Alkenylmetals with Carboxylic Acid Halides and Anhydrides
pp. 1
Hydrides
pp. 1
Oxidation with Osmium(VIII) Oxide/4-Methylmorpholine -Oxide
pp. 1
Direct Chlorination with Hydrogen Chloride and Potassium Permanganate
pp. 1
Elimination Reactions
pp. 1
Hydrolysis of ,-Acetals
pp. 1
Deprotection of αHydroxy Alkylphosphonates
pp. 1
Nucleophilic Reagents
pp. 1
With Carboxylic Acids, Esters, or Anhydrides
pp. 1
Synthesis from α-Hydroxylated Sulfones
pp. 1
Of Diphenylsulfonium Isopropylide to Chiral Lactams
pp. 1
Enantioselective Alkylation via Chiral Lithium Amide Deprotonation
pp. 1
From Amino Nitrogenated and Related Compounds
pp. 1
Rearrangement of 1,2-Diheterofunctionalized Compounds
pp. 1
From an Alkanone via a Preformed Acetate Enol Ether
pp. 1
From 1,2-Diketones or α-Oxoaldehydes
pp. 1
Bromination with Bromine Donors: -Bromosuccinimide in the Presence of Ammonium Acetate
pp. 1
Acidic Hydrolysis of Haloalkenes
pp. 1
Synthesis from α-Diazo-β-oxo Sulfones
pp. 1
Pinacol-Type Rearrangements
pp. 1
With --Butylbenzenesulfinimidoyl Chloride
pp. 1
Heteroatom-Substituted Aryl Ketones
pp. 1
Addition of Methyllithium to Cyclopropane Carboxylic Acids
pp. 1
1,1-Bis(seleno)cyclopropanes
pp. 1
Nitrosative Cleavage of Oximes and Derivatives
pp. 1
Of α-Oxo Phosphorus Ylides
pp. 1
Miscellaneous Aryl Organometallic Reagents
pp. 1
Palladium(0)-Catalyzed Coupling of Trialkynylindiums with Acid Chlorides
pp. 1
Benzocyclobutanones from Heteroatom-Substituted Benzoyl Compounds
pp. 1
Sigmatropic Rearrangement
pp. 1
Boron Hydrides
pp. 1
α-Sulfanyl Ketones
pp. 1
Via a Preformed Enamine
pp. 1
Addition of Allylmetals to Carboxylic Amides
pp. 1
Hydrolysis of Enamines and Derivatives
pp. 1
Ring Opening of Cycloalkanes
pp. 1
Synthesis of Diiodo Ketones by Direct Iodination of Ketones
pp. 1
Oxidative Ring Opening
pp. 1
Direct Chlorination with Chlorine
pp. 1
Oxidation of Halides
pp. 1
Beirut Reaction
pp. 1
Substitution of an α-Hydrogen Atom
pp. 1
Pericyclic Elimination of α-Sulfinyl and α-Seleninyl Ketones
pp. 1
With Rhodium Complexes
pp. 1
Dehydrogenation with Alkenes and Alkynes
pp. 1
Hydroxy and Sulfanyl Ketones and Derivatives
pp. 1
By the Sakurai–Hosomi Reaction
pp. 1
α-Diazo Ketones
pp. 1
With Cyclopropanols
pp. 1
Substitution of Hydrogen by Bromine
pp. 1
1,2-Diols and Derivatives
pp. 1
Addition of Hydrogen
pp. 1
Hetero-Michael Additions
pp. 1
Enolates Bearing α-Dithiane Sulfoxides
pp. 1
β,γ-Alkynyl Ketones
pp. 1
Deracemization by Enantioselective Protonation of Enolates
pp. 1
α-Amino Ketones
pp. 1
Metal-Induced Cleavage of ,-Acetals
pp. 1
By Elimination of α,γ-Dioxo Phosphonium Ylides
pp. 1
Oxidation
pp. 1
Wittig Alkenation of 1,2-Dicarbonyls
pp. 1
Oxidation by Ruthenium(IV) Oxide
pp. 1
Synthesis
pp. 1
Oxidation of α-Oxo Dithianes
pp. 1
2-Hydroxy Ketones and Derivatives
pp. 1
α,β-Unsaturated Ketones
pp. 1
Synthesis from -Sulfanyl- and -Sulfonylimines
pp. 1
From Amino Amides, Lactams, and Aminonitriles
pp. 1
By Michael and Michael-Type Addition Reactions
pp. 1
Rearrangement of Epoxides
pp. 1
Synthesis from an α,β-Unsaturated Ketone by Reductive Bromination
pp. 1
By Addition of Organosilicon Reagents
pp. 1
From Isocyanides
pp. 1
By Aldehydes (via Cyanohydrins and Related Compounds)
pp. 1
Oxidation with Dioxiranes
pp. 1
Synthesis from Acyl Halides
pp. 1
Synthesis from Functional Anhydrides, Esters, Nitriles, or Amides
pp. 1
Enantioselective Isomerization
pp. 1
By Fragmentation
pp. 1
The Pauson–Khand Reaction
pp. 1
Of Arenes, Phenols, and Catechols
pp. 1
Synthesis
pp. 1
With Selenoesters
pp. 1
Addition of Alkenylmetals to Carboxylic Esters and Derivatives
pp. 1
Of 1-(Arylsulfanyl)-1-(1-hydroxyalkyl)cyclopropanes
pp. 1
Rearrangement of (1-Bromoalkylidene)cyclopropanes
pp. 1
Addition of Carbon Functionalities
pp. 1
Reductive Cleavage of Hydrazone Derivatives
pp. 1
Coupling of Aldehydes
pp. 1
Reductive Alkylation of Nitroalkenes
pp. 1
From Carbon Dioxide and Its Derivatives
pp. 1
Synthesis
pp. 1
Of a Bicyclo[4.1.0]heptan-2-one Tosylhydrazone
pp. 1
Reduction of Propargylic Ketones
pp. 1
Ring Opening
pp. 1
Via the Ring Opening of an α-Nitro Epoxide
pp. 1
With an Achiral Proton Source under the Influence of a Chiral Ligand
pp. 1
Of Ketene Thioacetals and Alkenes
pp. 1
Of Ketene Acetals and Acrylic or Maleic Acid Derivatives
pp. 1
Oxidation of α,α-Difluoro Alcohols
pp. 1
Cycloadditions of 1,2-Diketones
pp. 1
Epoxidation of α-Sulfanyl-α,β-unsaturated Ketones
pp. 1
Reduction of Enones
pp. 1
Synthesis from α-Diazo Ketones
pp. 1
Of Alkanones and Alkenones
pp. 1
Metal-Induced Cleavage of -Acetals
pp. 1
Oxidation with 3-Chloroperoxybenzoic Acid
pp. 1
By Base-Mediated Dienolate Formation
pp. 1
With Organic Iodine(V) Compounds
pp. 1
Secondary Amine Induced Ring Closure of α-Halo Ketones
pp. 1
Oxidation of Alkenes with Cleavage of a C=C Bond
pp. 1
Addition of Alkynylboronates
pp. 1
Acylation and Carbonylation of Aryl Metallic Species Generated from Aromatic Halides
pp. 1
By Ring Formation
pp. 1
With Nitrogen–Oxygen Compounds
pp. 1
Oxo Esters and Oxo Amides
pp. 1
Cyclization and Cycloaddition
pp. 1
Synthesis
pp. 1
Synthesis
pp. 1
With Anhydrides, Carboxylic Acids, and Esters
pp. 1
Synthesis from Alkynes
pp. 1
Additional Methods
pp. 1
Synthesis
pp. 1
Rearrangement of Allene Oxides
pp. 1
α-Alkoxy-α-halo Ketones
pp. 1
Reduction of Nitroalkenes
pp. 1
Reduction of α,α-Diheterosubstituted Ketones
pp. 1
Alkene Metathesis
pp. 1
Hydrolysis of Thioketones
pp. 1
Synthesis from α,α-Dichloro Ketones by Reduction
pp. 1
Oxonitriles
pp. 1
From Acylsilanes
pp. 1
Other Methods
pp. 1
Isomerization of Allylic Alcohols
pp. 1
Intramolecular Alkylation by Electrophilic Aromatic Substitution
pp. 1
Radical Acylation
pp. 1
Synthesis
pp. 1
Addition of Alkynylaluminum Reagents
pp. 1
By Gold-Catalyzed Hydration
pp. 1
Synthesis
pp. 1
Of a δ-Halo Cyanohydrin
pp. 1
Hydrolysis of -Acetals
pp. 1
Synthesis from Nitroalkenes
pp. 1
Addition of Bromine to 1,2-Bis(siloxy)alkenes
pp. 1
Hydroxy-Substituted Diaryl Ketones by Acyl Radical Substitution
pp. 1
Synthesis
pp. 1
Free Radical Alkylation
pp. 1
α-(Dialkoxyphosphoryl) Ketones by Rearrangement of a Vinyl Phosphate
pp. 1
Synthesis of α,α-Dialkoxy Ketones from α-Sulfinyl Ketones
pp. 1
Heterobimetallic Catalysis
pp. 1
By Other Carbonylative Methods
pp. 1
By a Hydroboration–Oxidation Sequence
pp. 1
Of Cycloocta-2,4,6-trienones
pp. 1
Ring Contraction
pp. 1
Of γ-Chloro Ketones
pp. 1
Hydrolysis of O-Acylated Cyanohydrins
pp. 1
Of Unsaturated Nitriles
pp. 1
α-Sulfanylation of Silyl Enol Ethers or Enamines
pp. 1
Tandem Michael Addition/Intramolecular Aldol Reaction (Robinson Annulation)
pp. 1
Using α-Amino-α-(sulfonylmethyl)lithium Reagents
pp. 1
By Metal–Carbonyl Reagents
pp. 1
Ring Expansion by Nonradical Methods
pp. 1
Reduction of α-Sulfonyl Ketones
pp. 1
Synthesis
pp. 1
Dieckmann Condensation
pp. 1
Oxidation with Nitrogen Compounds
pp. 1
Electrophilic Acylation of Acid Chlorides and Anhydrides
pp. 1
Transition-Metal-Catalyzed Alkylation of Aryl Ketones
pp. 1
Of 1-Azaspiro[2.2]pentanes
pp. 1
Oxidation of α-Chloro-α-sulfinyl Alcohols
pp. 1
α,α-Diselanyl Ketones
pp. 1
Ring Openings
pp. 1
Fragmentation of 1,2-Diols with -Halosuccinimide
pp. 1
Photolysis of ,-Acetals
pp. 1
Reduction of α-Oxygenated Ketones
pp. 1
Tandem Isomerization–Aldol Reaction
pp. 1
Of 1-(Aminomethyl)cyclopropanols
pp. 1
By Addition of Alcohols or Amines
pp. 1
Addition of Dialkoxycarbenes to Ketones
pp. 1
Hydrolysis of Hydrazone Derivatives
pp. 1
Hydrolysis
pp. 1
Oxidative Cleavage of Hydrazone Derivatives
pp. 1
Synthesis
pp. 1
Fragmentation of 1,3-Amino Alcohols
pp. 1
Synthesis from Enol Derivatives
pp. 1
With Permanganate
pp. 1
With Metal–Carbonyl Complexes
pp. 1
Direct Iodination under Acidic Conditions
pp. 1
Fragmentation of Ketones (Norrish Type II Fragmentation)
pp. 1
Synthesis from 1-[(Methylsulfanyl)methyl]-1-1,2,3-benzotriazoles, Dihydrobenzothiazoles, or Nitromethyl Sulfides
pp. 1
Ring Expansion
pp. 1
Direct Fluorination of Ketones
pp. 1
Synthesis from Nitriles
pp. 1
Oxidative Decyanation
pp. 1
Benzylic Oxidation
pp. 1
With Organotitanium or Organozirconium Reagents
pp. 1
Of 1-(1-Hydroxyalkyl)-1-(trimethylsilyl)cyclopropanes
pp. 1
Electrophilic Cleavage of -Acetals
pp. 1
Miscellaneous Fragmentation Reactions of 1,2-Diols
pp. 1
Epimerization via Enols and Enolates
pp. 1
Oxidative Cleavage of Oximes and Derivatives with High-Valency Metals
pp. 1
By Addition of Grignard Reagents
pp. 1
Synthesis via α,α-Dibromo Anions
pp. 1
Electrochemical Oxidation
pp. 1
Synthesis from Allenes
pp. 1
Synthesis with Retention of the Functional Group
pp. 1
Thermal Isomerization
pp. 1
Selanylation under Basic Conditions
pp. 1
Base-Induced Dehydrohalogenation of α-Halo Ketones
pp. 1
2-Sulfanyl and 2-Selenyl Alcohol Derivatives
pp. 1
Radical Acylation of Unsaturated Carbonyl Compounds
pp. 1
Acidic Conditions
pp. 1
Using Mercury Salts
pp. 1
Fungal Deracemization
pp. 1
Diazo-Transfer Reactions with Active Methylene Compounds
pp. 1
With β-Acyl Radicals
pp. 1
Addition of Organometallic Reagents
pp. 1
Addition of Thiols
pp. 1
Aryl Ketones with the Carbonyl in a Ring
pp. 1
Substitution of Cyclopropanone Derivatives
pp. 1
With Chromic Acid in Aqueous Solution
pp. 1
Addition of Allylmetals to Reactive Carboxylic Acid Derivatives
pp. 1
Of Nitro Ketones
pp. 1
Oxidation of Benzylic Halides
pp. 1
Friedel–Crafts Acylation
pp. 1
Monoalkylation of Lithium Enolates
pp. 1
Oxidation of Benzylic Alcohols and Ethers
pp. 1
With Organorhodium and Organopalladium Compounds
pp. 1
Substitution of Alkenes
pp. 1
Fluorination of α-Alkoxy Ketones
pp. 1
With Anhydrides
pp. 1
With Organocopper Reagents
pp. 1
By Oxy-Cope Rearrangement
pp. 1
Transition-Metal-Catalyzed Vinylation of Aryl Ketones
pp. 1
Oxidation of Cyclopropenes
pp. 1
Synthesis
pp. 1
From α-Lithio ,-Acetal Reagents
pp. 1
By Mercury-Catalyzed Hydration
pp. 1
From Ene Halides
pp. 1
From 1,2-Bis(trimethylsiloxy)cyclobutene
pp. 1
Organocatalysis
pp. 1
Of 1-Vinylcyclopropanols
pp. 1
Preparation from Preformed Four-Membered Rings
pp. 1
α,β-Epoxy Ketones
pp. 1
Fries Rearrangement
pp. 1
Nucleophilic Reagents and Hydrides
pp. 1
Of α-Hydroxy Ketones
pp. 1
Halogen-Substituted Aryl Ketones
pp. 1
Synthesis from an Enol Ether by Enol Acetate
pp. 1
Transition Metal Hydrides
pp. 1
By Addition of Organoboron Reagents
pp. 1
Wittig Reaction of Oxophosphoranes
pp. 1
Solvolyses
pp. 1
By Addition of Organoaluminum Reagents
pp. 1
Of Diazocyclopropane to Aldehydes
pp. 1
Aluminum Hydrides
pp. 1
Regioselective α-Selanylation of O-Silylated Enols or Boryl Enol Ethers
pp. 1
Synthesis
pp. 1
With Organic Iodine(III) Compounds
pp. 1
Bromination in the Presence of an Oxidant
pp. 1
By Direct Transition-Metal-Promoted Coupling
pp. 1
Alkylative and Electrophilic Cleavage of ,-Acetals
pp. 1
Synthesis
pp. 1
Of Carbenes to Undec-2-en-5-yn-1-ol
pp. 1
With Hypochlorite and Related Oxidants
pp. 1
Oxidation of Propargyl Alcohols
pp. 1
Synthesis
pp. 1
With Alkenes
pp. 1
Applications
pp. 1
Deprotonation with a Base Prior to Chlorination
pp. 1
Hydrations
pp. 1
With Aldehydes
pp. 1
Synthesis via a Silyl Enol Ether
pp. 1
Ring Contraction of Cyclic 1,2-Diketones
pp. 1
With Other Metal Compounds
pp. 1
With Bromo Compounds
pp. 1
Oxidation with Hydrogen Peroxide
pp. 1
By Acylation of an Organometallic Reagent with a Propargylic Ester
pp. 1
Carbonylation
pp. 1
By Addition of Organometallic Reagents
pp. 1
α-Phosphino and α-Phosphoryl Ketones
pp. 1
With Dimethyl Sulfoxide
pp. 1
Arylboryl Reagents
pp. 1
Synthesis from Miscellaneous Acylating Reagents
pp. 1
Intramolecular Aldol Condensation
pp. 1
From α,α-Dihydroxy Ketones
pp. 1
Cyclopropane Thioacetals
pp. 1
Carbonylation of Cyano Compounds
pp. 1
Ring Expansion of Alicyclic Ketones
pp. 1
Of Cyclohex-3-enones
pp. 1
Coupling Reactions between Carboxylic Acid Derivatives and Imine Derivatives
pp. 1
Transition-Metal-Catalyzed Addition of Aryl Halides and Carbon Monoxide to Allenes
pp. 1
Oxidation of Halo Alcohols
pp. 1
Hydrolysis
pp. 1
Heteroatom-Substituted Aryl Ketones by [4 + 2] Aromatic Ring Formation: Aromatization of Cycloadducts Derived from Cyanophthalides
pp. 1
Of Cyclopropenylium Salts
pp. 1
Hydration of Alkynes
pp. 1
Of Thionyl Chloride to Silyl Enol Ethers
pp. 1
Photolysis of β,γ-Unsaturated Ketones
pp. 1
Nucleophilic Acylation
pp. 1
Acylation of Lithiated Alkynes with Carbonyl Compounds
pp. 1
Oxidation of Secondary Alcohols
pp. 1
Radicals and Nucleophilic Reagents
pp. 1
Reduction of Ynones
pp. 1
Cleavage of α-Alkoxyalkylated Sulfones
pp. 1
Synthesis from Carboxylic Acids
pp. 1
Of 1-(1-Hydroxyalkyl)- or 1-Formylcyclopropanols
pp. 1
Oxidation of Secondary Alcohol Derivatives
pp. 1
Substitution
pp. 1
Heteroatom-Substituted Aryl Ketones by Intramolecular Cyclization and Aromatization
pp. 1
Cleavage of ,-Acetals by Exchange with Another Carbonyl Compound
pp. 1
Hydrolytic Cleavage of α-(Dialkylamino)nitriles
pp. 1
Of Methylenecyclobutane
pp. 1
Of Titanacyclobutanes
pp. 1
By Oxidation with Dimethyldioxirane or an Oxaziridine
pp. 1
Oxidation with Hydroperoxides and Peracids
pp. 1
Other Reductive Cleavages of Oximes and Derivatives
pp. 1
Bromination with Bromine Donors in Dimethyl Sulfoxide
pp. 1
With Miscellaneous Organometallic Reagents
pp. 1
Using Oxygen
pp. 1
Aryl Ketones by Electrocyclization and Aromatization
pp. 1
Chlorination of α-Amino Ketones
pp. 1
Synthesis
pp. 1
From Nonoxygenated Acetals or Other Functions
pp. 1
Hydrolysis of α-Oxo Thioketals
pp. 1
With Copper(II) Salts
pp. 1
α-Hydroxy and α-Oxo Ketones
pp. 1
Synthesis from α-Oxoaldehydes or 1,2-Diketones
pp. 1
Of Oxoenolates
pp. 1
By Substitution of Halogen
pp. 1
1,2-Diketones
pp. 1
By Oxidation of α-Hydroxy ,-Acetals
pp. 1
Synthesis
pp. 1
Other Oxidative Cleavages of Oximes and Derivatives
pp. 1
Synthesis
pp. 1
Synthesis
pp. 1
By Oxidation of Intermediate Boron Adducts
pp. 1
With Other Reagents
pp. 1
Cyclopropanation of Silylketene Acetals
pp. 1
By Addition of an Organometallic Group
pp. 1
Of 1-(1-Hydroxyalkyl)-1-selanylcyclopropanes
pp. 1
α-Alkoxy-α-seleno Ketones
pp. 1
Heteroatom-Substituted Aryl Ketones by [4 + 2] Aromatic Ring Formation: Aromatization of Adducts Derived from Activated Cyanomethylene Compounds
pp. 1
Synthesis
pp. 1
Direct Chlorination with Manganese(IV) Chloride
pp. 1
Propargyl Ketones
pp. 1
Of Hydroxy Ketones and Diols
pp. 1
Hydration of Arylalkynes
pp. 1
Synthesis
pp. 1
Diketones and Oxo Imines
pp. 1
Reduction of α-Diazo Ketones
pp. 1
By Propargylic Oxidation of Alkynes
pp. 1
Hydrolysis of ,Acetals
pp. 1
Cyclopropanone Hemiacetals
pp. 1
Alkylation by Phase-Transfer Catalysis
pp. 1
By Oxidation of α-Amino Ketones
pp. 1
Aerobic Oxidation and Ozonolysis of Hydrazone Derivatives
pp. 1
Of O-Protected Alk-3-en-1-ols or Alk-3-yn-1-ols
pp. 1
Cyclization and Cycloaddition
pp. 1
Synthesis
pp. 1
Hydrolysis of Enol Esters
pp. 1
By Electrocyclization and Aromatization
pp. 1
With Hypofluorous Acid
pp. 1
With Vanadium-Based Catalysts
pp. 1
Coupling of Terminal Alkynes and Acid Chlorides under Bimetallic Copper(I)/Palladium Conditions
pp. 1
Nucleophilic Acylation of Carboxylic Acid Derivatives by Acyllithium Reagents
pp. 1
From Nitrogen-Containing Carbonyl Compounds
pp. 1
From Methyl (Methylsulfanyl)methyl Sulfoxide
pp. 1
Electroreduction of α,α′-Dihalo Ketones
pp. 1
Ring Opening of Oxygenated Heterocycles
pp. 1
Direct Bromination with Bromine in Concentrated Sulfuric Acid
pp. 1
Synthesis
pp. 1
By Propargylation of Enolates
pp. 1
Alcoholysis of 1′-Substituted Cyclopropyl Ethers
pp. 1
Direct Substitution
pp. 1
Nitrogen-Substituted Aryl Ketones
pp. 1
Of Cyclohex-2-enones
pp. 1
Substitution of Hydrogen by Iodine
pp. 1
Fragmentation of α,β-Unsaturated Ketones (Eschenmoser Fragmentation)
pp. 1
Oxidation of Nitrogen Compounds
pp. 1
Nucleophilic Cleavage of -Acetals
pp. 1
Synthesis
pp. 1
Of ,-Diethylprop-1-yn-1-amine and Alkenes
pp. 1
By Addition of Organozinc Reagents
pp. 1
Synthesis from Anhydrides, Esters, or Amides and an Organometallic Reagent
pp. 1
Transfer Hydrogenation
pp. 1
Iodination of Enolates
pp. 1
Using Iodotrimethylsilane
pp. 1
Isomerization with Ring Expansion
pp. 1
Acidic Hydrolysis of Hydrazones and Derivatives
pp. 1
Stereoselective Applications
pp. 1
Of Amides
pp. 1
From 5,6-Dihydro-1,3-oxazines
pp. 1
From Oxygen-Containing Carbonyl Compounds
pp. 1
Basic Conditions
pp. 1
Via Pummerer Reaction from α-Sulfoxy Ketones
pp. 1
Addition of Heteroatoms
pp. 1
Decomposition of Tertiary Alkyl Hypochlorites
pp. 1
Hydrolysis of ,-Acetals by Exchange with Another Carbonyl Compound
pp. 1
Addition of Organometallics to α,β-Unsaturated Carboxylic Amides
pp. 1
Synthesis from Enol Ethers
pp. 1
Elimination of a Hydrogen Halide from α-Halo Ketones
pp. 1
Palladium-Catalyzed Asymmetric Alkylations and Arylations of Alkali Ketone Enolates
pp. 1
Fragmentation of 1,2-Diols with Lead(IV) Acetate
pp. 1
Of Sulfur-Containing Compounds
pp. 1
Synthesis by Oxidative Addition to an Alkene
pp. 1
Synthesis of α-Acetoxy-β-oxo Sulfides
pp. 1
Partial and Full Reduction Methodologies
pp. 1
Additional Methods
pp. 1
Sodium Iodide Induced Dehalogenation
pp. 1
Ring Enlargement of the Cyclopropane Intermediate Formed by a Simmons–Smith Cyclopropanation Reaction
pp. 1
Synthesis from α-Seleno Ketones
pp. 1
Synthesis
pp. 1
Substitution of a Hydrogen Atom
pp. 1
With -Oxides
pp. 1
Houben–Hoesch Reaction
pp. 1
α,α-Difluoro Ketones
pp. 1
Substitution of a Hydrogen Atom from an Alkanone
pp. 1
With Grignard Reagents
pp. 1
Reduction of 1,2-Diketones
pp. 1
Synthesis
pp. 1
Other Alkynyl Ketones
pp. 1
Synthesis from Enamines and Derivatives
pp. 1
Fragmentation of 1,2-Diols
pp. 1
Oxidation
pp. 1
Oxidation with Dimethyl Sulfoxide
pp. 1
With Iron Compounds
pp. 1
Hydrogenation under Homogeneous Conditions
pp. 1
Sodium-Mediated Ring Closure of β-Halo Esters
pp. 1
Via Cycloaddition
pp. 1
Main Group Metals
pp. 1
From 1,1-Dihalocyclopropanes
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