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Stereoselective Reactions of Carbonyl and Imino Groups
Using the Darzens Reaction
other
Author(s):
D. J. Ramón
,
M. Yus
Publication date
(Online):
2011
Publisher:
Georg Thieme Verlag KG
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Author and book information
Book Chapter
Publication date (Print):
2011
Publication date (Online):
2011
Page
: 1
DOI:
10.1055/sos-SD-202-00186
SO-VID:
7fecba08-f4c8-4d60-8ee9-841a7d536334
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Book chapters
pp. 1
Rhodium-Catalyzed Addition of Alkenyltrifluoroborates
pp. 1
Reactions Catalyzed by Chiral Metal Complexes
pp. 1
Diastereoselective Reduction of Ketones
pp. 1
-Selective Additions
pp. 1
Homodimerization of Aryl Aldehydes by Enzyme Catalysis
pp. 1
Asymmetric Direct Reductive Amination of Aldehydes
pp. 1
Utility of Hydrogen Bonding in Bisspiroketalization toward Azaspiracid
pp. 1
Asymmetric Direct Reductive Amination of Ketones
pp. 1
Synthesis of Aziridines by Addition of Ammonium Ylides to Imines
pp. 1
Using the Darzens Reaction with Aldehydes
pp. 1
Heterodimerization of Aryl Aldehydes by Enzyme Catalysis
pp. 1
Addition to β-Carbolines
pp. 1
Tethering Restriction To Control Spiroketalization toward Spirofungin
pp. 1
Asymmetric Catalytic Hydroboration
pp. 1
Organocatalytic Asymmetric Transfer Hydrogenation of Acyclic Imines
pp. 1
Enantioselective Addition of Alkenylaluminum Reagents
pp. 1
Steric Effects in Spiroaminal Formation toward Azaspiracid
pp. 1
Dihydroxyacetone Phosphate from Dihydroxyacetone
pp. 1
Use of 1,1′-Bi-2-naphthol
pp. 1
Using a Binuclear Zirconium–1,1′-Bi-2-naphthol Catalyst
pp. 1
Reactions Catalyzed by a Proline–Surfactant Organocatalyst
pp. 1
Using an ()-Oxynitrilase under Microaqueous Conditions
pp. 1
Aldol Addition of Acetaldehyde, Acetone, and Fluoroacetone to Aldehydes
pp. 1
Organocatalytic Hydrosilylation
pp. 1
Hydrogenation of α-Keto Esters
pp. 1
Hydrophosphonylation of Carbonyl and Imino Groups
pp. 1
Brønsted Acid Activation of the Imine
pp. 1
Epoxidation of Carbonyl Compounds
pp. 1
Proline-Catalyzed -Selective Mannich Reactions of Cyclic Imines
pp. 1
Dihydroxyacetone Phosphate from Chemical Synthesis
pp. 1
Chemical and Chemo-Enzymatic Deracemization of Secondary Alcohols
pp. 1
Using a Chiral ,′-Dioxide for Three-Component Strecker Reactions
pp. 1
Asymmetric Intramolecular Stetter Reaction of Aryl Aldehydes
pp. 1
Addition of Sulfur Ylides
pp. 1
Hydrogenation of α-Substituted β-Keto Esters: Dynamic Kinetic Resolution
pp. 1
Tandem Sulfone Alkylation/Sulfinic Acid Extrusion toward Milbemycin
pp. 1
Alkylation of Aldehydes with a Stereogenic Element at Other Positions
pp. 1
Alkenylation of Carbonyl and Imino Groups
pp. 1
Direct Enantioselective Aldol Reactions
pp. 1
Biocatalytic Kinetic Resolution of Secondary Alcohols
pp. 1
Addition to Ketimines
pp. 1
Acid-Catalyzed, Protic Solvent Spiroketalization toward Spirofungin
pp. 1
Acid-Catalyzed, Protic Solvent Spiroaminal Formation toward Sanglifehrin
pp. 1
Chiral Tertiary Phosphine Catalysis
pp. 1
Addition to Chiral Aldimines
pp. 1
Diastereoselective Addition
pp. 1
Optimization of Reaction Conditions
pp. 1
Protic Acid Promoted Michael Addition toward Spongistatin/Altohyrtin
pp. 1
Reactions Using a Lewis Base
pp. 1
5,5,6-Bisspiroketals
pp. 1
Using Chiral Lewis Base Catalysts with Allyl- and Crotyltrichlorosilane Reagents
pp. 1
Reactions Using Other Donors
pp. 1
Reactions Using Ester Donors
pp. 1
Reactions with Chiral Copper Catalysts
pp. 1
Via Hydrosilylation
pp. 1
General Aspects of Working with Whole Cells and Enzyme Preparations
pp. 1
Using Chiral Imines with Allylindium Reagents
pp. 1
Reactions of Glyoxamides with Alkylidenemalonates
pp. 1
Addition of Heteroatom-Substituted Anions to Carbonyl Compounds (Excluding the Darzens Reaction)
pp. 1
Reactions Catalyzed by Proline Derivatives
pp. 1
Using Achiral Aldehydes and Amino Alcohols as Ligands
pp. 1
Lewis Acid Mediated Spiroaminal Formation toward Azaspiracid
pp. 1
Via Transfer Hydrogenation with Organocatalysts
pp. 1
Catalytic Reactions
pp. 1
Diketones
pp. 1
Ring-Closing Metathesis toward Aigialospirol
pp. 1
Biocatalytic Deracemization of Secondary Alcohols
pp. 1
Asymmetric Direct Reductive Amination of β-Keto Amides
pp. 1
Allylation Using Chiral Allylmetal Reagents
pp. 1
Using Chiral Metal Catalysts
pp. 1
Immobilized Catalysts
pp. 1
Heteroatom Diels–Alder Approach to Berkelic Acid
pp. 1
Asymmetric Hydrogenation of Acyclic -Alkylimines
pp. 1
Alkylation of Aldehydes with a Stereogenic Center at the α-Position
pp. 1
Asymmetric Direct Reductive Amination of Ketones with Hantzsch Esters
pp. 1
Epoxidation with α-Halo Sulfinyl Compounds
pp. 1
Designed Amino Acid Catalysis
pp. 1
Aryl Additions Using Haloarenes
pp. 1
5,6-Spiroketals
pp. 1
Use of Chiral Lewis Acids
pp. 1
Anionic Cyclization toward Spirofungin
pp. 1
Proline-Catalyzed Aza-Morita–Baylis–Hillman Reaction
pp. 1
Enantioselective Addition of Terminal Alkynes to Aliphatic Aldehydes via Zinc(II) Salts
pp. 1
Reactions of Thioamides Catalyzed by a Copper Catalyst
pp. 1
Hydroboration of Ketones Catalyzed by Oxazaborolidines
pp. 1
Aldol Addition of 1-Hydroxyalkan-2-ones to Aldehydes
pp. 1
Addition to Imines (Strecker Reaction)
pp. 1
Addition of Ylides Other than Sulfur Ylides
pp. 1
6,6,5-Bisspiroketals
pp. 1
Reaction Media for Enzymatic Ketone Reductions
pp. 1
Other Methods for Cofactor Regeneration
pp. 1
Diaryl Ketones
pp. 1
Yttrium-Catalyzed Reaction of α-Hydroxy Ketones
pp. 1
Using Achiral Aldehydes and Diol Derivatives as Ligands
pp. 1
Using a Chiral 1,1′-Bi-2-naphthol Phosphate
pp. 1
Enantioselective Reduction of Aldehydes and Ketones
pp. 1
Addition to Chiral Keto Imines
pp. 1
Hydrogenation of Unsaturated Ketones (Alkenyl Alkyl Ketones)
pp. 1
Unsubstituted Additions
pp. 1
Reactions Using Aldehyde Donors
pp. 1
Reduction of Aromatic Ketones
pp. 1
Aziridination with Guanidinium Ylides
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate to Aliphatic and Haloaliphatic Aldehydes
pp. 1
Dihydroxyacetone Phosphate from Glycerol and Analogues
pp. 1
Stereoselective Synthesis 2
pp. 1
Oxidative Kinetic Resolution of α-Hydroxy Esters, Amides, Thioesters, and Phosphonates
pp. 1
Synthesis of β-Amino Ketone Products
pp. 1
Asymmetric Direct Reductive Amination of Ketones with Ammonium Formate
pp. 1
Using Aldehydes
pp. 1
Phosphoric Acid/Metal Phosphate Catalysis
pp. 1
Hydrogenation of Alkyl Ketones
pp. 1
Spiroketals
pp. 1
Hydroboration of Ketones Catalyzed by (Aminoalkoxy)boranes and Aminoborates
pp. 1
Aziridination of Imines
pp. 1
Acid-Catalyzed, Protic Solvent Bisspiroketalization toward Azaspiracid
pp. 1
Substrate Spectrum of Alcohol Dehydrogenases
pp. 1
Transfer of a Hydroxyacetyl Moiety to Aldehydes
pp. 1
Sequential Two-Step Aldol Additions of Acetaldehyde to Aldehydes
pp. 1
Using Chiral Palladium Catalysts with Allylsilane Reagents
pp. 1
Diastereoselection through Chelate Intermediates
pp. 1
Deracemization of α-Amino Acids
pp. 1
Reactions of Hetaryl Aldehydes with Nitroalkenes
pp. 1
Use of Cinchona Alkaloid Based Catalysts
pp. 1
Iodoetherification toward Spongistatin/Altohyrtin
pp. 1
Using a Thiourea–Schiff Base Catalyst
pp. 1
Acidic Conditions/Aprotic Solvent toward Pectenotoxin
pp. 1
Chiral Silicon Lewis Acid Promoted Addition
pp. 1
Using Gadolinium and a Glucose-Derived Chiral Ligand
pp. 1
Enzymes from Genetically Engineered Organisms
pp. 1
Reactions Using Other Ketone Donors
pp. 1
Enantioselective Allylation of Ketimines
pp. 1
Acid-Mediated Heteroatom Michael Approach toward Azaspiracid
pp. 1
Hydrosilylation of C=N Bonds
pp. 1
-Selective and Unsubstituted Nitro-Mannich Reactions
pp. 1
Addition of Ester Enolates to -(-Butylsulfinyl)imines
pp. 1
Asymmetric Direct Reductive Amination of β-Keto Esters
pp. 1
Hydrosilylation Catalyzed by Rhodium Complexes
pp. 1
Arylation of Imines with Arylboronic Acids and Arylboroxins
pp. 1
Baeyer–Villiger Method for Spiroketal Formation
pp. 1
Diastereoselective Hydrogenation of Carbonyl Groups
pp. 1
Addition to Imines
pp. 1
Hydrogenation of Simple Ketones
pp. 1
Reactions with Chiral Zirconium Catalysts
pp. 1
Addition of Heteroatom-Substituted Anions to Imines (Excluding the Darzens Reaction)
pp. 1
Lithium Binaphtholate Salt Catalysis
pp. 1
Using Chiral Organometallics and Ketones
pp. 1
Reactions with Chiral Titanium Catalysts
pp. 1
Using Iridium Catalysts
pp. 1
Catalytic, Asymmetric Additions of Alkynes to Aliphatic Aldehydes via Zinc(II) Salts
pp. 1
Using Ruthenium Catalysts
pp. 1
Enantioselective Allylation of Aldimines
pp. 1
Alkenylation of Aldehydes
pp. 1
Lewis Acid Activation of the Imine
pp. 1
Utility of Kinetic and Thermodynamic Conditions toward Azaspiracid
pp. 1
Addition of Diazo Compounds to Imines
pp. 1
Thiourea Hydrogen-Bond Catalysis
pp. 1
Hydrogenation of Aromatic Ketones
pp. 1
Alkylation Using the Darzens Reaction with Imines with Stereogenic Elements at the N-Substituent
pp. 1
Addition to Isoquinolines
pp. 1
Acetaldehyde as Nucleophile
pp. 1
Using Enzymes
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate to Nitrogen-Containing Aldehydes
pp. 1
Deracemization via Oxidative Kinetic Resolution
pp. 1
Heteroatom Diels–Alder Approach toward Reveromycin
pp. 1
Using Chiral Allyltitanium Reagents
pp. 1
6,6-Spiroaminals
pp. 1
Alkylation of Imines with Stereogenic Elements at the N-Substituent
pp. 1
Using the Darzens Reaction
pp. 1
Asymmetric Mukaiyama Aldol Reaction Using Chiral Aldehydes or Chiral Silyl Enol Ethers
pp. 1
Dialkyl, Alkyl Alkenyl, and Alkyl Alkynyl Ketones
pp. 1
Using a Dipeptide Catalyst
pp. 1
Bisspiroketals
pp. 1
Using Chiral Diol Catalysts with Allylboronate Reagents
pp. 1
Using a Synthetic Peptide and Aluminum
pp. 1
Enantioselective Allylation of Ketones
pp. 1
Using an Aluminum–Schiff Base Catalyst
pp. 1
Using Chiral Imines with Allyl Grignard Reagents
pp. 1
Reduction with Borohydrides, Aluminum Hydrides, and Boranes
pp. 1
Additions to Ketimines
pp. 1
Cinchona Alkaloid Derived Phase-Transfer Catalysis
pp. 1
Asymmetric Vinylogous Mukaiyama Aldol Reaction
pp. 1
Arsonium Ylides
pp. 1
Asymmetric Mukaiyama Aldol Reaction in Aqueous Media
pp. 1
Epoxidation with α-Halo Sulfonyl Compounds
pp. 1
Selective Addition of Siloxyfurans
pp. 1
Reductive Amination of C=O Bonds
pp. 1
Hydrocyanation of Carbonyl and Imino Groups
pp. 1
Using Achiral Aldehydes and Diamine Derivatives as Ligands
pp. 1
Synthesis of -1,2-Amino Alcohols
pp. 1
Via Transfer Hydrogenation with Metal Catalysts
pp. 1
Asymmetric Hydrogenation of Cyclic Imines
pp. 1
Via Hydrogenation
pp. 1
Thiourea-Functionalized Cinchona Alkaloid Catalysis
pp. 1
Using Chiral Sulfoxide Catalysts with Allyl- and Crotyltrichlorosilane Reagents
pp. 1
Alkenylation of Ketones
pp. 1
Reactions Catalyzed by a Titanium Complex
pp. 1
Reactions Giving Highly Substituted Products
pp. 1
Enantioselective Allylation of Aldehydes
pp. 1
Acid-Catalyzed Spiroaminal Formation toward Sanglifehrin
pp. 1
Aldol Addition of Pyruvate to -Arabinose and Analogues
pp. 1
Nitroaldol Reactions
pp. 1
Using Chiral Allylborane and Allylboronate Reagents
pp. 1
Selection of an Alcohol Dehydrogenase
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate Analogues to Aldehydes
pp. 1
Use of Proline-Based Catalysts
pp. 1
Using Chiral Organometallics and Aldehydes
pp. 1
Selection of Reaction Conditions
pp. 1
Using a Cinchona Alkaloid
pp. 1
Addition of Chiral Nucleophiles
pp. 1
Copper(I)–Phosphine Catalysis
pp. 1
Anionic Cyclization toward Pectenotoxin
pp. 1
Vinylogous Mannich Reaction
pp. 1
Selective Nitro-Mannich Reactions
pp. 1
Reactions of a Glycine Schiff Base Catalyzed by a Chiral Quaternary Ammonium Salt
pp. 1
Allylation Using Chiral Imines
pp. 1
Choice of Cofactor Regeneration Systems
pp. 1
Use of Chiral Thioureas
pp. 1
Reactions with Chiral Boron Catalysts
pp. 1
Electrochemical Oxidation
pp. 1
2,3-Dichloro-5,6-dicyanobenzo-1,4-quinone-Mediated Deprotection Approach to Pectenotoxin-2
pp. 1
Addition of Chiral Ylides to Achiral Imines
pp. 1
Reduction in Organic Solvents
pp. 1
Asymmetric Direct Reductive Amination of β-Hydroxy Ketones
pp. 1
Addition of Achiral Ylides to Achiral Imines
pp. 1
Dihydroxyacetone Phosphate from Sucrose via “Artificial Metabolism”
pp. 1
Reactions of -Propanoylthiazolidinethiones Catalyzed by a Nickel Complex
pp. 1
The Meerwein–Ponndorf–Verley Reduction of Ketones
pp. 1
Asymmetric Intramolecular Benzoin Reactions
pp. 1
In Situ Generation of Dihydroxyacetone Phosphate Mimics from Dihydroxyacetone
pp. 1
Asymmetric Hydrogenation of C=N Bonds with Metal Catalysts
pp. 1
Copper-Catalyzed Additions of Alkenyl(trimethoxy)silanes
pp. 1
Addition to Formyl Imines
pp. 1
Arylation of Aldehydes
pp. 1
Oxidative Kinetic Resolution of Activated Secondary Alcohols
pp. 1
Kinetic Resolution of Secondary Alcohols via Transfer Hydrogenation
pp. 1
Acid-Mediated Michael Addition toward Calyculin
pp. 1
Stereoselective Reactions on Chiral or Racemic Substrates
pp. 1
6,5,6-Bisspiroketals
pp. 1
5,5-Spiroketals
pp. 1
Chromium-Catalyzed Alkenylation (Nozaki–Hiyama–Kishi Reaction)
pp. 1
Reactions Using Methylene Ketone Donors
pp. 1
Tandem Azide Hydrogenation/Spiroaminal Formation toward Azaspiracid
pp. 1
Enantioselective Addition of Terminal Alkynes to α-Oxo Esters
pp. 1
Phosphine Catalysis
pp. 1
Deracemization of Amino Acids and Amines
pp. 1
Spiroaminals
pp. 1
Copper Hydride Catalyzed Hydrosilylation
pp. 1
Asymmetric Transfer Hydrogenation of Cyclic Imines with Metal Catalysts in Water
pp. 1
Additions to Aldimines and Ketimines
pp. 1
Reactions Catalyzed by a Chiral Zinc(II) Complex
pp. 1
Dihydroxyacetone Phosphate from -Fructose 1,6-Bisphosphate
pp. 1
Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Group 8 and 9 Metal Complexes
pp. 1
Asymmetric Intermolecular Acylation of α,β-Unsaturated Amides Catalyzed by Metallophosphites
pp. 1
Asymmetric Hydrogenation of Acyclic -Arylimines
pp. 1
Alkenylation with Boronic Acids
pp. 1
Silver-Catalyzed Additions of Enol Ethers
pp. 1
Asymmetric Transfer Hydrogenation of Imines with Metal Catalysts in Organic Media
pp. 1
Using Ketone Derivatives
pp. 1
Using a Vanadium–Salalen Catalyst and Acetone Cyanohydrin
pp. 1
Using Chiral Imines with Allylzinc Reagents
pp. 1
Tandem Iodoetherification/Lewis Acid Catalyzed Cyclization toward Azaspiracid
pp. 1
6,6-Spiroketals
pp. 1
Reoxidation by Bulk Oxidants
pp. 1
Reduction of Ketones Mediated by Wild-Type Whole Cells, Engineered Whole Cells, Enzyme Preparations, and Immobilized Enzymes
pp. 1
Reductive Coupling of Aldehydes and Alkynes
pp. 1
Using an ()-Oxynitrilase from (Cassava)
pp. 1
Cofactor Regeneration by Glucose Dehydrogenase
pp. 1
Using Palladium Catalysts
pp. 1
Acid-Catalyzed Cyclization of Allenyl Enol Ethers toward Salinomycin
pp. 1
Addition to Chiral Ketones
pp. 1
Biocatalytic Kinetic Resolution of Amino Acids and Amines
pp. 1
Deracemization via Oxidation–Reduction Coupled Processes
pp. 1
Arylation of Carbonyl and Imino Groups
pp. 1
Alkylation Using the Darzens Reaction
pp. 1
Reactions of Aryl Aldehydes with 1,3-Diarylprop-2-en-1-ones
pp. 1
Asymmetric Intramolecular Stetter Reactions Catalyzed by N-Heterocyclic Carbenes
pp. 1
Chiral Ligand/Metal Complex Catalysis of the Mukaiyama Aldol Reaction
pp. 1
Using Organocatalysts
pp. 1
Amino Acid Catalyzed Reactions
pp. 1
Reactions of Ethyl Diazoacetate Catalyzed by a Magnesium Complex
pp. 1
Spirodiepoxide Ring Opening toward Pectenotoxin
pp. 1
Reactions with Chiral Tin Catalysts
pp. 1
Additions of Aldehydes
pp. 1
Using Chiral Silver Catalysts with Allylsilane Reagents
pp. 1
Cyanosilylation of Carbonyl and Imino Groups
pp. 1
Addition of Achiral Ylides to Chiral Imines
pp. 1
Using Achiral Ketones
pp. 1
Synthesis of 1,2-Diamines
pp. 1
Diastereoselective Reduction
pp. 1
Kinetic Resolution Using Molecular Oxygen as Terminal Oxidant
pp. 1
Enantioselective Addition of Terminal Alkynes to Unactivated Ketones
pp. 1
Formation of Quaternary Stereocenters
pp. 1
Rhodium-Catalyzed Coupling of Acetylene
pp. 1
Reactions Catalyzed by Proline
pp. 1
Additions to Nitrogen-Containing Heterocycles
pp. 1
Reactions Catalyzed by an Axially Chiral Amino Sulfonamide
pp. 1
Cyclic Ketones
pp. 1
Using Chiral Allylsilane Reagents
pp. 1
Organocatalysis of the Mukaiyama Aldol Reaction
pp. 1
Reactions with Chiral Scandium Catalysts
pp. 1
Use of 1,1′-Bi-2-naphthylamine- and 1,1′-Bi-2-naphthol-Based Bifunctional Catalysts
pp. 1
Using an Aluminum–Salalen Catalyst
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate to Aldehydes
pp. 1
Lewis Base Catalyzed Reactions
pp. 1
Brønsted Acid Catalyzed Reactions
pp. 1
Asymmetric Intermolecular Stetter Reactions Catalyzed by N-Heterocyclic Carbenes
pp. 1
Heteroatom Diels–Alder/Ketal Reorganization Strategy to Monensin
pp. 1
Tandem Aromatic Addition to Aldehyde/Ketalization toward Berkelic Acid
pp. 1
Aldol Addition of Pyruvate to Aldehydes
pp. 1
Acid-Catalyzed, Protic Solvent Spiroketalization toward Milbemycin
pp. 1
Arylation of Imines
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate to Thiol-Containing Aldehydes
pp. 1
Reactions Catalyzed by Other Amine Organocatalysts
pp. 1
Using Chiral Iridium Catalysts with Allyl Acetates
pp. 1
Hydrosilylation of Ketones
pp. 1
Kinetic Resolution of Secondary Alcohols Using Manganese–Salen Complexes
pp. 1
Allylation Using Achiral Allyl Sources with Chiral Catalysts
pp. 1
Methods of Dihydroxyacetone Phosphate Synthesis
pp. 1
Ammonium Ylides
pp. 1
Catalyzed Reactions of Enolates
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate to Other Aldehydes
pp. 1
Biomimetic Reduction
pp. 1
Using Cyclic Ketones
pp. 1
Using a Chiral Ruthenium Catalyst and Lithium Carbonate
pp. 1
Asymmetric Intramolecular Stetter Reaction of Aliphatic Aldehydes
pp. 1
Using Acyclic Ketones
pp. 1
Comparison of Enzyme Formulations
pp. 1
Availability of Alcohol Dehydrogenases
pp. 1
Asymmetric Transfer Hydrogenation of Quinolines with Metal Catalysts in Water
pp. 1
Using an Aluminum–Salen Catalyst
pp. 1
Base-Catalyzed Michael Addition toward Pinnatoxin
pp. 1
Kinetic Resolution of Secondary Alcohols via Nitroxyl Radical Based Systems
pp. 1
Using an ()-Oxynitrilase from Shoots
pp. 1
Aryl Additions Using Aryl Sources Based on Zinc
pp. 1
Additions to Special Imines
pp. 1
Pummerer-Type Michael Addition toward Rubromycin
pp. 1
Reactions with Chiral Aldehydes
pp. 1
Using a Titanium and -Salicyl-β-amino Alcohol System
pp. 1
Reactions Catalyzed by Organocatalysts
pp. 1
Heterodimerization of Aryl Aldehydes Catalyzed by Metallophosphites
pp. 1
Addition to Carbonyls
pp. 1
Enantioselective Addition of Terminal Alkynes to Ketones
pp. 1
Nitro-Mannich Reaction
pp. 1
Direct Reductive Amination with Sodium Triacetoxyborohydride
pp. 1
Use of Neighboring-Group Effects in Bisspiroketal Formation toward Pinnatoxin
pp. 1
Aldehyde–Ketone Crossed Benzoin Reactions Catalyzed by N-Heterocyclic Carbenes
pp. 1
Enantioselective Addition of Alkenylzinc Reagents
pp. 1
Diastereoselection Based on Steric Hindrance
pp. 1
Aryl Additions Using Aryl Sources Based on Boron
pp. 1
Asymmetric Transfer Hydrogenation of C=N Bonds with Organocatalysts
pp. 1
Enantioselective Hydrogenation of Carbonyl Groups
pp. 1
Catalyzed Reactions of Enamines
pp. 1
Enantioselective Addition
pp. 1
Acetophenones Substituted on the Aromatic Ring
pp. 1
5,6-Spiroaminals
pp. 1
Aryl Additions with Organoaluminum Reagents
pp. 1
Synthesis with Switchable Selectivity
pp. 1
Asymmetric Hydrosilylation of Imines with Metal Catalysts
pp. 1
Using a Dimeric Vanadium–Salen Catalyst with Potassium Cyanide
pp. 1
Alkylation of Aldehydes with a Stereogenic Center at the β-Position
pp. 1
Other Aromatic Compounds
pp. 1
Using a Titanium Bifunctional Mixed Catalyst
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate to Hydroxy-Containing Aldehydes
pp. 1
Special Applications of Alcohol Dehydrogenases
pp. 1
Asymmetric Hydrogenation of Miscellaneous C=N—X Compounds
pp. 1
Aldol Addition of Glycine to Aldehydes
pp. 1
Heterogeneous Acidic Cyclization toward Rubromycin
pp. 1
Arylation of Ketones
pp. 1
Asymmetric Hydrogenation of α-Imino Esters
pp. 1
Desymmetrization of Cyclohexadienones
pp. 1
Cofactor Regeneration Systems
pp. 1
Using Aluminum and a 1,1′-Bi-2-naphthol Bis(phosphine oxide) Ligand
pp. 1
Hydrogenation of Functionalized Ketones
pp. 1
Cationic Palladium–Aqua Catalysis
pp. 1
Reactions Catalyzed by Hydrogen-Bonding Molecules
pp. 1
Bifunctional Chiral Phosphines
pp. 1
Using Aldimines
pp. 1
Hydrogenation of β-Keto Esters
pp. 1
Brønsted Acid Catalyzed -Selective Mannich Reaction
pp. 1
Whole-Cell Reductions with Wild-Type Organisms
pp. 1
Iodolactonization toward Spiroaminals
pp. 1
Self- and Cross-Aldol Reactions of Glycolaldehyde
pp. 1
Using an ()-3,3′-Bis[(dialkylamino)methyl]-1,1′-bi-2-naphthol/Dimethylaluminum Chloride System
pp. 1
Zirconium(IV)–Bis(1,1′-bi-2-naphthol) Catalysis
pp. 1
Reactions Using Methyl Ketone Donors
pp. 1
Reduction of Aldehydes
pp. 1
Stoichiometric Zinc(II)-Mediated Enantioselective Alkynylations
pp. 1
Addition to Chiral Aldehydes
pp. 1
Hydroboration of Functionalized Ketones Catalyzed by Oxazaborolidines
pp. 1
Organocatalytic Asymmetric Transfer Hydrogenation of Cyclic Imines
pp. 1
Reactions Using Chiral Copper Catalysts
pp. 1
Addition to Aldehydes
pp. 1
Reagent-Controlled Opening of Enol Ether Epoxides toward Spiroketals
pp. 1
Acetophenones Substituted on the Methyl Group
pp. 1
Comparison of Cofactor Regeneration Systems
pp. 1
Summary and Outlook
pp. 1
Diphenylzinc Additions
pp. 1
Enantioselective Reduction
pp. 1
Addition to N-Heterocycles (Reissert Reaction)
pp. 1
Reactions of Hetaryl Aldehydes with Arylmethylenemalonates
pp. 1
Proline-Catalyzed Morita–Baylis–Hillman Reactions
pp. 1
Catalytic Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes
pp. 1
Use of Chiral Brønsted Acids
pp. 1
Telluronium Ylides
pp. 1
Using Chiral Allylboronate Reagents
pp. 1
Hydrogenation of Acylsilanes
pp. 1
Hydrogenation of Miscellaneous Substrates
pp. 1
Reactions Using Chiral Metal Trifluoromethanesulfonate Complexes
pp. 1
Using an Aluminum–Bis(quinolinato) Catalyst
pp. 1
Transfer Hydrogenation
pp. 1
Stoichiometric Sulfur Ylide Epoxidations
pp. 1
Self- and Cross-Aldol Reactions of Acetaldehyde
pp. 1
Titanium Hydride Catalyzed Hydrosilylation
pp. 1
Catalytic Sulfur Ylide Epoxidations
pp. 1
Synthesis of β-Amino Ester and β-Amino Amide Products
pp. 1
Reactions Catalyzed by a Chiral Copper(II) Complex
pp. 1
Using a Quaternary Ammonium Salt as a Phase-Transfer Catalyst
pp. 1
Alcohol Dehydrogenases (Ketoreductases): The Enzymes for Carbonyl Reduction
pp. 1
Asymmetric Hydrosilylation of Imines with Organocatalysts
pp. 1
Via Biocatalysts
pp. 1
Direct Diastereoselective Aldol Reactions
pp. 1
Additions to Aldimines
pp. 1
Aldehyde–Imine Cross Coupling Catalyzed by N-Heterocyclic Carbenes
pp. 1
Alkenylation with Organozinc Reagents through Hydroboration–Transmetalation of Alkynes
pp. 1
Reactions Using Chiral Iron Catalysts
pp. 1
Addition of Diazo Compounds to Carbonyl Compounds
pp. 1
Using an Amino Acid Salt
pp. 1
Cofactor Regeneration by Formate Dehydrogenase
pp. 1
Asymmetric Intermolecular Benzoin Reactions of Aryl Aldehydes
pp. 1
Organocatalytic Asymmetric Transfer Hydrogenation of α-Imino Esters
pp. 1
Tandem Oxidative Deprotection/Cyclization toward Norhalichondrin
pp. 1
Modulated Reactions
pp. 1
Via Hydroboronation
pp. 1
-Selective Vinylogous Mannich Reactions
pp. 1
Reactions with Chiral Silyl Enol Ethers
pp. 1
Using a Cinchonine–2,2′-Biphenol–Titanium Catalyst System
pp. 1
Synthesis of -1,2-Diamines
pp. 1
Synthesis of Propargylic Aziridines by Addition of Allenylzinc Compounds to Imines
pp. 1
α-Keto and β-Keto Acid Derivatives
pp. 1
Metal Catalysis
pp. 1
Alkylation of Imines with Stereogenic Elements at the C-Substituent
pp. 1
Combination of Chiral Acid and Achiral Lewis Base
pp. 1
Aldol Addition of Pyruvate to -Acetyl--mannosamine and Analogues
pp. 1
Asymmetric Transfer Hydrogenation of C=N Bonds with Metal Catalysts
pp. 1
Tandem Staudinger/Aza-Wittig Strategy toward Azaspiracid
pp. 1
Reaction with a Chiral Silver Catalyst
pp. 1
Using Chiral Catalysts with Allylindium Reagents
pp. 1
Outlook
pp. 1
Reaction in Chiral Ionic Liquids
pp. 1
Nucleophilic Chiral Amine Catalysis
pp. 1
Alkenylation of Imines
pp. 1
Reactions Using Ketone Donors
pp. 1
Using a Thiourea Catalyst
pp. 1
Brønsted Acid Catalyzed Mannich Reaction of Acyclic Silyl Dienolates
pp. 1
Coupled Substrate for Cofactor Regeneration
pp. 1
Radical-Based Oxidative Cyclization toward Spirolides
pp. 1
Reduction in Water
pp. 1
Aziridination of Carbonyl Compounds
pp. 1
Addition of Malonates and β-Keto Esters
pp. 1
Reactions Catalyzed by Chiral Lanthanum Complexes
pp. 1
Hydroboration of C=N Bonds
pp. 1
Exploration into Hydrogen Bonding and Acid Selection in the Control of Spiroketalization toward Spongistatin/Altohyrtin
pp. 1
Deracemization of Primary, Secondary, and Tertiary Amines
pp. 1
Aldol Addition of Dihydroxyacetone Phosphate to Dialdehydes (“Tandem” Aldolization)
pp. 1
Homodimerization of Aryl Aldehydes Catalyzed by N-Heterocyclic Carbenes
pp. 1
Iridium-Catalyzed Coupling of Alkynes
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